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1. 发明专利

JPS6119066A Manufacture of battery 失效
标题翻译：电池制造
公开(公告)号：JPS6119066A
公开(公告)日：1986-01-27
申请号：JP13840984
申请日：1984-07-04
申请人： Matsushita Electric Ind Co Ltd
发明人： OKAZAKI RIYOUJI , YANAGIHARA NOBUYUKI , GAMOU KOUJI , TAKADA KANJI , MIURA AKIRA
IPC分类号： H01M6/06 , H01M4/38 , H01M4/62 , H01M6/50 , H01M10/52
CPC分类号： H01M10/52 , H01M6/50
摘要： PURPOSE:To obtain a primary battery having high reliability, good performance, and low environmental problem by assembling a hydrogen absorption alloy which absorption and desorption of hydrogen were performed at least once before assembling in a battery. CONSTITUTION:A hydrogen absorption alloy is crushed in an atmosphere of argon in powder having a particle size of 10-100mum. About 1wt% fluorine resin having a particle size of 1mum or less is added to the hydrogen absorption alloy and stirred to give water repellent property to the alloy. The alloy powder is degassed under vacuum at about 200 deg.C, and hydrogen is absorbed into the alloy to nearly saturation at a pressure of 30atm. at room temperature, then hydrogen is completely removed by vacuum. The alloy which absorption and desorption of hydrogen were performed at least once is assembled in a battery. Thereby, a primary battery having high reliability, good performance, and low environmental problem is obtained.
摘要翻译：目的：通过组装氢吸收合金，在组装电池前至少进行一次氢的吸收和解吸，获得具有高可靠性，良好性能和低环境问题的一次电池。构成：将氢吸收合金在氩气气氛中粉碎，粉末粒度为10-100μm。将大约1重量％的粒径为1μm以下的氟树脂加入到吸氢合金中并搅拌以赋予合金防水性。合金粉末在约200℃真空下脱气，氢气在30atm的压力下吸收到合金中几乎饱和。在室温下，通过真空完全除去氢。进行至少一次氢的吸收和解吸的合金被组装在电池中。从而获得具有高可靠性，良好性能和低环境问题的一次电池。

2. 发明专利

JPS60226677A INTERMITTENT OPERATION TYPE MULTISTAGE DOUBLE EFFECT COOLINGDEVICE 失效
公开(公告)号：JPS60226677A
公开(公告)日：1985-11-11
申请号：JP8220384
申请日：1984-04-24
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： TAKESHITA ISAO , GAMOU KOUJI , MORIWAKI YOSHIO , YANAGIHARA NOBUYUKI
IPC分类号： F25B17/12 , F25B23/00

3. 发明专利

JPS6046901A METHOD FOR RELEASING STORED HYDROGEN GAS 失效
公开(公告)号：JPS6046901A
公开(公告)日：1985-03-14
申请号：JP13819784
申请日：1984-07-03
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： YANAGIHARA NOBUYUKI , GAMOU KOUJI , MORIWAKI YOSHIO , IWAKI TSUTOMU
IPC分类号： F17C9/02 , C01B3/00 , F17C7/00 , F17C11/00
摘要： PURPOSE:To release stored hydrogen gas efficiently, with reduced heat quantity of the external heat source, by storing the heat generated in the occlusion of hydrogen in a hydrogen occlusion alloy temporarily in a heat storage vessel, and releasing the hydrogen by the combined use of the stored heat and the heat of the external assistant heat source. CONSTITUTION:The valve 8 connected to the hydrogen storage vessel 1 filled with granular hydrogen occlusion alloy 2 is closed, the valve 7 is opened to evacuate the hydrogen storage vessel 1, and hydrogen gas is introduced into the hydrogen storage vessel 1 through the filter 9 to effect the occlusion of the hydrogen gas in the hydrogen occlusion alloy 2. The heat of occlusion generated by this process is stored in the heat medium 15 in the heat storage vessel 11 by circulating the heat medium in the pipe 4 by the aid of the heat exchanger 10 in the hydrogen storage vessel 1 and the heat exchanger 12 in the heat storage vessel 11. The occluded hydrogen can be released by closing the valve 7, opening the valve 8, heating the heat medium 15 with electrical heater 17 connected to the electrical source 18, circulating the heat transferred from the external heat source and the heat stored in the heat medium by the pump 13, and using the heat for the heating of the hydrogen occlusion alloy 2.

