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1. 发明专利

JP2014224053A 遷移金属化合物、オレフィン重合用触媒およびオレフィン系重合体の製造方法有权
标题翻译：过渡金属化合物，烯烃聚合催化剂和烯烃聚合物的制造方法
公开(公告)号：JP2014224053A
公开(公告)日：2014-12-04
申请号：JP2013102698
申请日：2013-05-15
申请人：三井化学株式会社 , Mitsui Chemicals Inc
发明人： MICHIGAMI KENJI , TANAKA YOICHI , UEHARA NAOKI , ISHII SEIICHI , MATSUKI TOMOAKI
IPC分类号： C07C251/24 , C07D307/06 , C08F4/645
CPC分类号： Y02P20/52
摘要：【課題】高温でも耐熱性があり、オレフィンの重合活性が高く、共重合を行う際の共重合性に優れる、遷移金属化合物を含有するオレフィン重合用触媒および該触媒の存在下で行うオレフィン系重合体の製造方法を提供する。【解決手段】遷移金属化合物は、下記一般式(I)で表される。また、オレフィン重合用触媒は、該遷移金属化合物を含有し、好ましくは有機金属化合物、有機アルミニウムオキシ化合物、および前記遷移金属化合物と反応してイオン対を形成する化合物から選ばれる少なくとも1種の化合物を含む。【選択図】なし
摘要翻译：要解决的问题：提供一种包含过渡金属化合物的烯烃聚合催化剂，即使在高温下也具有耐热性，在烯烃中具有高聚合活性，并且在进行共聚时具有优异的共聚特性，以及烯烃聚合物在存在下的制造方法的催化剂。溶解：过渡金属化合物由下面通式（I）表示。烯烃聚合催化剂包括过渡金属化合物，优选包括选自有机金属化合物，有机铝氧化合物和与过渡金属化合物反应形成离子对的化合物中的至少一种化合物。

2. 发明专利

JP2013227382A Resin composition, foam, and foaming modifier 有权
标题翻译：树脂组合物，泡沫和泡沫改性剂
公开(公告)号：JP2013227382A
公开(公告)日：2013-11-07
申请号：JP2012098929
申请日：2012-04-24
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KIMURA KAZUKI , INOUE GORO , ISAKI TAKEHARU , MICHIGAMI KENJI , IWASHITA AKIHIKO , SUZUKI MAKOTO
IPC分类号： C08J9/12 , C08F8/46 , C08F255/02 , C08L23/28 , C08L51/00 , C08L67/00 , C08L69/00 , C08L77/00
摘要： PROBLEM TO BE SOLVED: To provide: a foam that includes a thermoplastic resin chosen from a polyamide resin, a polyester resin and a polycarbonate resin, has a uniform minute foam structure, and excels in molded appearance; a thermoplastic resin composition to obtain the foam; and a foaming modifier.SOLUTION: A resin composition includes a thermoplastic resin chosen from a polyamide resin, a polyester resin and polycarbonate resin, has a specific viscoelastic property, and is such that a melt tension and a melt flow rate has a particular relationship, when a foaming agent is add to the resin composition to be foamed, a foam that has a uniform and minute foam structure, and excels in molded appearance can be obtained.
摘要翻译：要解决的问题：提供：包含选自聚酰胺树脂，聚酯树脂和聚碳酸酯树脂的热塑性树脂的泡沫体具有均匀的微小泡沫结构，并且成型外观优异; 获得泡沫的热塑性树脂组合物; 和发泡改性剂。溶液：树脂组合物包含选自聚酰胺树脂，聚酯树脂和聚碳酸酯树脂的热塑性树脂，具有特定的粘弹性，熔体张力和熔体流动速率具有特定的关系，当将发泡剂添加到待发泡的树脂组合物中时，可以获得具有均匀和微小的泡沫结构并且具有优异的模塑外观的泡沫。

