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    • 5. 发明专利
    • Nozzle for continuous casting and method for manufacturing the same
    • 用于连续铸造的喷嘴及其制造方法
    • JP2010005662A
    • 2010-01-14
    • JP2008167836
    • 2008-06-26
    • Kurosaki Harima Corp黒崎播磨株式会社
    • MORIKAWA KATSUMISASAKI AKINARIHAREN KOICHIYOSHITOMI TAKENORIHIRAIWA YOSHITAKA
    • B22D11/10B22D41/50B22D41/54
    • PROBLEM TO BE SOLVED: To provide a nozzle for continuous casting in which durability is enhanced by arranging a refractory layer of high performance, e.g., high corrosion resistance or high adhesion preventive properties, on the inner hole side, and to provide a method for manufacturing a nozzle for continuous casting in which push breaking of the outer circumferential side layer due to the difference in thermal expansion between the inner hole side layer and the outer circumferential side layer of body material is prevented, and exfoliation of the inner hole side layer in the way of casting is prevented. SOLUTION: The nozzle for continuous casting has such an integral structure as the boundary portion of the inner hole side layer 2 and an intermediate layer 4 touches the boundary portion of the intermediate layer 4 and the outer circumferential side layer 3 directly wherein the bonding strength of the intermediate layer and the inner hole side layer and the outer circumferential side layer adjoining the intermediate layer is 0.01 to 1.5 Mpa in a 1,000°C non-oxidizing atmosphere, and a compression rate K(%) of the intermediate layer in the 1,000°C non-oxidizing atmosphere under the pressure of 2.5 Mpa is 10% to 80%. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种连续铸造用喷嘴,其通过在内孔侧配置高性能的耐火材料层(例如高耐腐蚀性或高附着力的性能)来提高耐久性,并提供一种 制造连续铸造用喷嘴的方法,其中防止由于内部空间侧层和主体材料的外周侧层之间的热膨胀差导致的外周侧层的推压断裂,并且内孔侧的剥离 防止了铸造方式的层。 解决方案:用于连续铸造的喷嘴具有与内孔侧层2的边界部分一样的一体结构,中间层4直接接触中间层4和外周侧层3的边界部分,其中, 在1000℃非氧化性气氛中,中间层与邻接中间层的内壁侧层和外周侧层的接合强度为0.01〜1.5Mpa,中间层的压缩率K(%)为 压力为2.5Mpa的1000℃非氧化性气氛为10%〜80%。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Refractory raw material coated with nanocarbon, its manufacturing method, refractory using the same and manufacturing method of refractory
    • 用纳米碳制造的原料原料,其制造方法,使用该制造方法的制造方法和制造方法
    • JP2008133177A
    • 2008-06-12
    • JP2007277550
    • 2007-10-25
    • Kurosaki Harima Corp黒崎播磨株式会社
    • HOKII TOSHIYUKIYOSHITOMI TAKENORISURUGA TOSHIHIROMORIKAWA KATSUMIMOCHIDA ISAOIN SEIKO
    • C04B35/628C01B31/02C04B35/043C04B35/103F27D1/00
    • PROBLEM TO BE SOLVED: To provide a refractory raw material and its manufacturing method where the uniform dispersion of carbon nanotubes (CNT) or carbon nanofibers (CNF) can be relatively easily performed in a refractory and where the refractory excellent in thermal shock resistance and slag resistance can be achieved and to provide a refractory using the refractory raw material and its manufacturing method. SOLUTION: The refractory raw material coated with nanocarbon where the surface of refractory raw material particles 1 is coated with CNT or CNF is manufactured by supporting a catalyst on the refractory raw material particles and by heat-treating the resultant refractory raw material particles under the contact with a carbon compound. The refractory raw material coated with nanocarbon is blended with a refractory raw material by 1-30 mass% to form a refractory raw materila composition. The refractory composition is added with an organic binder, kneaded and heat-treated after molding, to thereby prepare a refractory containing nanocarbon. COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:为了提供耐火材料及其制造方法,其中可以相对容易地在耐火材料中进行碳纳米管(CNT)或碳纳米纤维(CNF)的均匀分散,并且耐热性优异的耐火材料 可以实现电阻和耐渣性,并提供使用耐火材料的耐火材料及其制造方法。 解决方案:通过将耐火材料颗粒上的催化剂负载并且对所得到的耐火材料颗粒进行热处理,制造涂覆有耐火材料颗粒1的表面涂覆有CNT或CNF的纳米碳的耐火材料 与碳化合物接触。 将涂覆有纳米碳的难熔原料与耐火原料共混1-30质量%以形成耐火材料原料组合物。 向耐火材料组合物中添加有机粘合剂,在成型后进行捏合和热处理,由此制备含有纳米碳的耐火材料。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Oxidation resistance evaluating method of carbon-containing refractory
    • 含碳耐火材料的氧化电阻评估方法
    • JP2009204594A
    • 2009-09-10
    • JP2008050183
    • 2008-02-29
    • Kurosaki Harima Corp黒崎播磨株式会社
    • AKAMINE KEIICHIROSURUGA TOSHIHIROYOSHITOMI TAKENORI
    • G01N17/00B22D11/10B22D41/32
    • PROBLEM TO BE SOLVED: To provide an oxidation-resistance evaluating method of carbon-containing refractory for obtaining evaluation similar to the evaluation in an actual furnace.
