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1. 发明专利

JP2002097224A PHOTOSETTING COMPOSITION AND ITS CURED PRODUCT 失效
公开(公告)号：JP2002097224A
公开(公告)日：2002-04-02
申请号：JP2000292460
申请日：2000-09-26
申请人： MITSUBISHI CHEM CORP
发明人： CHOKAI TAKASHI , MIKI YASUAKI , TAMURA YUTAKA , HAYAKAWA SEIICHIRO
IPC分类号： C08F2/44 , C08F2/50 , C08F20/38 , C08F290/06 , C08F299/02 , C08K5/04 , C08K5/3475 , C08L33/14 , C09D5/00 , C09D181/00 , C09D181/02 , C09J181/00 , C09J181/02 , G02B1/04 , G02B1/10 , G02B1/111
摘要： PROBLEM TO BE SOLVED: To provide a composition of which the good curability is obtained by the irradiation of an active energy rays such as ultraviolet rays and the physical properties of a cured product are high reflective index and high transparency, and the weather resistance of an optical material is good. SOLUTION: The photosetting composition is characterized by containing (A) a sulfur-containing (meth)acrylate compound represented by the formula (I) or a radical reactive composition containing the compound, (B) an ultraviolet absorbent, (C) an antioxidant and (D) a polymerization initiator.

2. 发明专利

JPH10167836A BINDER RESIN FOR COMPACTING CERAMIC 失效
公开(公告)号：JPH10167836A
公开(公告)日：1998-06-23
申请号：JP33701296
申请日：1996-12-17
申请人： MITSUBISHI CHEM CORP
发明人： CHOKAI TAKASHI , TODA ATSUSHI
IPC分类号： C04B35/632 , C08F220/12
摘要： PROBLEM TO BE SOLVED: To ensure satisfactory stability of a slurry and to obtain a high strength superior compact by using a resin obtd. by copolymerizing isobutyl methacrylate with 2-ethylhexyl methacrylate and methacrylic ester. SOLUTION: This binder resin is made of a methacrylic ester copolymer obtd. by copolymerizing 60-99wt.% isobutyl methacrylate with 1-39wt.% 2- ethylhexyl methacrylate and 1-15wt.% methacrylic ester having a hydroxyl group at the β- or ω-position. The methacrylic ester is preferably 2-hydroxyethyl methacrylate and moderate flexibility is imparted to a green sheet. The wt. average mol.wt. of the copolymer is about 10,000-1,500,000, preferably about 150,000-350,000. A green sheet using this binder resin has superior formability.

3. 发明专利

JP2003176332A HETEROCYCLE-CONTAINING COMPOUND AND COMPOSITION CONTAINING THE SAME 审中-公开
公开(公告)号：JP2003176332A
公开(公告)日：2003-06-24
申请号：JP2001378878
申请日：2001-12-12
申请人： MITSUBISHI CHEM CORP
发明人： UTSU HIROMI , CHOKAI TAKASHI , MIKI YASUAKI
IPC分类号： G02B1/04 , C08G59/04 , C08G75/08 , C09J163/00 , C09J181/00 , C09J201/02
摘要： PROBLEM TO BE SOLVED: To provide a compound and a composition suitably used for adhesives, coatings and resin molded products and a cured product of the composition suitably used for optical members. SOLUTION: This heterocycle-containing compound is represented by general formula (I). COPYRIGHT: (C)2003,JPO

