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1. 发明专利

JP2013121946A Method and apparatus for producing methacrolein and methacrylic acid from isobutanol 审中-公开
标题翻译：从ISOBUTANOL生产甲基纤维素和甲基丙烯酸的方法和装置
公开(公告)号：JP2013121946A
公开(公告)日：2013-06-20
申请号：JP2012243381
申请日：2012-11-05
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： AKIHARA HIDEJI , OYAUCHI KEN
IPC分类号： C07C27/00 , C07B61/00 , C07C45/00 , C07C45/35 , C07C47/22 , C07C51/00 , C07C51/21 , C07C57/04 , C07C67/08 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To provide a method and apparatus for producing a raw material of methacrylic resin efficiently from isobutanol.SOLUTION: This invention relates to: a method and apparatus for producing methacrolein and methacrylic acid from isobutanol, characterized by dehydrating and oxidizing the isobutanol by passing at least the isobutanol through a fixed-bed reaction device filled with a dehydration catalyst and an oxidation catalyst at a previous step and at a subsequent step, respectively; and an apparatus for producing the methacrolein and methacrylic acid, including the fixed-bed reaction device that is filled with the dehydration catalyst and the oxidation catalyst at the previous step and at the subsequent step, respectively, and dehydrates and oxidizes the isobutanol.
摘要翻译：解决的问题：提供从异丁醇有效地生产甲基丙烯酸树脂的原料的方法和装置。本发明涉及：由异丁醇生产异丁烯醛和甲基丙烯酸的方法和装置，其特征在于，通过至少使异丁醇通过填充有脱水催化剂的固定床反应装置使异丁醇脱水和氧化，氧化催化剂分别在前一步骤和随后的步骤中; 以及分别在上一步骤和后续步骤中包含填充有脱水催化剂和氧化催化剂的固定床反应装置的甲基丙烯醛和甲基丙烯酸的制造装置，并使异丁醇脱水并氧化。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2010005555A Method of preparing catalyst for use in preparing unsaturated aldehyde and unsaturated carboxylic acid 有权
标题翻译：制备用于制备不饱和醛和不饱和羧酸的催化剂的方法
公开(公告)号：JP2010005555A
公开(公告)日：2010-01-14
申请号：JP2008168746
申请日：2008-06-27
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： YAMADA KOHEI , OYAUCHI KEN
IPC分类号： B01J27/192 , B01J37/00 , B01J37/04 , C07C27/14 , C07C45/35 , C07C47/22 , C07C51/25 , C07C57/05
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method of preparing a catalyst whose molded body has excellent mechanical strength, capable of preparing corresponding unsaturated aldehydes or corresponding unsaturated carboxylic acids at a high yield from propylene, isobutylene, tertiarybutyl alcohol, or methyl tertiarybutyl ether. SOLUTION: The method of preparing a molded catalyst comprising at least molybdenum, bismuth and iron for use in preparing unsaturated aldehydes or unsaturated carboxylic acids by the vapor phase catalytic oxidation of propylene, isobutylene, tertiarybutyl alcohol, or methyl tertiarybutyl ether with molecular oxygen, is characterized by adding a polymer comprising a glucose unit and a mannose unit into particles comprising the catalyst components upon molding the particles into a molded body. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种制备其成型体具有优异机械强度的催化剂的方法，能够以高产率从丙烯，异丁烯，叔丁醇或甲基叔丁基制备相应的不饱和醛或相应的不饱和羧酸醚。解决方案：制备含有至少钼，铋和铁的模制催化剂的方法，用于通过丙烯，异丁烯，叔丁醇或甲基叔丁基醚与分子的气相催化氧化制备不饱和醛或不饱和羧酸氧的特征在于，在将颗粒成型成模制体时，将包含葡萄糖单元和甘露糖单元的聚合物添加到包含催化剂组分的颗粒中。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2012030140A METHOD FOR PRODUCING CATALYST WHICH CONTAINS AND CARRIES PALLADIUM, CATALYST WHICH CONTAINS AND CARRIES PALLADIUM, AND METHOD FOR PRODUCING α,β-UNSATURATED CARBOXYLIC ACID 审中-公开
标题翻译：生产含有载体和载体的催化剂的方法，其中含有羧甲基纤维素的载体和制备α，β-不饱和羧酸的方法
公开(公告)号：JP2012030140A
公开(公告)日：2012-02-16
申请号：JP2010169167
申请日：2010-07-28
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： AKIHARA HIDEJI , TAKEDA AKIO , KONDO MASAHIDE , OYAUCHI KEN
IPC分类号： B01J23/44 , B01J37/02 , C07B61/00 , C07C51/25 , C07C57/045
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for producing, with high productivity, α,β-unsaturated carboxylic acid from alcohol, olefin or α,β-unsaturated aldehyde.SOLUTION: A carrier which carries a palladium compound in which the palladium element is in an oxidative state is dipped in a solution of a tellurium compound in which the tellurium element is in an oxidative state, and, within 10 minutes after that, the reduction of the palladium and tellurium elements is started to gain a catalyst which contains and carries palladium, wherein the carrier carries the palladium metal and the tellurium metal; or a carrier which carries palladium metal in which the palladium element is in a metallic state is dipped in a solution of a tellurium compound in which the tellurium element is in an oxidative state, and, within 10 minutes after that, the reduction of the tellurium element is started to gain the catalyst which contains and carries palladium, wherein the carrier carries the palladium metal and the tellurium metal.
