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    • 2. 发明专利
    • PHOTOELECTRIC CONVERSION ELEMENT
    • JPH1187064A
    • 1999-03-30
    • JP24271497
    • 1997-09-08
    • MITSUBISHI ELECTRIC CORP
    • NAGAE ISAMUFUJIMOTO TAKAMITSUHIZUKA YUJI
    • G03G5/07C08G77/14C08L101/12C09K19/38G02F1/13H05B33/12H05B33/14H05B33/22
    • PROBLEM TO BE SOLVED: To improve various characteristics of response speed, diffraction efficiency and luminous efficiency through improvement of the charge-mobility by forming a charge transfer layer of an organic compound out of a high molecular liquid crystal material, which has charge transfer ability using hopping conduction and the alignment of which is possible. SOLUTION: A positive electrode 1 of a metal such as Pt having a large work function or ITO or the like having high transparency, a charge transfer layer 2 obtained by dispersing a light emitting material in the organic compound and working as a light emitting layer, a negative electrode 3 consisting of a metal such as Ca, Li having a small work function and Ag or Al are laminated in order on a substrate 4 of transparent glass or the like so as to obtain a single-layer organic EL element as a photoelectric conversion element. At this stage, as a charge transfer layer 2, a high molecular liquid crystal material, which has charge transfer ability with hopping conduction and of which orientation is possible, is used. Degree of charge-transfer is improved by using this material in the aligned condition. As a high molecular liquid crystal material, discotic liquid crystal or rod-like liquid crystal is desirable.
    • 3. 发明专利
    • LIQUID CRYSTAL DISPLAY ELEMENT
    • JPH095754A
    • 1997-01-10
    • JP14907395
    • 1995-06-15
    • MITSUBISHI ELECTRIC CORP
    • TABATA SHINTSUMURA AKIRAMIZUNUMA MASAYATAMAYA AKIRAFUJIMOTO TAKAMITSU
    • G02F1/1337
    • PURPOSE: To obtain a wide visual angle by adding an optically active compd. which gives a helical structure to the orientation of liquid crystal molecules of a liquid crystal having negative dielectric anisotropy, forming a liquid crystal layer and orienting the liquid crystal molecules perpendicular to the plane of an orienting film. CONSTITUTION: Orienting films 23, 27 are formed by applying org. silane compd. films on transparent electrodes 22, 26 formed on glass substrates 21, 25, respectively. These substrates are disposed with the orienting films 23, 27 facing each other to form a space, and a liquid crystal layer 32 is held in this space to constitute a liquid crystal cell 34. This liquid crystal layer is prepared by adding an optically active compd. which gives a helical structure to the orientation of liquid crystal molecules, for example, by adding cholesterisnonate by 2%, to a liquid crystal material having negative dielectric anisotropy. Further, polarizing plates 28, 29 with the polarization directions perpendicular to each other are disposed on the both sides of the liquid crystal cell 34 to obtain a liquid crystal element 35. The liquid crystal molecules in the liquid crystal layer 32 are oriented perpendicular to the film plane of the orienting films 23, 27. Thereby, when enough voltage is applied, the liquid crystal molecules are released from the control of the orienting films so that the orienting axes of liquid crystal molecules are randomly distributed in the plane parallel to the substrate plane.