3. 发明专利

JP2008239607A Transition metal compound and catalyst for polymerization comprising the transition metal compound 有权
标题翻译：过渡金属化合物和包含过渡金属化合物的聚合催化剂
公开(公告)号：JP2008239607A
公开(公告)日：2008-10-09
申请号：JP2008033887
申请日：2008-02-15
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KINOSHITA SHINSUKE , MICHIGAMI KENJI , UEHARA NAOKI , SAKUMA ATSUSHI , MIYAKE ATSUKO , YOSHIDA IKUNORI
IPC分类号： C07F7/28 , C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a new transition metal compound having excellent olefin polymerization performances and to provide a catalyst component for polymerizing an olefin composed of the transition metal compound and producing a high molecular weight polymer. SOLUTION: The transition metal compound is represented by general formula (1). The catalyst for polymerizing the olefin is composed of a component (A) and a component (B): (A) the transition metal compound and (B) at least one kind of compound selected from the group consisting of (B-1) an organometallic compound, (B-2) an organoaluminumoxy compound and (B-3) a compound reactive with the transition metal compound (A) and forming an ion pair. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的烯烃聚合性能的新的过渡金属化合物，并提供用于聚合由过渡金属化合物组成的烯烃和生产高分子量聚合物的催化剂组分。过渡金属化合物由通式（1）表示。用于聚合烯烃的催化剂由组分（A）和组分（B）组成：（A）过渡金属化合物和（B）至少一种选自（B-1）有机金属化合物，（B-2）有机铝氧化合物和（B-3）与过渡金属化合物（A）反应并形成离子对的化合物。版权所有（C）2009，JPO＆INPIT