摘要翻译：待解决的问题：提供一种从醇，烯烃或α，β-不饱和醛生产α，β-不饱和羧酸的催化剂。溶液：将钯元素处于氧化态的钯化合物的载体浸渍在碲元素处于氧化态的碲化合物的溶液中，在10分钟后，开始还原钯和碲元素以获得含有并携带钯的催化剂，其中载体携带钯金属和碲金属; 或携带其中钯元素处于金属状态的钯金属的载体浸渍在其中碲元素处于氧化态的碲化合物的溶液中，并且在10分钟之后，碲的还原元素开始获得含有并携带钯的催化剂，其中载体携带钯金属和碲金属。版权所有（C）2012，JPO＆INPIT

4. 发明专利

JP2011088084A Method for producing noble metal-containing supported catalyst, the catalyst produced thereby and method for producing alpha,beta-unsaturated carboxylic acid 有权
标题翻译：用于生产含金属的载体催化剂的方法，生产的催化剂及其制备方法，用于制备ALPHA，不饱和羧酸的羧酸
公开(公告)号：JP2011088084A
公开(公告)日：2011-05-06
申请号：JP2009244231
申请日：2009-10-23
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： AKIHARA HIDEJI , TAKEDA AKIO , MIZUTANI KOICHI , OYAUCHI KEN
IPC分类号： B01J37/03 , B01J23/44 , B01J27/057 , B01J37/16 , C07B61/00 , C07C51/215 , C07C57/05
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a noble metal-containing supported catalyst to be used for producing α,β-unsaturated carboxylic acid from olefin or α,β-unsaturated aldehyde with high productivity, a method for producing the noble metal-containing supported catalyst, and a method for producing α,β-unsaturated carboxylic acid with high productivity. SOLUTION: The method for producing the noble metal-containing supported catalyst, which is used for producing α,β-unsaturated carboxylic acid from olefin or α,β-unsaturated aldehyde, comprises: a step (1) of obtaining an aqueous solution in which a noble metal salt and a base generating agent are dissolved; a step (2) of impregnating a carrier with the aqueous solution obtained at the step (1); a step (3) of heating/drying the impregnated carrier obtained at the step (2); a step (4) of firing the dried carrier obtained at the step (3) to obtain the noble metal oxide-deposited carrier being a catalyst precursor; and a step (5) of reducing a noble metal oxide in the catalyst precursor obtained at the step (4). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供一种用于以高生产率从烯烃或α，β-不饱和醛制备α，β-不饱和羧酸的贵金属负载型催化剂，该贵金属 - 含有载体的催化剂，以及高生产率的α，β-不饱和羧酸的制造方法。解决方案：用于从烯烃或α，β-不饱和醛制备α，β-不饱和羧酸的用于制备含贵金属的负载型催化剂的方法包括：步骤（1）获得含水的溶解有贵金属盐和碱发生剂的溶液; 用步骤（1）获得的水溶液浸渍载体的步骤（2）; 在步骤（2）中获得的浸渍载体的加热/干燥步骤（3）; 步骤（4），烧制步骤（3）得到的干燥载体，得到作为催化剂前体的贵金属氧化物沉积载体; 以及在步骤（4）中获得的催化剂前体中还原贵金属氧化物的步骤（5）。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2010253436A Method for manufacturing metal particle composite 审中-公开
标题翻译：制造金属颗粒复合材料的方法
公开(公告)号：JP2010253436A
公开(公告)日：2010-11-11
申请号：JP2009109251
申请日：2009-04-28
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： AKIHARA HIDEJI , YASUKAWA JUNYA , MIZUTANI KOICHI , OYAUCHI KEN
IPC分类号： B01J29/035 , B01J23/44
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a composite of metal particles with a several nano meter size and bearing a mesoporous material coated on the surface.
