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1. 发明专利

JPH057323B2 失效
公开(公告)号：JPH057323B2
公开(公告)日：1993-01-28
申请号：JP704884
申请日：1984-01-20
申请人： MITSUBISHI HEAVY IND LTD
发明人： TSUNEYOSHI KIKUJI , SHIMOMURA MASAHITO
IPC分类号： B01D53/14 , B01J20/02 , B01J20/20 , C01B32/40

2. 发明专利

JPH0416518A METHOD FOR MODIFYING SURFACE OF INORGANIC MATERIAL 失效
公开(公告)号：JPH0416518A
公开(公告)日：1992-01-21
申请号：JP11581890
申请日：1990-05-07
申请人： MITSUBISHI HEAVY IND LTD
发明人： SHIMOMURA MASAHITO , HASHIZUME KATSUHIRO
IPC分类号： C01G49/08 , C01G23/04 , C08K9/06 , C09C3/12
摘要： PURPOSE:To reform the surface of an inorg. material by treating the material of alumina, etc., with an aq. silicate soln. to form a silicon film on the surface, allowing an alkoxysilane to act on the film and binding the silane to the film. CONSTITUTION:An aq. soln. of a silicate such as water glass is added to the powder of an inorg. material of glass, alumina, silica, etc., and sufficiently agitated, and the inorg. material powder is filtered off and washed with water until the filtrate is neutralized. The powder with the amt. of hydroxyl group on the surface increased by this treatment is mixed with trimethoxymethylsilane, heated, agitated, then sufficiently washed with methanol and dried in vacuum. The amt. of the alkoxysilane residue bound to the surface by the reaction of the hydroxyl group on the surface with the alkoxysilane is increased, and the surface is reformed.

3. 发明专利

JPH02305997A COMPOSITE PLATING METHOD 失效
公开(公告)号：JPH02305997A
公开(公告)日：1990-12-19
申请号：JP12441189
申请日：1989-05-19
申请人： MITSUBISHI HEAVY IND LTD
发明人： UEDA TAKASHI , SHIMOMURA MASAHITO
IPC分类号： C25D15/02
摘要： PURPOSE:To simultaneously render wear resistant and self-lubricant by codepositing alumina coupled with silane and other inorg. powder in a metallic Co plating film to form a composite plating film. CONSTITUTION:Alumina coupled with silane such as alkoxyalkylsilane and at least one kind of other inorg. powder are dispersed in a Co electroplating bath and a cationic surfactant or a surfactant having cationic property in the plating bath is added to the bath by 0.01-5.0wt.% and well dispersed. Electroplating is carried out with the resulting plating bath to obtain a composite plating film contg. the alumina and inorg. powder uniformly dispersed in Co plating film. The inorg. powder is preferably boron nitride powder.

4. 发明专利

JPH02115029A GAS SEPARATING MEMBRANE 失效
公开(公告)号：JPH02115029A
公开(公告)日：1990-04-27
申请号：JP26617488
申请日：1988-10-24
申请人： MITSUBISHI HEAVY IND LTD
发明人： TSURUMAKI SHIGERU , SHIMOMURA MASAHITO
IPC分类号： B01D71/70 , B01D71/78 , C08G59/00 , C08G59/20 , C08G59/30 , C08G59/40 , C08L63/00
摘要： PURPOSE:To obtain an excellent gas separating membrane by crosslinking graft copolymerizing the graft polymer of nitrocellulose and siloxane oligomer with another siloxane oligomer at the time of forming a membrane. CONSTITUTION:The siloxane oligomer of the general formula shown by the formula I having epoxy groups in the terminal portions thereof (wherein n is an interger of 1-20) dissolved in an organic solvent (acetone) is added, with heating and stirring, to the nitrocellulose large in the oxygen-nitrogen separation coefficient and relatively permeable to oxygen to prepare a graft copolymer. The resulting graft copolymer, after refining, is dissolved again in the organic solvent and, after addition thereto of the siloxane oligomer of the general formula shown by the formula II having amino groups in the terminal portions thereof (wherein n is an interger of 1-20), it is caused to flow over a glass plate and heated to form a membrane of cross-linked graft copolymer, thereby obtaining a thinner gas separating membrane having a high selectivity and permeability and an excellent oxygen permeation rate.