4. 发明专利

JPS6044781A HEAT PUMP TYPE HOT-WATER SUPPLY INSTRUMENT UTILIZING METALLIC HYDRIDE 失效
公开(公告)号：JPS6044781A
公开(公告)日：1985-03-09
申请号：JP15348983
申请日：1983-08-22
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： GAMOU KOUJI , MORIWAKI YOSHIO , TAGASHIRA MINORU , MITSUMATA TADAYASU
IPC分类号： F25B17/12 , F25B17/00 , F25B23/00

5. 发明专利

JPS58207353A Hydrogen storing material 失效
标题翻译：氢储存材料
公开(公告)号：JPS58207353A
公开(公告)日：1983-12-02
申请号：JP8902882
申请日：1982-05-25
申请人： Matsushita Electric Ind Co Ltd
发明人： GAMOU KOUJI , MORIWAKI YOSHIO , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： C22C22/00 , C01B3/00
CPC分类号： Y02E60/327
摘要： PURPOSE: To obtain a hydrogen storing ternary material increasing the maximum amount of hydrogen to be occluded at room temp. and having enhanced stability and operational performance, by adding a small amount of Mg to a Ti-Mn alloy.
CONSTITUTION: This hydrogen storing material consists of ≤8wt% Mg, 32W 48wt% Ti and the balance Mn. The ternary alloy material forms hardly an oxide layer or a nitride layer at ordinary temp. The alloy absorbs gaseous hydrogen rapidly, easily and almost independently of impurities in the hydrogen, and it releases high purity gaseous hydrogen. In stages for occluding and releasing gaseous hydrogen, the quantities of heat of formation of metallic hydride and heat of decomposition of it are small.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：获得在室温下吸收最大氢气量的储氢三元材料。并且通过向Ti-Mn合金中添加少量的Mg而具有增强的稳定性和操作性能。构成：该储氢材料由<= 8wt％Mg，32-48wt％Ti和余量Mn组成。三元合金材料在常温下几乎不形成氧化物层或氮化物层。该合金快速，容易且几乎独立于氢中的杂质吸收气态氢，并释放出高纯度的气态氢。在用于封闭和释放气态氢的阶段中，金属氢化物的形成热量和其分解热量很小。

6. 发明专利

JPS58181701A Method for handling hydrogen storing metallic material 失效
标题翻译：处理氢储存金属材料的方法
公开(公告)号：JPS58181701A
公开(公告)日：1983-10-24
申请号：JP6372782
申请日：1982-04-15
申请人： Matsushita Electric Ind Co Ltd
发明人： MORIWAKI YOSHIO , GAMOU KOUJI , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： C01B3/00 , B01J20/02 , F17C11/00
CPC分类号： C01B3/0005 , Y02C10/08 , Y02E60/321 , Y02E60/327 , Y02P30/30
摘要： PURPOSE: To handle an H
2 storing metallic material contg. occluded H
2 without deteriorating the performance by dehydrogenating the material in a vessel and bringing it into contact with CO
2 or a gaseous mixture of CO
2 with an inert gas to cover the surface of the metallic material with CO
2 by adsorption.
CONSTITUTION: A vessel 2 holding an H
2 storing metallic material 1 contg. occluded H
2 is evacuated by opening a valve 6 of the exhaust port 5 of the vessel 2 to dehydrogenate the material 1. A valve 9 of the inlet 8 for a gas for adsorption is then opened to introduce CO
2 or a gaseous mixture of CO
2 with an inert gas into the vessel 2 under ≥2kg/cm
2 pressure, and by keeping the state for ≥30min, the surface of the material 1 is covered with CO
2 by adsorption. The material 1 is taken out of the vessel 2, and it is transferred to other vessel and preserved.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：处理H2储存金属材料封闭的H2，而不会使容器中的材料脱氢而使性能下降，并使其与CO 2或CO 2与惰性气体的气体混合物接触，以通过吸附用CO 2覆盖金属材料的表面。构成：容纳H2储存金属材料的容器2，通过打开容器2的排气口5的阀6将吸入的H 2抽真空，使材料1脱氢。然后打开用于吸附气体的入口8的阀9，以将CO 2或CO 2的气体混合物与惰性气体在≥2kg/ cm 2压力下进入容器2，通过保持> = 30min的状态，材料1的表面通过吸附被CO 2覆盖。将材料1从容器2中取出，并将其转移到其他容器中并保存。

7. 发明专利

JPS5819456A MATERIAL FOR REVERSIBLY ABSORBING AND RELEASING HYDROGEN 失效
公开(公告)号：JPS5819456A
公开(公告)日：1983-02-04
申请号：JP11574781
申请日：1981-07-23
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： GAMOU KOUJI , UCHINO HIDEO , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： C22C16/00 , C01B3/00 , C22C22/00
摘要： PURPOSE:To obtain the titled material capable of arbitrarily controlling and keeping the pressure of H2 in a vacuum apparatus by means of the surrounding temp. and the residual H2 content by specifying the atomic ratio of Mn to Zr in a Zr-Mn alloy. CONSTITUTION:The titled material is an alloy represented by the formula (where x is 0.01-0.18). The material is somewhat viscous, it does not ignite even after repeating H2 absorption and release, and it shows well the expected performance in the form of lumps without requiring pulverization prior to use. The Zr-Mn alloy is homogeneously solubilized at >=about 1860 deg.C and can be manufactured by an arc melting method. In case of x =about 90% beta-Zr phase is required. In case of x>0.18, the amount of intermetallic compound ZrMn2 phase is increased, so H2 is absorbed at a lower temp. under a much lower pressure of H2, yet H2 is released under a relatively high pressure. In case of X