SOLUTION: A metal particle composite is produced by a method involving steps of producing a slurry containing a basic compound and metal salt fine particles in a solvent; mixing an alkoxide to be a raw material of the mesoporous material with the slurry; forming a composite by compounding the metal salt fine particles with the mesoporous material; forming a metal oxide composite by firing the composite in an oxygen-containing gas atmosphere; and reducing the metal oxide composite.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于制造几纳米尺寸的金属颗粒和表面上涂覆有介孔材料的复合材料的方法。解决方案：通过包括在溶剂中生产含有碱性化合物和金属盐微粒的浆料的步骤的方法制备金属颗粒复合材料; 将作为介孔材料的原料的醇盐与浆料混合; 通过将金属盐微粒与介孔材料混合而形成复合材料; 通过在含氧气体气氛中烧结复合材料形成金属氧化物复合物; 并还原金属氧化物复合物。版权所有（C）2011，JPO＆INPIT

6. 发明专利

JP2009207995A Catalyst for producing unsaturated aldehyde and unsaturated carboxylic acid and its manufacturing method 有权
标题翻译：用于生产不饱和二醛和不饱和羧酸的催化剂及其制备方法
公开(公告)号：JP2009207995A
公开(公告)日：2009-09-17
申请号：JP2008053364
申请日：2008-03-04
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： OYAUCHI KEN , YAMADA KOHEI
IPC分类号： B01J27/192 , C07B61/00 , C07C45/33 , C07C45/35 , C07C47/22 , C07C51/215 , C07C51/235 , C07C57/05
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for producing unsaturated carboxylic acid at higher selectivity while keeping the total selectivity of the objective unsaturated aldehyde and unsaturated carboxylic acid and a method for manufacturing the catalyst. SOLUTION: The catalyst, which is used for producing corresponding unsaturated aldehyde and unsaturated carboxylic acid by subjecting propylene, isobutylene, tertiary butyl alcohol or methyl tertiary butyl ether to vapor phase catalytic oxidation by using molecular oxygen, contains molybdenum, bismuth, iron and antimony at the least, at least one element (M) selected from the group consisting of cobalt, nickel, manganese, lead, calcium, magnesium, strontium, barium and zinc, and crystals of MMoO 4 , Fe 2 (MoO 4 ) 3 and BiSbO 4 at the least. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种以更高的选择性制备不饱和羧酸的催化剂，同时保持目标不饱和醛和不饱和羧酸的总选择性和制备催化剂的方法。解决方案：通过使用分子氧使丙烯，异丁烯，叔丁醇或甲基叔丁基醚进行气相催化氧化而用于生产相应的不饱和醛和不饱和羧酸的催化剂含有钼，铋，铁和锑，至少一种选自钴，镍，锰，铅，钙，镁，锶，钡和锌的元素（M）和MMoO 4 SBS的晶体， Fe（SBO）2 SBB（SBO），SBS 3，SBS 3，SBS 4，SBS 3，版权所有（C）2009，JPO＆INPIT

7. 发明专利

JP2012130919A Method for producing catalyst for synthesizing unsaturated aldehyde and unsaturated carboxylic acid 有权
标题翻译：生产用于合成不饱和醛和不饱和羧酸的催化剂的方法
公开(公告)号：JP2012130919A
公开(公告)日：2012-07-12
申请号：JP2012037256
申请日：2012-02-23
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： YAMADA KOHEI , OYAUCHI KEN
IPC分类号： B01J27/192 , C07B61/00 , C07C27/14 , C07C47/22 , C07C57/05
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a catalyst with which unsaturated aldehyde and unsaturated carboxylic acid corresponding to propylene, isobutylene, tertiary butyl alcohol or methyl tertiary-butyl ether are produced in high yield, and which has excellent mechanical strength.SOLUTION: The method for producing the catalyst for synthesizing unsaturated aldehyde and unsaturated carboxylic acid is provided in which 0.1-3 parts mass of silica gel having an average particle diameter of 1-10 nm in terms of anhydrous silicic acid (SiO), an organic binder which has a viscosity at 20°C of ≥10,000 mPa-s when formed into a 2 mass% aqueous solution, and at least one selected from the group comprising water and alcohol is added to and kneaded with 100 parts mass of spherical particles having an average particle diameter of 40-150μm which is obtained by spray-drying a solution or slurry containing molybdenum, bismuth and iron at the least, then the obtained kneaded material is subjected to extrusion molding, and after that, the extrusion-molded material is dried and heat treated.
