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    • 2. 发明专利
    • Gas barrier film formed from aqueous polymerizable monomer composition and method for producing the film
    • 从水性聚合单体组合物形成的气体阻隔膜和用于生产膜的方法
    • JP2011063806A
    • 2011-03-31
    • JP2010237350
    • 2010-10-22
    • Kureha Corp株式会社クレハ
    • INABA YUSAKUOKURA MASAYUKIKAWASHIMA MOTOTAKA
    • C08J5/18B32B27/32C08F2/00C08J7/04
    • B32B27/30B05D3/0254B05D3/067B05D3/068B05D7/04B32B15/08B32B27/08B32B27/10B32B27/26B32B27/28B32B27/308B32B2255/10B32B2255/12B32B2255/26B32B2307/7242B32B2307/7244B32B2439/40B32B2439/70B32B2439/80C08F220/06C08J7/047C08J7/18C08J2433/00C08L33/02C08L2312/00C09D4/00
    • PROBLEM TO BE SOLVED: To provide a monolayer or multilayer gas barrier film including an ionically crosslinked polycarboxylic acid polymer film excellent in gas barrier properties, and to provide a production method producible of the monolayer or multilayer gas barrier film comprising the ionically crosslinked polycarboxylic acid polymer film using an aqueous polymerizable monomer composition by a simple method. SOLUTION: The gas barrier film including the ionically crosslinked polycarboxylic acid polymer film and the production method thereof are provided, wherein polymerization treatment of a coating film of the aqueous polymerizable monomer composition, which contains an α, β-unsaturated carboxylic acid monomer and a polyvalent metal ion in an amount sufficient to neutralize 10-90% of a carboxy group of the α, β-unsaturated carboxylic acid monomer dissolved or dispersed in water in an amount of 20-85 wt.% based on the total amount of the composition, is performed and heat treatment of the cured coating film formed from the polymerization treatment is performed to form the ionically crosslinked polycarboxylic acid polymer film having an oxygen transmission rate of 50×10 -4 cm 3 (STP)/(m 2 ×s×MPa) or less as measured under high-humidity conditions of a temperature of 30°C and a relative humidity of 80%. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种包含阻气性优异的离子交联的多元羧酸聚合物膜的单层或多层阻气膜,并提供可生产单层或多层阻气膜的制备方法,其包括离子交联 通过简单的方法使用含水可聚合单体组合物的多元羧酸聚合物膜。 解决方案:提供包含离子交联的多元羧酸聚合物膜的阻气膜及其制备方法,其中含有α,β-不饱和羧酸单体的水性可聚合单体组合物的涂膜的聚合处理 和多价金属离子,其量足以中和溶解或分散在水中的α,β-不饱和羧酸单体的10-90%的羧基,其量为20-85重量%,基于 进行组合,并进行由聚合处理形成的固化涂膜的热处理,以形成氧透过率为50×10 -4 SP SP的离子交联的多元羧酸聚合物膜 在温度30℃,相对湿度80%的高湿度条件下测定的粘度> 3 (STP)/(m 2 ×s×MPa)以下。 版权所有(C)2011,JPO&INPIT
    • 3. 发明专利
    • Polymerizable monomer composition and gas barrier film formed by using the same and method for producing the same film
    • 可聚合单体组合物和使用其形成的气体阻挡膜和用于生产相同膜的方法
    • JP2006188675A
    • 2006-07-20
    • JP2005353915
    • 2005-12-07
    • Kureha Corp株式会社クレハ
    • INABA YUSAKUOKURA MASAYUKIKAWASHIMA MOTOTAKA
    • C08J7/04B05D3/06B05D7/24C08F220/20
