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    • 3. 发明专利
    • Storage battery device
    • 存储电池设备
    • JP2008166268A
    • 2008-07-17
    • JP2007314400
    • 2007-12-05
    • Kyushu UnivMazda Motor Corpマツダ株式会社国立大学法人九州大学
    • FUJITA HIROTERUKAI HIROYUKITAIO YOSHINORITAKAMI AKIHIDEISHIHARA TATSUKI
    • H01M10/05H01G9/035H01G11/22H01G11/32H01G11/38H01G11/52H01G11/58H01M10/0568H01M10/0569
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a storage battery device in which a capacity per weight is raised and an energy storing capability is remarkably increased.
      SOLUTION: As a material for a conductive material layer of a cathode 10, graphite, a carbon material having a laminated structure is used and as a material for a conductive material layer of an anode 12, an active carbon, a carbon material having a high specific surface area. A nonaqueous electrolyte solution 16 contains an organic electrolyte material of 1-n-butylpyridinium hexa fluoro phosphate (CgH
      14 F
      6 NP) and a solvent of propylene carbonate (PC) and ethyl methyl carbonate. An anion in the nonaqueous solution 16 is intercalated in between the layers of the cathode 10 and a cation adsorbs on an outermost surface of the anode 12 and as a result, a capacity per weight can be raised and an energy storing capability can be increased remarkably.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种蓄电池装置,其中每重量的容量升高并且能量存储能力显着增加。 解决方案:作为阴极10的导电材料层的材料,使用石墨,具有层压结构的碳材料,并且作为用于阳极12,活性炭,碳材料的导电材料层的材料 具有高比表面积。 非水电解质溶液16含有1-正丁基吡啶鎓六氟磷酸盐(CgH 14 6 NP)的有机电解质材料和碳酸亚丙酯(PC)和 碳酸甲乙酯。 非水溶液16中的阴离子插入在阴极10的层之间,阳离子吸附在阳极12的最外表面上,结果可以提高每重量的容量,并且能够显着提高能量存储能力 。 版权所有(C)2008,JPO&INPIT
    • 6. 发明专利
    • Production method of spherical phenolic resin granule, production method of carbon material, and production method of activated carbon material
    • 球形酚醛树脂生产方法,碳材料的生产方法和活性炭材料的生产方法
    • JP2013203783A
    • 2013-10-07
    • JP2012071599
    • 2012-03-27
    • Hiroshima Univ国立大学法人広島大学Mazda Motor Corpマツダ株式会社Gun Ei Chem Ind Co Ltd群栄化学工業株式会社
    • TAMAI HISASHIKAI HIROYUKITAIO YOSHINORITAKAMI AKIHIDEOGURA KAZUHIROKIMURA MASARUTANIOKA TOSHIYA
    • C08G8/00C01B31/02C01B31/08C08G8/20H01G11/22H01M4/587
    • Y02E60/13
    • PROBLEM TO BE SOLVED: To provide the production method of a spherical phenolic resin granule, by which the average particle diameter of fine spherical phenolic resin particles can be controlled and spherical phenolic resin particles can be efficiently recovered without performing centrifugal separation, and to obtain a fine spherical carbon material and an activated carbon material.SOLUTION: The production method of a spherical phenolic resin granule includes steps of: making phenols including polyvalent phenols be subjected to condensation reaction with aldehydes in the presence of a condensation catalyst in an aqueous medium to obtain a spherical phenolic resin dispersion liquid in which a spherical phenolic resin is dispersed; adding an organic coagulant to the spherical phenolic resin dispersion liquid to obtain a coagulated product; separating and recovering the coagulated product; drying the separated and recovered coagulated product to obtain a dried product; mixing the dried product with a binder to obtain a mixture; and granulating the mixture to obtain a granule. The production method of a carbon material using the above spherical phenolic resin granule, and the production method of an activated carbon material using the spherical phenolic resin granule are also disclosed.
    • 要解决的问题:为了提供球形酚醛树脂颗粒的制备方法,通过该球形酚醛树脂颗粒的球形酚醛树脂颗粒的平均粒径可以被控制,球形酚醛树脂颗粒可以在不进行离心分离的情况下有效地回收,并获得 细球形碳材料和活性炭材料。解决方案:球形酚醛树脂颗粒的制备方法包括以下步骤:使含酚多酚的酚在缩合催化剂存在下在水介质中与醛进行缩合反应,得到 分散有球形酚醛树脂的球形酚醛树脂分散液; 向球状酚醛树脂分散液中加入有机凝结剂,得到凝固物; 分离和回收凝结产物; 干燥分离回收的凝结物,得到干燥物; 将干燥产物与粘合剂混合以获得混合物; 并将混合物造粒以获得颗粒。 还公开了使用上述球形酚醛树脂颗粒的碳材料的制造方法和使用球形酚醛树脂颗粒的活性炭材料的制造方法。
    • 8. 发明专利
    • Carbonaceous material, storage battery having the same, and method for manufacturing the same
    • 碳质材料,具有该材料的储存电池及其制造方法
    • JP2010254537A
    • 2010-11-11
    • JP2009109668
    • 2009-04-28
    • Mazda Motor Corpマツダ株式会社
    • FUJITA HIROTERUKAI HIROYUKITAIO YOSHINORIMINEO SUSUMUISHIHARA TATSUKI
    • C01B31/04C01B31/08H01G11/02H01G11/06H01G11/22H01G11/30H01G11/32H01G11/42H01M4/587
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a carbonaceous material increasing the amount of intercalation of ion, when being used as a storage battery and achieving higher capacity of the storage battery.
      SOLUTION: The carbonaceous material has a layered structure, in which a plurality of amorphous parts are dispersed on a (002) plane and the average area of the amorphous parts is 1.5 nm
      2 or more. Alternatively, the carbonaceous material has the layered structure, in which a plurality of amorphous parts are dispersed on the (002) plane and the proportion of the total areas of amorphous parts in the (002) to the sum of areas of amorphous parts and crystalline parts in the (002) plane is 30% or more. Because of such a structure of the carbonaceous material, when the carbonaceous material is used, for example, as a storage battery, the amount of intercalation can be increased and the capacity can be increased.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供增加离子插入量的碳质材料,当用作蓄电池并实现更高容量的蓄电池时。 解决方案:碳质材料具有层状结构,其中多个非晶部分分散在(002)面上,非晶部分的平均面积为1.5nm 2 以上。 或者,碳质材料具有层状结构,其中多个非晶部分分散在(002)面上,并且(002)中的非晶部分的总面积与无定形部分和晶体的面积之和的比例 (002)面中的零件为30%以上。 由于碳质材料的这种结构,当使用碳质材料时,例如作为蓄电池,可以提高插层量,并且能够提高容量。 版权所有(C)2011,JPO&INPIT