      SOLUTION: The carbon-containing refractory (evaluation sample 11) for evaluating the oxidation resistance is lined on a side wall of an inner wall of a reaction vessel 5 of a high frequency induction furnace 1, the evaluation sample 11 is brought into contact with molten iron 10 of low carbon iron, and the molten iron 10 is stirred by a stirring tool 2. The oxygen concentration in the molten iron is measured by an oxygen sensor 3. When the oxygen concentration is high, carbon, aluminum or the like is added to the molten iron 10, and is made to react with oxygen, thereby controlling the oxygen concentration in the molten iron. After a lapse of a predetermined time, the thickness of a decarbonized layer of an iron bath section of the evaluation sample 11 is measured.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供与实际炉中的评价类似的含碳耐火材料的耐氧化性评价方法。 解决方案:将用于评价耐氧化性的含碳耐火材料(评价试料11)排列在高频感应炉1的反应容器5的内壁的侧壁上,将评价试料11 与低碳铁的铁水10接触,通过搅拌工具2搅拌铁水10.铁氧中的氧浓度由氧传感器3测定。当氧浓度高时,碳,铝或 加入到铁水10中,与氧反应,从而控制铁水中的氧浓度。 经过预定时间后,测量评估样品11的铁浴部分的脱碳层的厚度。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Tundish for continuous casting
    • 连续铸造用TUNDISH
    • JP2003326340A
    • 2003-11-18
    • JP2002134653
    • 2002-05-09
    • Kurosaki Harima Corp黒崎播磨株式会社
    • SHIMIZU KOICHIHOKII TOSHIYUKIOGATA KOJIYOSHITOMI TAKENORIASANO KEISUKE
    • B22D11/10B22D41/02C04B35/043
    • PROBLEM TO BE SOLVED: To reduce Al 2 O 3 base inclusion in molten steel, to restrain mechanical spalling of a refractory and to easily use the hot-rotation in a tundish used for continuously casting a metal especially, a steel. SOLUTION: Since an increase in wearing with the mechanical spalling of the refractory in the case of using MgO-CaO base refractory as the refractory for tundish has a deep dependence with a load softening characteristic of the refractory, when the refractory is held to 5 hours under condition of 0.2 MPa compression stress at 1550°C near the average using temperature of the tundish, the refractory shrunk at 1-10% in the loaded direction is applied to a lining material of the tundish and/or a weir and thus, the stress caused by thermal expansion is absorbed and the occurrence of the mechanical spalling can remarkably be restrained. COPYRIGHT: (C)2004,JPO
    • 要解决的问题:为了减少钢水中的Al 2 3 基体夹杂物,以抑制耐火材料的机械剥落,并且容易地将热旋转 用于连续铸造金属的中间包,特别是钢。 解决方案:由于在使用MgO-CaO基耐火材料作为中间包的耐火材料的情况下耐火材料的机械剥落的磨损增加与耐火材料的负荷软化特性有很深的相关性,因此当耐火材料保持时 在中温包的平均使用温度附近在1550℃的0.2MPa压缩应力的条件下至5小时,耐火材料在负载方向上收缩1-10%被施加到中间包和/或堰的衬里材料, 因此,热膨胀引起的应力被吸收,并且可以显着地抑制机械剥落的发生。 版权所有(C)2004,JPO