5. 发明专利

JPH024430A SEPARATION OF ORGANIC SOLVENT 失效
公开(公告)号：JPH024430A
公开(公告)日：1990-01-09
申请号：JP15227988
申请日：1988-06-22
申请人： MITSUBISHI HEAVY IND LTD
发明人： TSURUMAKI SHIGERU , SHIMOMURA MASAHITO
IPC分类号： B01D61/36 , B01D71/68 , C07C17/00 , C07C17/38 , C07C17/389 , C07C19/01 , C07C19/041 , C07C19/08 , C07C21/12 , C07C67/00 , D01F6/76
摘要： PURPOSE:To perform the high order concentration and separation of an orq. solvent/liquid mixture by subjecting the org. solvent/liquid mixture to permeable and evaporative separation using a non-porous membrane formed from aromatic polysulfone represented by a specific general formula. CONSTITUTION:An org. solvent/liquid mixture is subjected to permeable and evaporative separation using a non-porous membrane formed from aromatic polysulfone represented by formula I or II (wherein n is an integer of 50-100). The MW of the aforementioned aromatic polysulfone is pref. 20,000-40,000 and a non-porous membrane formed from said polysulfone has no pore other than molecular gaps formed by the thermal vibration of the constitutional polymer of said membrane and the diameter of each molecular gas is 10Angstrom or less. As the org. solvent/liquid mixture separable by this method, there is a mixture of chlorine substituted compounds of hydrocarbon and fluorine/chlorine substituted compounds of hydrocarbon.

6. 发明专利

JPS63256966A MAGNETIC MATERIAL FOR PRINTING 失效
公开(公告)号：JPS63256966A
公开(公告)日：1988-10-24
申请号：JP9071587
申请日：1987-04-15
申请人： MITSUBISHI HEAVY IND LTD
发明人： SHIMOMURA MASAHITO , TSURUMAKI SHIGERU
IPC分类号： H01F1/12 , G03G9/083
摘要： PURPOSE:To obtain a lipophilic magnetic material to be used in a magnetic offset printing method by consisting said material of a specific polymer and magnetic powder and allowing a chemical bond to exist between the particle surface of the magnetic powder and the polymer molecule. CONSTITUTION:This magnetic material consists of the polymer which is solid at ordinary temp.-60 deg.C, has >=80 deg. contact angle with water and is soluble in a specific solvent and the magnetic powder. The chemical bond exists between the particle surface of the magnetic powder and the polymer molecule of this magnetic material for printing. More specifically, this material is dispersed into the solvent in which the polymer, i.e., the constituting component thereof is soluble and after the material is adhered to the image part on the surface of a magnetic drum, the drum is dried, by which the material can be fixed to the outside surface of the drum. In addition, the material does not wet with water even if the material contacts the damping water after fixing. Since the material has a sufficient property to retain lipophilic ink, the material is usable as the magnetic material even in a magnetic offset printing method.

7. 发明专利

JPS63144070A HYDROPHILIC MAGNETIC MATERIAL FOR PRINTING 失效
公开(公告)号：JPS63144070A
公开(公告)日：1988-06-16
申请号：JP29055286
申请日：1986-12-08
申请人： MITSUBISHI HEAVY IND LTD
发明人： SHIMOMURA MASAHITO
IPC分类号： B41M1/22 , H01F1/12
摘要： PURPOSE:To enhance fixability, by using a magnetic powder and a hydrophilic polymer as constituents of the title material and making chemical bonds be present between the particle surfaces of the powder and the molecules of the polymer. CONSTITUTION:A magnetic material used as a constituent of a hydrophilic magnetic material is a powder of a ferromagnetic material such as iron, cobalt, nickel and an alloy thereof, and the particle surfaces of the magnetic powder and molecules of a hydrophilic polymer are chemically bonded by covalent bonds, ion bonds, coordinate bonds or the like. The magnetic material is dispersed in a solvent in which the polymer is soluble, the dispersed liquid is supplied to the outer surface of a magnetic drum magnetized at magnetic body parts of the surface which correspond to non-image areas, and the solvent is removed by drying from the hydrophilic magnetic material adhered to the non-image areas, whereby fixation is completed. Separation between the magnetic powder and the polymer does not occur at the time of dispersion in the solvent or at the time of fixation on the outer surface of the magnetic drum, and the polymer bonded to the magnetic powder is solidified in the subsequent process of removal of the solvent by drying, resulting in a fixed condition.

8. 发明专利

JPS634844A ADSORBENT FOR CARBON MONOXIDE 失效
公开(公告)号：JPS634844A
公开(公告)日：1988-01-09
申请号：JP14623186
申请日：1986-06-24
申请人： MITSUBISHI HEAVY IND LTD
发明人： TSUNEYOSHI KIKUJI , SHIMOMURA MASAHITO
IPC分类号： C10K1/32 , B01D53/02 , B01D53/34 , B01D53/62 , B01J20/02 , B01J20/20 , B01J20/22 , C01B32/40
摘要： PURPOSE:To obtain the titled adsorbent free from the deterioration of performance even if repeating adsorption and desorption by using activated carbon and cuprous thiocyanate as the constitutional components. CONSTITUTION:Cuprous thiocyanate and a solvent (i.e. acetonitrile or the like) are mixed and stirred. Then dried activated carbon is added in 0.5-30 preferably 2-5 weight ratio for cuprous thiocyanate and stirred. Then the mixture is heated under reduced pressure to sufficiently distill the solvent, and an adsorbent being a solid for monoxide is obtained. The obtained adsorbent quickly adsorbs carbon monoxide under ordinary temp. and ordinary pressure, and adsorbed carbon monoxide can be desorbed by heating this adsorbent or decompressing it or reducing the partial pressure of a carbon monoxide. Therefore carbon monoxide can be easily separated from a gaseous mixture. Further the performance of this adsorbent is not deteriorated even if repeating adsorption and desorption.

