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    • 8. 发明专利
    • Apparatus for removing so3 component in exhaust gas
    • 用于去除排气中SO3组分的装置
    • JP2003001054A
    • 2003-01-07
    • JP2001188405
    • 2001-06-21
    • Asahi Glass Co LtdMitsubishi Heavy Ind Ltd三菱重工業株式会社旭硝子株式会社
    • KATO MASAYAKATAYAMA HIROYUKIYADA KATSUTOSHIHIRANO HACHIROMORI YOICHIYAMAMOTO KAZUYOSHI
    • F23J15/00B01D53/34B01D53/50B01D53/77B01D53/81
    • B01D53/502B01D2251/304B01D2251/606B01D2257/302
    • PROBLEM TO BE SOLVED: To remove SO
      3 in an exhaust gas without causing a significant increase in the operation cost.
      SOLUTION: The concentration of SO
      3 in the exhaust gas is reduced by providing a sodium carbonate supplying device 20 for supplying sodium carbonate to the exhaust gas at the outlet of a boiler 1, and a SO
      3 -separating device 10 is provided for separating and removing the SO
      3 component from the exhaust gas at the inlet of a wet type desulfurization device 7. In the SO
      3 separating device 10, a shell and tube type heat exchanger is provided, and the exhaust gas and water to be supplied to the boiler are passed through the shell side and the tube side, respectively, so as to cool the temperature of the exhaust gas to a temperature lower than the dew point of gaseous H
      2 SO
      4 . With the lowering of the temperature of the exhaust gas, the SO
      3 component in the exhaust gas reacts with moisture in the exhaust gas and forms the gaseous H
      2 SO
      4 , and further, the formed H
      2 SO
      4 gas condenses and sticks on the surface of the tube. The SO
      3 component can be removed from the exhaust gas by washing liquid H
      2 SO
      4 stuck on the tube with water. Thereby, the consumption of sodium carbonate is markedly reduced and the increase in the cost for operating a plant is prevented.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:排除废气中的SO 3,而不会导致运行成本的显着增加。 解决方案:通过在锅炉1的出口处设置用于向排气中提供碳酸钠的碳酸钠供应装置20,排气中的SO 3浓度降低,并且提供SO 3分离装置10用于分离和除去 SO 3成分从湿式脱硫装置7的入口处的排气中排出。在SO 3分离装置10中,设置有壳管型热交换器,供给锅炉的废气和水通过 壳体侧和管侧,以将废气的温度降低到低于气态H 2 SO 4的露点的温度。 随着废气温度的降低,废气中的SO 3成分与废气中的水分反应,形成气态H 2 SO 4,此外,所形成的H 2 SO 4气体冷凝并粘附在管的表面上。 通过用水清洗粘在管上的H2 SO4液体可以将SO3组分从废气中除去。 因此,碳酸钠的消耗明显降低,并且防止了操作植物的成本的增加。