4. 发明专利

JPH09169846A CURABLE COMPOSITION AND COATING AGENT 失效
公开(公告)号：JPH09169846A
公开(公告)日：1997-06-30
申请号：JP27078096
申请日：1996-10-14
申请人： MITSUBISHI CHEM CORP
发明人： TANAKA TOSHIYUKI , TODA ATSUSHI , YAMAOKA HIROAKI , CHOKAI TAKASHI
IPC分类号： C08G77/14 , C08G77/22 , C08K5/54 , C08K5/5419 , C08L83/04 , C08L83/06 , C09D133/00 , C09D133/04 , C09D183/04 , C09D183/06
摘要： PROBLEM TO BE SOLVED: To obtain a curable compsn. improved in hardness, clarity, adhesive properties, resistances to chemicals and solvents, storage stability of the soln., and softness by compounding an alkoxysilane, a silane coupling agent, water, an org. solvent, and a catalyst and specifying the water content. SOLUTION: This curable compsn. is prepd. by compounding a tetraalkoxysilane represented by the formula: R n Si(OR )4-n (wherein R and R are each a 1-20C alkyl; and (n) is 1-3)(e.g. tetramethoxysilane) and/or its oligomer formed by its hydrolysis and condensation (A), an epoxidized silane coupling agent such as represented by formula I or II (wherein R is methyl or ethyl)(B) in a wt. ratio to component A of (10:1)-(1:10), at least one org. solvent (C) selected from among an alcohol, a glycol, a hydrocarbon, an ester, a ketone, an ether, etc., (C) in a wt. ratio to component A of 0.5-10, a catalyst (e.g. an inorg. or org. acid or an alkali catalyst), water in an amt. theoretically capable of hydrolyzing and condensing 40-75% of component A, and, if necessary, an acrylic resin.

5. 发明专利

JPH07150106A COATING COMPOSITION 失效
公开(公告)号：JPH07150106A
公开(公告)日：1995-06-13
申请号：JP29677293
申请日：1993-11-26
申请人： NIPPON SYNTHETIC CHEM IND , MITSUBISHI CHEM CORP
发明人： YAMAOKA HIROAKI , CHOKAI TAKASHI , OTA TAKAYUKI
IPC分类号： C09D133/14 , C09D133/04 , C09D163/00 , C09D183/04
摘要： PURPOSE:To obtain a coating composition excellent in scratch resistance, adhesion, storage stability, etc. CONSTITUTION:This composition comprises 5-85wt.%, based on the resin component, silicate oligomer represented by the formula (wherein n is an integer of 1-20; and R is 1-4 C alkyl or phenyl), 15-95 pts.wt., based on the resin component, acrylic copolymer comprising an epoxy (meth)acrylate and (meth)acrylic acid and 10-400 pts.wt., per 100 pts.wt. resin component, organic solvent.

6. 发明专利

JP2003231682A HETEROCYCLE-CONTAINING COMPOUND AND COMPOSITION THEREOF 审中-公开
公开(公告)号：JP2003231682A
公开(公告)日：2003-08-19
申请号：JP2002029607
申请日：2002-02-06
申请人： MITSUBISHI CHEM CORP
发明人： UTSU HIROMI , CHOKAI TAKASHI , MIKI YASUAKI
IPC分类号： C07D331/02 , C07D303/27 , C08G59/20
摘要： PROBLEM TO BE SOLVED: To obtain a heterocycle-containing compound, a curable composition comprising the compound and a resin material having a high refractive index and photo-setting and thermosetting properties. SOLUTION: The heterocycle-containing compound is represented by formula (1) [wherein, R 1 to R 4 denote each independently a 1-10C bivalent hydrocarbon group; X 1 to X 4 denote each independently 0 or S; Y 1 and Y 2 denote each independently 0 or S; (m), (n), (p) and (q) denote each independently an integer of 0-10; (r) denotes an integer of 0-10; and Z 1 and Z 2 denote each independently a bivalent aryl group which may have a substituent, except that (p), (q) and (r) are each 0, Y 1 and Y 2 are each 0 or S; and Z 2 is C 6 H 4 ]. COPYRIGHT: (C)2003,JPO

7. 发明专利

JP2001329020A METHOD FOR MANUFACTURING AMINO GROUP CONTAINING COPOLYMER 失效
公开(公告)号：JP2001329020A
公开(公告)日：2001-11-27
申请号：JP2000154115
申请日：2000-05-25
申请人： MITSUBISHI CHEM CORP , NIPPON SYNTHETIC CHEM IND
发明人： AOYAMA MASATO , CHOKAI TAKASHI , TANAKA TOSHIYUKI
IPC分类号： C08F8/12
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing an amino group containing copolymer easily at a high yield by effectively hydrolyzing a precursor of the copolymer. SOLUTION: A copolymer comprising a repeating unit represented by the following general formulas (I) and (II) (wherein R and R' are each independently a hydrogen atom, an alkyl group or an aryl group) is suspended in a solvent mixture comprising isopropyl alcohol and a compound having a boiling point of >=70 deg.C and a solubility parameter of >=25 (MPa)1/2 and is hydrolyzed into this amine functional copolymer.