9. 发明专利

JPS59147642A Carbon monoxide-conversion catalyst 失效
标题翻译：碳一氧化碳转化催化剂
公开(公告)号：JPS59147642A
公开(公告)日：1984-08-24
申请号：JP2347683
申请日：1983-02-15
申请人： Hiroshima Gas Kk , Mitsubishi Heavy Ind Ltd
发明人： ATSUKAWA MASUMI , NISHIMOTO KOREHIKO , SHIMOMURA MASAHITO , MANTSUKA YASUSHI , SAITOU MASAHIRO , MIHO TADANOBU , KANEMITSU TOSHINORI
IPC分类号： C01B3/16 , B01J23/74 , B01J23/745 , B01J23/78 , B01J23/80 , B01J23/86 , B01J23/88 , B01J27/02 , B01J27/055 , B01J27/20 , B01J35/02 , B01J35/04
CPC分类号： Y02P20/52
摘要： PURPOSE:To lessen the pressure-loss at a catalyst layer and to obtain a carbon monoxide-conversion catalyst capable of decreasing an energy cost required for transporting a conversion gas, by bringing the reforming gas into contact with the catalyst in a condition so as to make the flowing direction parallel to the catalyst surface. CONSTITUTION:A base material consisting of plural parallel plates, cylindrical or honeycomb-shaped base material are painted or impregnated with effective catalyst components consisting of Fe2O3-Cr2O3 or the like. The catalyst is brought into contact with a gaseous mixture contg. carbon monoxide and water in a condition so as to bring the flowing direction parallel to the catalyst surface to promote the reforming reaction. By this catalyst, the increase of a pressure loss in the lapse of time at the catalyst layer is prevented and the conversion rate of carbon monoxide can be improved.
摘要翻译：目的：为了减轻催化剂层的压力损失，得到能够降低输送转化气体所需的能量成本的一氧化碳转化催化剂，通过使重整气体与催化剂接触，使流动方向平行于催化剂表面。构成：由多个平行板，圆柱形或蜂窝状基材组成的基材由具有由Fe 2 O 3 -Cr 2 O 3等组成的有效催化剂组分涂漆或浸渍。使催化剂与气体混合物接触。一氧化碳和水，使流动方向平行于催化剂表面，促进重整反应。通过该催化剂，可以防止在催化剂层中经过时间的压力损失的增加，并且可以提高一氧化碳的转化率。

10. 发明专利

JPS59140290A Preparation of hydrocarbon 失效
标题翻译：油料的制备
公开(公告)号：JPS59140290A
公开(公告)日：1984-08-11
申请号：JP1376583
申请日：1983-02-01
申请人： Mitsubishi Heavy Ind Ltd
发明人： SHIMOMURA MASAHITO
IPC分类号： C07C1/06 , C07C1/00 , C07C67/00 , C10G2/00 , C10G3/00
CPC分类号： Y02P30/20
摘要： PURPOSE: To avoid accumulation of carbon on the surface of a catalyst and produce hydrocarbon consistently over a long period of time, by reacting carbon monoxide with hydrocarbon in a partly hydrogenated polycyclic condensed aromatic compd. in the presence of a catalyst.
CONSTITUTION: A mixed gas containing carbon monoxide and hydrogen is led into a suspension phase obtained by adding about 5W10% catalyst (e.g. Fe-Cu- ZnO-K
2 O catalyst, Ru-Al
2 O
3 catalyst or Fischer-Tropsch active ingredient- zeolite compound catalyst) to a partly hydrogenated polycyclic condensed aromatic compd. (e.g. tetralin, 1, 2, 3, 4-tetrahydrofluorene or dihydropyrene) and they are made to interact at about 250W500°C under a pressure of about 10W 100kg/cm
2 and at a GHSV of about 250W10,000h
-1 per volume of catalyst to synthesize hydrocarbon.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了避免碳在催化剂表面积累，长时间一致地生产碳氢化合物，通过在部分氢化的多环稠合芳烃化合物中使一氧化碳与烃反应。在催化剂存在下。构成：将含有一氧化碳和氢气的混合气体引入通过添加约5-10％催化剂（例如Fe-Cu-ZnO-K2O催化剂，Ru-Al 2 O 3催化剂或费 - 托活性成分 - 沸石化合物催化剂）至部分氢化的多环稠合芳族化合物。（例如四氢化萘，1,2,3,4,4-四氢芴或二氢苯乙烯），并使它们在约250-500℃，约10-100kg / cm 2的压力和约250℃的GHSV下相互作用 -10,000h -1，以体积的催化剂合成烃。

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