4. 发明专利

JP2008231267A Catalyst and process for olefin polymerization 有权
标题翻译：烯烃聚合的催化剂和方法
公开(公告)号：JP2008231267A
公开(公告)日：2008-10-02
申请号：JP2007073563
申请日：2007-03-20
申请人： Mitsui Chemicals Inc , Okayama Univ , 三井化学株式会社 , 国立大学法人岡山大学
发明人： TAKAI KAZUHIKO , OSHIKI TOSHIYUKI , MICHIGAMI KENJI
IPC分类号： C08F4/68 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for olefin polymerization having the excellent olefin polymerization capability and a production process for an olefin using the catalyst. SOLUTION: The olefin polymerization catalyst includes a transition metal compound (A) represented by following general formula (I): LM(X 1 ) l (X 2 ) m Y n , (wherein L is a tridendate anion ligand represented by RQ(Pz 1 ) i (Pz 2 ) 3-i or a neutral ligand (R is a hydrogen atom, a halogen atom, a hydrocarbon group, and the like, Q is a boron, and the like, Pz 1 is a pyrazolyl group with at least the third place substituted by an alkyl group, and the like, Pz 2 is a non-substituted pyrazolyl group or a substituted pyrazolyl group, and i is an integer of 1-3), M is a transition metal atom selected from the group 5 of the periodic table, X 1 and X 2 are a hydrogen atom, a halogen atom, a hydrocarbon group, and the like, Y is a neutral ligand having an electron donating group, l+m is a number satisfying the valence of M, a plurality of groups represented by X 1 and X 2 may bond with each other so as to form a ring, and n is an integer of 0-3). COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的烯烃聚合能力的烯烃聚合催化剂和使用该催化剂的烯烃的生产方法。解决方案：烯烃聚合催化剂包括由以下通式（I）表示的过渡金属化合物（A）：LM（X 1 ）（X 1）表示的三配体阴离子配位体或者中性配体（R是氢原子，卤素原子，烃基等），Q（X），X 是硼等，其中至少第三位被烷基取代的吡唑基，等等，Pz 2 是非 - 取代的吡唑基或取代的吡唑基，i是1-3的整数），M是选自周期表第5组的过渡金属原子，X 1 和X 2是氢原子，卤原子，烃基等，Y是具有给电子基团的中性配体，l + m是满足M价数的数，表示的多个基团通过X 1 和X 2 可以键合彼此形成环，n为0-3的整数）。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2010144180A Polyolefin 有权
标题翻译：聚烯烃
公开(公告)号：JP2010144180A
公开(公告)日：2010-07-01
申请号：JP2010003965
申请日：2010-01-12
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KAWAI KOJI , YAMASHITA MASAHIRO , DOI YASUSHI , KAWAHARA NOBUO , MICHIGAMI KENJI , KANEYOSHI HIROMU , MORI RYOJI
IPC分类号： C08F10/00 , C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F110/06
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/15 , C08F210/16 , C08F210/08 , C08F2500/17
摘要： PROBLEM TO BE SOLVED: To provide a polyolefin suitable for use in a nonwoven fabric, a film, a sealant, an industrial material, transparent injection, a block polymer, an alloy, a modifying material, or the like and specifically, broadly available for applications, such as sanitary materials, civil engineering materials, automobile materials, home electric appliances, food containers, packaging materials, or miscellaneous goods. SOLUTION: The polyolefin contains a repeating unit (U 1 ) derived from one α-olefin selected from a 3-8C α-olefin and optionally a repeating unit (U 2 ), other than the repeating unit (U 1 ), derived from at least one olefin selected from a 2-20C α-olefin, wherein (i) both 2, 1-insertion and 1, 3-insertion are 0.2% or less, (ii) a molecular weight distribution (Mw/Mn) obtained by gel permeation chromatography is 1-3, and (iii) an amount of dissolvable component in decane is 2 wt.% or less. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供适用于无纺布，膜，密封剂，工业材料，透明注射剂，嵌段聚合物，合金，改性材料等的聚烯烃，具体地说，可广泛应用于卫生材料，土木工程材料，汽车材料，家用电器，食品容器，包装材料或杂项用途。解决方案：聚烯烃包含衍生自选自3-8Cα-烯烃和任选的重复单元的一种α-烯烃的重复单元（U 1 ）（U SB'），除了选自2-20℃α-烯烃中的至少一种烯烃以外的重复单元（U 1 ），其中（i）2,1-插入和1， 3-插入量为0.2％以下，（ii）通过凝胶渗透色谱法得到的分子量分布（Mw / Mn）为1-3，（iii）癸烷中可溶成分的含量为2重量％以下。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2008239960A Olefinic polymer including cyclic olefin-derived skeletal structure 审中-公开
标题翻译：烯烃聚合物，包括循环烯烃衍生的骨架结构
公开(公告)号：JP2008239960A
公开(公告)日：2008-10-09
申请号：JP2008033888
申请日：2008-02-15
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KINOSHITA SHINSUKE , KIZU KOICHI , MICHIGAMI KENJI , YOSHIDA IKUNORI
IPC分类号： C08F32/00 , C08F4/646
摘要： PROBLEM TO BE SOLVED: To provide a production method of an olefinic polymer, realizing high activity and a high cyclic olefin incorporation ratio, as compared to a conventional polymerization catalyst for a cyclic olefin. SOLUTION: The method produces an olefin polymer which contains, as an essential ingredient, a 4-30C cyclic olefin (C) represented by general formula (I) (wherein e is an integer of 0-20; R 1 to R 8 may be the same or different from each other and are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a halogenated hydrocarbon group, a silyl group-substituted hydrocarbon group, and a hydrocarbon group-substituted silyl group; and two groups selected from groups represented by R 3 -R 8 may be bonded so as to form a ring together with carbon atoms to which the two groups bond). COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：与用于环状烯烃的常规聚合催化剂相比，提供烯烃聚合物的制备方法，实现高活性和高环烯烃的引入比。解决方案：该方法生产一种烯烃聚合物，其含有作为必要成分的由通式（I）表示的4-30C环烯烃（C）（其中e为0-20的整数; R 1 至R 8可以相同或不同，并且各自为原子或选自氢原子，烃基，卤代烃基，甲硅烷基的基团 - 取代的烃基和烃基取代的甲硅烷基;选自由R 3表示的基团的两个基团可以键合形成环连同两个基团键合的碳原子）。版权所有（C）2009，JPO＆INPIT