摘要翻译：待解决的问题：提供一种制备催化剂的方法，以高产率制备对应于丙烯，异丁烯，叔丁醇或甲基叔丁基醚的不饱和醛和不饱和羧酸，并且具有优异的机械强度。解决方案：提供用于合成不饱和醛和不饱和羧酸的催化剂的制备方法，其中以无水硅酸（SiO 2）计，平均粒径为1-10nm的硅胶0.1-3质量份， SB POS =“POST”> 2 ），当形成为2质量％水溶液时，在20℃下具有≥10,000mPa·s的粘度的有机粘合剂，以及选自以下的至少一种：向100质量份平均粒径为40〜150μm的球状颗粒中添加水和醇，并将其混合至少至少含有钼，铋和铁的溶液或浆料，然后将所得捏合物进行挤出成型，然后将挤出成型材料进行干燥和热处理。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2010209063A METHOD FOR PRODUCING α,β-UNSATURATED CARBOXYLIC ACID 有权
标题翻译：生产α，β-不饱和羧酸的方法
公开(公告)号：JP2010209063A
公开(公告)日：2010-09-24
申请号：JP2010031123
申请日：2010-02-16
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： TAKEDA AKIO , MATSUI TOSHIKI , OYAUCHI KEN
IPC分类号： C07C51/25 , C07B61/00 , C07C57/045
摘要： PROBLEM TO BE SOLVED: To improve the productivity of the objective α,β-unsaturated carboxylic acid, in the production of α,β-unsaturated carboxylic acid by the liquid-phase oxidization of an alcohol, an olefin or an α,β-unsaturated aldehyde with molecular oxygen, and to stabilize catalyst life (inhibiting of activity fall).
SOLUTION: In the production of α,β-unsaturated carboxylic acid by the liquid-phase oxidization of an alcohol, an olefin or an α,β-unsaturated aldehyde with molecular oxygen, a catalyst containing palladium and tellurium is used, a molybdenum feeding liquid in which a molybdenum compound is included in the condition of having been dissolved and/or distributed, and the mass proportion of a molybdenum element is at least one mass ppm and at most 40 mass ppm, is fed into a reaction system which performs the liquid-phase oxidation, and the liquid phase oxidation is performed on a condition in which the mass proportion of the molybdenum element which exists in the reaction system does not exceed 270 mass ppm based on the mass of a liquid which exists in the reaction system.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：为了提高α，β-不饱和羧酸的目标物的生产率，在通过醇，烯烃或α的液相氧化制备α，β-不饱和羧酸时， β-不饱和醛与分子氧，并稳定催化剂寿命（抑制活性下降）。解决方案：在通过醇，烯烃或α，β-不饱和醛与分子氧的液相氧化制备α，β-不饱和羧酸时，使用含有钯和碲的催化剂，在已经溶解和/或分散的条件下包含钼化合物的钼进料液，钼元素的质量比至少为质量ppm至多40质量ppm，供入到反应体系中，进行液相氧化，并且在反应体系中存在的钼元素的质量比例基于反应中存在的液体质量不超过270质量ppm的条件下进行液相氧化系统。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2010179281A Palladium-containing catalyst, manufacturing method of the same and manufacturing method of alpha and beta-unsaturated carboxylic acid 有权
标题翻译：含铂催化剂及其制备方法及其制备方法和不饱和羧酸的反应
公开(公告)号：JP2010179281A
公开(公告)日：2010-08-19
申请号：JP2009027442
申请日：2009-02-09
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： TAKENAKA JUNKI , AKIHARA HIDEJI , TAKEDA AKIO , OYAUCHI KEN
IPC分类号： B01J27/057 , B01J23/44 , B01J37/16 , C07B61/00 , C07C51/25 , C07C57/045