8. 发明专利

JPH0827421A COMPOSITION FOR SPIN COATING 失效
公开(公告)号：JPH0827421A
公开(公告)日：1996-01-30
申请号：JP16224894
申请日：1994-07-14
申请人： MITSUBISHI CHEM CORP
发明人： YAMAMOTO MASAKI , TODA ATSUSHI , CHOKAI TAKASHI
IPC分类号： B05D1/40 , B05D7/24 , C08G77/02 , C09D183/00 , C09D183/02 , G11B7/24 , G11B7/254 , G11B7/257 , H01L21/027 , H01L21/316
摘要： PURPOSE:To obtain a composition for spin coating, consisting essentially of a tetraalkoxysilane (a partial hydrolyzate), an organic solvent having a specific boiling point, water and an organic carboxylic acid, good in preservation stability and capable of providing a film having a flat surface without any striation. CONSTITUTION:This composition for spin coating consists essentially of (A) a tetraalkoxysilane (e.g. tetramethoxysilane) and/or its partial hydrolyzate, (B) an organic solvent having 110-170 deg.C boiling point (e.g. 2-ethoxyethanol), (C) water and (D) an organic carboxylic acid (e.g. maleic acid). The composition for the spin coating is obtained by mixing the tetraalkoxysilane (a partial hydrolyzate) with the organic solvent, stirring the resultant mixture at ambient temperature, uniformly dissolving the tetraalkoxysilane therein, then adding water and organic carboxylic acid thereto in the order, stirring the prepared mixture until the organic carboxylic acid is dissolved and subsequently allowing the resultant solution to stand at ambient temperature for 4 days. Thereby, the composition for the spin coating is good in preservation stability of the liquid and capable of providing a silica film having an extremely small dispersion in thickness and a flat surface without any striation.

9. 发明专利

JPH07286136A COMPOSITION FOR FORMING SILICA-BASED COATING FILM 失效
公开(公告)号：JPH07286136A
公开(公告)日：1995-10-31
申请号：JP8027894
申请日：1994-04-19
申请人： MITSUBISHI CHEM CORP
发明人： CHOKAI TAKASHI , YAMAMOTO MASAKI , TODA ATSUSHI
IPC分类号： C09D183/02 , C09D183/00
摘要： PURPOSE:To provide a composition for forming a silica-based coating film useful as an electrical insulating coating material, etc., having excellent storage stability, formability of thick film, transparency of coating film, hardness and cracking resistance, comprising a specific silane hydrolyzate, an alcohol, a mixture of organic carboxylic acids and water. CONSTITUTION:This composition comprises (A) a partial hydrolyzate of tetramethoxysilane having

10. 发明专利

JP2003267960A METHOD FOR PRODUCING EPOXY COMPOUND 审中-公开
公开(公告)号：JP2003267960A
公开(公告)日：2003-09-25
申请号：JP2002066482
申请日：2002-03-12
申请人： MITSUBISHI CHEM CORP
发明人： UTSU HIROMI , CHOKAI TAKASHI , MIKI YASUAKI
IPC分类号： C07D301/28 , C07B61/00 , C07D303/26 , C07D303/27
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an epoxy compound having a cyclic hydrocarbon group in high yield by a one-stage reaction. SOLUTION: The method for producing the epoxy compound comprises reacting a polyhydric alcohol represented by general formula (I), etc., (wherein, a, b and c denote each independently an integer of 0-2; and m and n denote each independently an integer of 0-10) and having the cyclic hydrocarbon group with an epihalohydrin in the presence of a base. In the method, the reaction is carried out in the presence of a phase transfer catalyst. COPYRIGHT: (C)2003,JPO

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