7. 发明专利

JP2007023110A Method for producing isotactic aromatic vinyl polymer and syndiotactic aromatic vinyl polymer simultaneously 审中-公开
标题翻译：同时生产异构芳族聚乙烯和聚氨酯芳族聚合物的方法
公开(公告)号：JP2007023110A
公开(公告)日：2007-02-01
申请号：JP2005204938
申请日：2005-07-13
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MICHIGAMI KENJI , ONDA MITSUHIKO , MITANI MAKOTO
IPC分类号： C08F4/64 , C08F12/00
摘要： PROBLEM TO BE SOLVED: To provide a polymerization process that can produce isotactic aromatic polymer and syndiotactic aromatic vinyl polymer simultaneously.
SOLUTION: Aromatic vinyl compound is allowed to polymerize at 10 to 50°C in the presence of a catalyst including at least one selected from ion pair forming compounds prepared by reaction between a single transition metal compound represented by (A) general formula (I) (wherein M means Ti, Zr or Hf) and (B) (B-1) an organic metal compound, (B-2) an organic aluminum oxy compound and (B-3) a transition metal.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供可以同时产生全同立构芳族聚合物和间同立构芳族乙烯基聚合物的聚合方法。解决方案：使芳族乙烯基化合物在催化剂存在下在10〜50℃下聚合，所述催化剂包括选自由（A）通式（A）表示的单个过渡金属化合物（I）（其中M表示Ti，Zr或Hf）和（B）（B-1）有机金属化合物，（B-2）有机铝氧基化合物和（B-3）过渡金属。版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2005239910A Olefin polymerization catalyst and method for polymerizing olefin 审中-公开
标题翻译：烯烃聚合催化剂和聚合烯烃的方法
公开(公告)号：JP2005239910A
公开(公告)日：2005-09-08
申请号：JP2004052712
申请日：2004-02-27
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MICHIGAMI KENJI , JORDAN RICHARD F
IPC分类号： C07F7/00 , C07F7/28 , C08F4/645 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst having excellent olefin polymerization ability and to provide a method for producing a functional polyolefin by using the catalyst. SOLUTION: The catalyst for olefin polymerization comprises a transition metal compound (A) represented by general formula (I) (wherein L is a three-seat anion ligand or a neutral ligand represented by RQ(Pz 1 ) i (Pz 2 ) 3-i ; R is a hydrogen atom, a halogen atom, a hydrocarbon group or the like; Q is boron, carbon or the like; at least 3-position of Pz 1 is a pyrazolyl group substituted with an unsubstituted aryl group, a substituted aryl group, a ≥3C alkyl group, cycloalkyl group, amino group, oxyhydrocarbon group or the like; Pz 2 is an unsaturated pyrazolyl group or a saturated pyrazolyl group; i is an integer of 1-3; M is a transition metal atom of the group III to XI of the periodic table; X is a hydrogen atom, a halogen atom, an oxygen atom, a hydrocarbon group or the like; Y is a neutral ligand having an electron-donating group; m is a number satisfying a valance of M and n is an integer of 0-3). COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有优异的烯烃聚合能力的催化剂，并提供使用该催化剂制备功能性聚烯烃的方法。解决方案：用于烯烃聚合的催化剂包括由通式（I）表示的过渡金属化合物（A）（其中L是三官能阴离子配体或由RQ表示的中性配体（Pz R 3是氢原子，卤素原子，烃基等; R 3是氢原子，卤素原子，烃基等; Q是硼，碳等; Pz 1的至少3-位是被未取代的芳基，取代的芳基，≥3C烷基，环烷基，氨基基团，羟基烃基等; Pz 2是不饱和吡唑基或饱和吡唑基; i是1-3的整数; M是第III至XI族的过渡金属原子周期表; X是氢原子，卤素原子，氧原子，烃基等; Y是具有给电子基团的中性配体; m是满足M值的数，n是 0-3的整数）。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2010001224A Method for producing transition metal compound 有权