    • PROBLEM TO BE SOLVED: To provide a production method capable of producing a unilamellar or multilamellar gas barrier film excellent in gas barrier property by simple steps. SOLUTION: The method for producing the gas barrier film comprises a step 1 for forming a coated film by applying a polymerizable monomer composition containing an α, β-unsaturated carboxylic acid monomer and a polymerizable polyfunctional (meth)acrylate having two or more carbon-carbon double bonds as a functional group in a weight ratio of (1:99) to (99.9:0.1) on to a base material and a step 2 for forming a crosslinked and cured coated film having ≤50×10 -4 cm 3 (STP)/(m 2 ×s×MPa) oxygen permeability measured under high humidity conditions of 30°C temperature and 80% relative humidity by subjecting the coated film to polymerization treatment by irradiation or heating of ionizing radiation or both of them. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供能够通过简单的步骤制造阻气性优异的单层或多层阻气膜的制造方法。 解决方案:制造阻气膜的方法包括通过涂布含有α,β-不饱和羧酸单体和具有两个或更多个的可聚合多官能(甲基)丙烯酸酯的可聚合单体组合物形成涂膜的步骤1 作为官能团的碳 - 碳双键以(1:99)至(99.9:0.1)的重量比施加到基材上,步骤2形成具有≤50×10 的交联固化涂膜, 在30℃温度和80%相对湿度的高湿度条件下测量的氧气渗透率测量的氧气渗透率测量的氧气渗透率(SPP)/(m 2 ×s×MPa) 通过照射或加热电离辐射或它们两者使涂覆膜进行聚合处理来实现湿度。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Nethod for manufacturing heat-treated poly-p-phenylene sulfide film
    • 用于制造热处理聚对苯二甲酰亚胺膜的网
    • JP2009138080A
    • 2009-06-25
    • JP2007315084
    • 2007-12-05
    • Kureha Corp株式会社クレハ
    • HOSODA TOMONORIHIDA KAZUNORIOKURA MASAYUKIOBA HIROYUKI
    • C08J7/00
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a heat-treated poly-p-phenylene sulfide film having not only high flatness but also especially excellent dimensional stability, and to provide a heat-treated poly-p-phenylene sulfide film producible by this method and equipped with high flatness and dimensional stability. SOLUTION: The manufacturing method of the heat-treated poly-p-phenylene sulfide film includes a heating step for heating a biaxially oriented poly-p-phenylene sulfide film. In the heating step, heating is performed at a predetermined temperature selected from a range higher than 160°C and lower than 290°C, and tensile stress lower than shrinkage stress at the predetermined temperature of the biaxially oriented poly-p-phenylene sulfide film is applied in one direction to the biaxially oriented poly-p-phenylene sulfide film. The heat-treated poly-p-phenylene sulfide film producible by this manufacturing method is also provided. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:为了提供热处理的聚对苯硫醚膜的制造方法,其不仅具有高的平整度,而且特别优异的尺寸稳定性,并且提供热处理的聚对苯硫醚 通过这种方法生产的薄膜,具有高平坦度和尺寸稳定性。 解决方案:热处理的聚对苯硫醚膜的制造方法包括加热双轴取向聚对苯硫醚膜的加热步骤。 在加热工序中,在从160℃以上290℃以下的规定温度下进行加热,拉伸应力低于双轴取向聚对苯硫醚膜的规定温度下的收缩应力 沿一个方向施加到双轴取向的聚对苯硫醚膜上。 还提供了通过该制造方法制造的热处理的聚对苯硫醚膜。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Laminate
    • 层压板
    • JP2006167993A
    • 2006-06-29
    • JP2004360435
    • 2004-12-13
    • Kureha Corp株式会社クレハ
    • OKURA MASAYUKITANAKA HIDEAKIOBA HIROYUKI
    • B32B27/30B32B5/24
    • PROBLEM TO BE SOLVED: To provide a laminate constituted so as not only to cut off a volatile harmful substance such as formaldehyde or the like produced from an adhesive or the like used when the laminate is formed to prevent the volatilization of the volatile harmful substance into an atmosphere but also to prevent the transfer of a plasticizer from a protective layer comprising a vinyl chloride resin containing the plasticizer, excellent in the anti-staining properties due to the bled plasticizer and especially useful for wallpaper.