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for manufacturing an α,β-unsaturated carboxylic acid with high productivity from an alcohol, olefin or α,β-unsaturated aldehyde, to provide a manufacturing method of the same and to provide a manufacturing method of an α,β-unsaturated carboxylic acid. SOLUTION: The manufacturing method of the α,β-unsaturated carboxylic acid manufactures the α,β-unsaturated carboxylic acid by conducting the liquid-phase oxidation of the alcohol, olefin or α,β-unsaturated aldehyde with molecular oxygen using the catalyst containing palladium and 0.001-0.04 mols aluminum per 1.0 mol of the palladium as catalyst consisting elements. The catalyst can be suitably manufactured by the step of reducing a compound containing palladium in the oxidation state with a reducing agent and the step of reducing a compound containing aluminum in the oxidation state with the reducing agent. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种由醇，烯烃或α，β-不饱和醛以高生产率制造α，β-不饱和羧酸的催化剂，以提供其制备方法，并提供一种 α，β-不饱和羧酸的制造方法。解决方案：通过使用分子氧进行醇，烯烃或α，β-不饱和醛的液相氧化，α，β-不饱和羧酸的制造方法通过使用含有钯的催化剂和0.001-0.04摩尔铝/ 1.0摩尔钯作为催化剂组成的元素。催化剂可以通过还原剂还原含有氧化态的钯的化合物和通过还原剂还原含有氧化态的铝的化合物的步骤来适当地制造。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2009285651A Apparatus for manufacturing liquid containing gas dissolved therein for carbonate spring 审中-公开
标题翻译：用于制造含有气体的液体用于碳酸盐弹簧的装置
公开(公告)号：JP2009285651A
公开(公告)日：2009-12-10
申请号：JP2009125731
申请日：2009-05-25
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： SAKAKIBARA MASANORI , OYAUCHI KEN , TASAKA HIROSHI
IPC分类号： B01F1/00 , A23L2/54 , A47K3/00 , A61H33/02 , A61H33/14 , B01F3/04 , B01F5/00 , B01F5/04 , B01F15/04 , G01N29/00
CPC分类号： A61H33/02 , A23L2/54 , A61H33/60 , A61H2033/145 , A61M35/00 , B01F3/0446 , B01F3/04787 , B01F3/04985 , B01F15/0022 , B01F15/00344 , B01F2003/04404 , B01F2003/04858 , B01F2003/04893 , B01F2215/0052 , Y10S261/07
摘要： PROBLEM TO BE SOLVED: To provide an apparatus for efficiently manufacturing a liquid containing a gas dissolved therein for carbonate spring in high concentration. SOLUTION: The apparatus for manufacturing a liquid containing a gas for carbonate spring comprises a carbon dioxide gas supply opening, a carbon dioxide gas dissolving unit communicated with the carbon dioxide gas supply opening, a water tank, a pump for sending water in the water tank into the carbon dioxide gas dissolving unit, a carbon dioxide gas supply control mean 5 for changing the carbon dioxide gas supply speed during the time when dissolving carbon dioxide gas, a plurality of electromagnetic valves 4' arranged in parallel in a carbon dioxide gas supply route respectively to be able to differently set carbon dioxide gas supply speed. The carbon dioxide gas supply speed control mean is equipped with the electromagnetic valve 4'. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于高浓度地含有溶解于其中的用于碳酸盐弹簧的气体的液体的制造装置。解决方案：用于制造含有用于碳酸盐弹簧的气体的液体的装置包括二氧化碳气体供给开口，与二氧化碳气体供给口连通的二氧化碳气体溶解单元，水箱，用于将水输送的泵水箱进入二氧化碳气体溶解单元，二氧化碳气体供给控制装置5，用于在二氧化碳气体溶解时改变二氧化碳气体供给速度;多个电解阀4'并联排列在二氧化碳供气路线分别能够不同地设定二氧化碳气体供应速度。二氧化碳气体供给速度控制装置配备有电磁阀4'。版权所有（C）2010，JPO＆INPIT

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