标题翻译：生产过渡金属化合物的方法
公开(公告)号：JP2010001224A
公开(公告)日：2010-01-07
申请号：JP2008159094
申请日：2008-06-18
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： UEHARA NAOKI , MICHIGAMI KENJI
IPC分类号： C07F7/28
摘要： PROBLEM TO BE SOLVED: To provide a method for effectively producing a specific transition metal compound useful as a catalyst component for olefin polymerization.
SOLUTION: This method for producing the transition metal compound is provided by performing the following "process 1" and "process 2" in this order. [The process 1]: For example, a process of converting a ligand (2,4-di-tert-butyl-6-(9H-fluoren-9-yl)phenol) to a dianionic ligand (L) (potassium(2,4-di-tert-butyl-6-(9H-fluoren-9-yl)phenoxide) by reacting with potassium hydride. [The process 2]: A process of preparing a transition metal compound (2,4-di-tert-butyl-6-(9H-fluoren-9-yl)phenoxy)titanium dichloride) by reacting the di-anionic ligand (L) obtained in the previous [process 1] with a transition metal compound (titanium tetrachloride).
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供有效地制备用作烯烃聚合的催化剂组分的特定过渡金属化合物的方法。解决方案：该过程金属化合物的制造方法是按照以下“工序1”和“工序2”进行的。 [方法1]：例如，将配体（2,4-二叔丁基-6-（9H-芴-9-基）苯酚）转化为二阴离子配体（L）（钾（2 ，4-二叔丁基-6-（9H-芴-9-基）酚盐）与氢化钾反应。[方法2]：制备过渡金属化合物（2,4-二叔丁基（9-芴-9-基）苯氧基）二氯化钛），通过使先前的[方法1]获得的二阴离子配位体（L）与过渡金属化合物（四氯化钛）反应。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2007224151A Manufacturing method of olefin polymer containing skeleton originated from internal olefin 有权
标题翻译：含有烯烃的烯烃聚合物的制备方法
公开(公告)号：JP2007224151A
公开(公告)日：2007-09-06
申请号：JP2006047168
申请日：2006-02-23
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MICHIGAMI KENJI , MITANI MAKOTO
IPC分类号： C08F10/00 , C08F4/6592 , C08F32/00
摘要： PROBLEM TO BE SOLVED: To provide a polyolefin having physical properties excellent in characteristics of transparency, impact resistance and the like compared with known products. SOLUTION: In the method, a 4-30C cyclic or acyclic olefin represented by general formula (I) is polymerized using a catalyst for addition polymerization to produce a polymer. In general formula (I), R 1 -R 4 may be the same with or different from each other and indicate an atom or group selected from a hydrogen atom, hydrocarbon group, halogenated hydrocarbon group, silyl group-substituted hydrocarbon group, and hydrocarbon group-substituted silyl group; either of R 1 and R 2 and either of R 3 and R 4 are hydrogen; and, of the groups indicated by R 1 -R 4 , mutually adjacent two groups may be bonded to form a ring together with the carbon atoms to which they are bonded. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供与已知产品相比具有优异的透明性，耐冲击性等特性的物理性能的聚烯烃。解决方案：在该方法中，由通式（I）表示的4-30C环状或非环状烯烃用加成聚合用催化剂聚合，生成聚合物。在通式（I）中，R 1和R 2彼此可以相同或不同，表示选自氢原子，烃基的原子或基团卤代烃基，甲硅烷基取代的烃基和烃基取代的甲硅烷基; R＆lt; SP＆gt; 1＆lt; SP＆gt;和＆lt; SP＆gt; 2＆lt; / SP＆gt;和R＆lt; SP＆gt; 3＆lt; SP＆gt;和＆lt; SP＆gt; 4＆lt; 在由R 1表示的基团中，相互相邻的两个基团可以与它们所键合的碳原子一起形成环。版权所有（C）2007，JPO＆INPIT

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