      SOLUTION: The laminate is characterized in that a film (P1) formed of a mixture of a polycarboxylic acid type polymer (A) and polyalcohols (B) and a film (P2), which is formed using the polycarboxylic acid type polymer (A), a metal compound (C) and the polyalcohols (B) used voluntarily as a raw material, are arranged on the surface side of the protective layer of the laminate composed of a fiber base material layer, an adhesive layer formed of a volatile harmful substance-containing adhesive and the protective layers of the plasticizer-containing vinyl chloride resin.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种不仅能够形成由形成层压体时使用的粘合剂等产生的挥发性有害物质如甲醛等的层压体,而且可以防止挥发性物质的挥发 有害物质进入气氛,而且还防止增塑剂从包含含有增塑剂的氯乙烯树脂的保护层转移,由于流失的增塑剂而具有优异的抗污染性,并且特别适用于壁纸。 解决方案:层压体的特征在于使用多元羧酸型聚合物形成的由多元羧酸型聚合物(A)和多元醇(B)的混合物形成的膜(P1)和膜(P2) (A),金属化合物(C)和自愿使用的多元醇(B)作为原料配置在由纤维基材层形成的层叠体的保护层的表面侧,由 含挥发性有害物质的粘合剂和含增塑剂的氯乙烯树脂的保护层。 版权所有(C)2006,JPO&NCIPI
    • 7. 发明专利
    • Polymerizable monomer composition, gas barrier film, and method for producing the gas barrier film
    • 可聚合单体组合物,气体阻隔膜和用于生产气体阻隔膜的方法
    • JP2007056084A
    • 2007-03-08
    • JP2005240665
    • 2005-08-23
    • Kureha Corp株式会社クレハ
    • INABA YUSAKUKAWASHIMA MOTOTAKAOKURA MASAYUKI
    • C08F20/04B05D5/00B05D7/04B32B27/30C08F22/02C08G18/62C08G59/42C08J7/04C08L101/02
    • PROBLEM TO BE SOLVED: To provide a method for producing a single-layer or multi-layer film excellent in gas barrier properties, capable of effectively producing the film through a simple procedure, and to provide the single-layer or multi-layer gas barrier film. SOLUTION: This method for producing the gas barrier film containing the crosslinked and cured coat has a process 1 for preparing a polymerizable monomer composition which contains an α,β-unsaturated carboxylic acid monomer and a crosslinkable organic compound having at least one functional group reactive with a carboxyl group in such a molar ratio that the ratio of a mol number B of functional groups in the crosslinkable organic compound to a mol number A of carboxyl groups in the α,β-unsaturated carboxylic acid monomer (B/A) is in a range of 0.15 to 2.20, a process 2 for coating a base material with the polymerizable monomer composition, so as to form a coat, and a process 3 for treating the coat by irradiating it with ionizing radiation and/or heating it, so as to form the crosslinked and cured coat. Further, the gas barrier film and the polymerizable monomer composition are provided, respectively. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种制造阻气性优异的单层或多层膜的方法,能够通过简单的步骤有效地制造膜,并且提供单层或多层膜, 层阻气膜。 解决方案:用于制备含有交联固化涂层的阻气膜的方法具有制备含有α,β-不饱和羧酸单体和具有至少一个官能团的交联性有机化合物的可聚合单体组合物的方法1 与羧基反应的基团的摩尔比使得可交联有机化合物中的官能团的摩尔数B与α,β-不饱和羧酸单体(B / A)中羧基的摩尔数A的比例 在0.15〜2.20的范围内,用于将可聚合单体组合物涂覆在基材上以形成涂层的方法2以及用电离辐射照射和/或加热来处理该涂层的方法3, 以形成交联和固化的涂层。 此外,分别设置阻气膜和可聚合单体组合物。 版权所有(C)2007,JPO&INPIT