8. 发明专利

JPS5816046A MATERIAL FOR REVERSIBLY ABSORBING AND RELEASING HYDROGEN 失效
公开(公告)号：JPS5816046A
公开(公告)日：1983-01-29
申请号：JP11473281
申请日：1981-07-22
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： GAMOU KOUJI , MORIWAKI YOSHIO , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： C22C16/00 , C01B3/00 , C22C27/02
摘要： PURPOSE:To obtain the titled material capable of arbitrarily controlling and keeping the pressure of H2 in a vacuum apparatus by means of the surrounding temp. and the residual H2 content by specifying the atomic ratio of a Zr-V alloy. CONSTITUTION:This material is an alloy represented by a general formula ZrVx (where x is 0.01-0.28). The alloy is somewhat viscous, it does not ignite in air even after repeating H2 absorption and release, and it shows well the expected performance in the form of lumps without requiring pulverization prior to use. A Zr-V alloy is homogeneously solubilized by heating to >=1,860 deg.C, and the alloy having the desired composition is easily obtd. by an Ar arc melting method or other method. The Zr-V alloy of this purpose is required to have >=90mol% beta- Zr phase, so the value of x is restricted to said range. When the value of x exceeds the upper limit, H2 is absorbed at a lower temp. under a much lower pressure of H2, yet H2 is released under a relatively high pressure. When the value of x is blow the lower limit, H2 is not almost absorbed at

9. 发明专利

JPS57182051A VACUUM PIPE TYPE SOLAR HEAT COLLECTOR 失效
公开(公告)号：JPS57182051A
公开(公告)日：1982-11-09
申请号：JP6735281
申请日：1981-05-02
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： MITSUATO TADAYASU , GAMOU KOUJI , UCHINO HIDEO , YOSHINO MASAAKI , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： F24S10/70 , F24S10/40
摘要： PURPOSE:To improve the efficiency, reliability and lifetime of the titled heat collector by a method wherein a metal hydride is sealed in a vacuum glass pipe which incorporates therein a heat collecting plate coated with a selective adsorption film and a heat medium pipe. CONSTITUTION:A U-shaped heat medium pipe 2 is disposed within a transparent soda glass pipe 1 and the heat collecting plate 5 coated with the selective adsorption film consisting of black chromium is also arranged in the pipe 1 in direct contact with the heat medium pipe 2. Further, a porous vessel 8 including therein a metal hydride such as NaH which is capable of discharging and adsorbing hydrogen in a reversible fashion is also provided in the glass pipe 1. The glass pipe 1 is then made vacuum and a predetermined quantity of hydrogen gas is put into the glass pipe 1. With the above structure, the hydrogen adsorbed by a hydrogen occluding alloy of which the porous vessel is made is discharged from the alloy due to a rise in temperature at the time of dry burning to thereby increase heat loss, so that the rising of the temperature of the heat collector and the deterioration of the selective adsorption film on the heat collecting plate 5 are prevented.

10. 发明专利

JPS57156308A PURIFYING METHOD OF NITROGEN GAS 失效
公开(公告)号：JPS57156308A
公开(公告)日：1982-09-27
申请号：JP3998181
申请日：1981-03-18
申请人： MATSUSHITA ELECTRIC IND CO LTD
发明人： MORIWAKI YOSHIO , GAMOU KOUJI , YANAGIHARA NOBUYUKI , IWAKI TSUTOMU
IPC分类号： B01J20/02 , C01B21/04
摘要： PURPOSE:To obtain N2 gas of high purity and good quality at a low cost, by passing a raw material N2 gas through a vessel packed with an alloy powder capable of occluding hydrogen or a powder prepared by dehydrogenating the hydrogenated alloy powder. CONSTITUTION:An alloy capable of occluding hydrogen, e.g. Ti-Mn, Ti-Fe or rare earth - Ni, is mechanically pulverized or hydrogenated in a high pressure hydrogen atmosphere to give a metallic hydride, which is then dehydrogenated to give an alloy hydride powder 2 for adsorbing a gas. The resultant hydride powder 2 is then packed in a powder holding vessel 1 having openings, and filters 3 for the powder scattering consisting of a sintered metal having a fine pore diameter are placed on the openings. A raw material N2 gas containing impurities, e.g. O2, CO, CO2, CH4, H2O, is introduced from one of the openings and purified. The hydride powder adsorbing the impurities is degassed under heating and can be regenerated without deteriorating the adsorbing characteristics.

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