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    • 2. 发明专利
    • Polymer electrolyte membrane for polymer electrolyte fuel cell, membrane-electrode assembly, and fuel cell
    • 用于聚合物电解质燃料电池,膜电极组件和燃料电池的聚合物电解质膜
    • JP2010061914A
    • 2010-03-18
    • JP2008224907
    • 2008-09-02
    • Kuraray Co Ltd株式会社クラレ
    • ONO TOMOHIRONAKAI SHINJINAKANO TAKESHIKUBO KEIJISUGO NOZOMI
    • H01M8/02C08J5/22H01B1/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a polymer electrolyte membrane for a polymer electrolyte fuel cell, having economic, ecologic, well moldable, strong and flexible properties in combination and having improved durability and radical resistance in particular, and to provide a membrane-electrode assembly and the polymer electrolyte fuel cell using the same. SOLUTION: The polymer electrolyte membrane for the polymer electrolyte fuel cell contains a block copolymer as a main component, the block copolymer using a polymer block A and a polymer block B phase-separated from each other as structural components, the polymer block A using aromatic vinyl compound units as main repetitive units and having ion conductive groups, the polymer block B forming a flexible phase, the ion conductive groups substantially existing only in the polymer block A, the polymer block B using conjugated diene units each of which has a carbon number of 4-8 and whose carbon-carbon double bonds are substantially all added to hydrogen, as main repetitive units. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供具有经济,生态,可模塑,强和柔性的组合的特性并且具有改进的耐久性和自由基阻力的聚合物电解质燃料电池用聚合物电解质膜,并提供膜 - 电极组件和使用其的聚合物电解质燃料电池。 解决方案:用于固体高分子电解质燃料电池的聚合物电解质膜包含嵌段共聚物作为主要成分,使用聚合物嵌段A的嵌段共聚物和作为结构成分相分离的聚合物嵌段B,聚合物嵌段 使用芳香族乙烯基化合物单元作为主要重复单元并具有离子导电基团,聚合物嵌段B形成柔性相,离子导电基团基本上仅存在于聚合物嵌段A中,聚合物嵌段B使用共轭二烯单元,其各自具有 碳原子数为4-8,其碳 - 碳双键基本全部加入到氢气中作为主要重复单元。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Curable resin composition and shaped product using the same
    • 可固化树脂组合物和使用它的成型产品
    • JP2006282714A
    • 2006-10-19
    • JP2005101295
    • 2005-03-31
    • Kuraray Co Ltd株式会社クラレ
    • KITANO TAKAHIROKUBO KEIJIKAWASAKI MASAHIRO
    • C08F2/44B29C67/00C08F287/00G03F7/004G03F7/027G03F7/033
    • PROBLEM TO BE SOLVED: To provide a curable resin composition for stereolithography affording a shaped product having high modulus of elasticity and excellent impact resistance without requiring a support and to provide the three-dimensional shaped product using the same composition. SOLUTION: The curable resin composition for the stereolithography comprises a methyl methacrylate polymer having ≥80% isotacticity, a block copolymer having a polyalkyl acrylate block and a polymethyl methacrylate block having ≥60% syndiotacticity and a photopolymerizable ethylenically unsaturated compound in a specific proportion. The three-dimensional shaped product is obtained by curing the composition. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种用于立体光刻的固化树脂组合物,其提供具有高弹性模量和优异的耐冲击性而不需要支撑物的成型产品,并提供使用相同组成的三维成形产品。 解决方案:用于立体光刻的可固化树脂组合物包括具有≥80%全同立构规整度的甲基丙烯酸甲酯聚合物,具有聚丙烯酸烷基酯嵌段的嵌段共聚物和具有≥60%间同立构规整度的聚甲基丙烯酸甲酯嵌段和可光聚合的烯键式不饱和化合物 比例。 通过固化组合物获得三维成形产品。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Curable resin composition and three-dimensional shaped product using the same
    • 可固化树脂组合物和三维形状的产品
    • JP2006282702A
    • 2006-10-19
    • JP2005100886
    • 2005-03-31
    • Kuraray Co Ltd株式会社クラレ
    • KITANO TAKAHIROKUBO KEIJIKAWASAKI MASAHIRO
    • C08F290/12
    • PROBLEM TO BE SOLVED: To provide a curable resin composition for a stereolithographic method affording a shaped product having high modulus of elasticity and excellent impact resistance without requiring a support and to provide the three-dimensional shaped product using the composition.
      SOLUTION: The curable resin composition for the stereolithographic method comprises a methyl methacrylate polymer having ≥80% isotacticity, a methacrylic ester copolymer having a polymerizable ethylenic double bond in the side chain and ≥40% syndiotacticity and a photopolymerizable ethylenically unsaturated compound in a specific proportion. The three-dimensional shaped product is obtained by curing the composition.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种用于立体光刻方法的可固化树脂组合物,其提供具有高弹性模量和优异的耐冲击性而不需要支撑物的成型产品,并提供使用该组合物的三维成形产品。 解决方案:用于立体光刻方法的可固化树脂组合物包括具有≥80%全同立构规整度的甲基丙烯酸甲酯聚合物,侧链中具有可聚合烯键式双键的甲基丙烯酸酯共聚物和≥40%间同立构规整度和可光聚合烯键式不饱和化合物 具体比例。 通过固化组合物获得三维成形产品。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Transfer material, method for producing the same and transferred material
    • 转移材料,其制造方法和转印材料
    • JP2006045355A
    • 2006-02-16
    • JP2004228633
    • 2004-08-04
    • Kuraray Co LtdNippon Fine Chem Co LtdOike Ind Co Ltd尾池工業株式会社日本精化株式会社株式会社クラレ
    • KITANO TAKAHIROSUZUKI KOICHIKUBO KEIJIKAWABATA TSUNEOKOJIMA MASAKI
    • C08F220/04B32B27/00B32B27/16
    • PROBLEM TO BE SOLVED: To provide a transfer material installed with a transferring layer consisting of a layer formed on a surface having generally a low wetting property such as a releasing base film and a different layer formed thereon, and realizing a good interlayer close adhesion so as not to produce "cissing" or "pin hole" on the different layer.
      SOLUTION: This transfer material having the releasing base film and the transfer layer installed thereon is provided with that the transfer layer is constituted by containing at least one layer of a cured resin layer consisting of a photo-curable resin composition. There, the curable resin composition contains a component (A), a solid state photo-polymerizable metal salt consisting of a divalent or trivalent metal with an organic carboxylic acid having an unsaturated bond, a component (B), a photo-polymerizable ethylenically unsaturated compound and a component (C), a photo-polymerization initiator, in a specific ratio.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种转印材料,其具有由形成在通常具有低润湿性的表面上形成的转印层的转印层,所述转印层通常具有低释放性基底膜和形成在其上的不同层,并且实现良好的中间层 密封性好,不会在不同的层上产生“裂缝”或“针孔”。

      解决方案:具有安装在其上的释放基膜和转印层的转印材料设置有转印层由至少一层由光固化树脂组合物组成的固化树脂层构成。 其中,固化性树脂组合物含有成分(A),由二价或三价金属与具有不饱和键的有机羧酸组成的固态光聚合性金属盐,成分(B),光聚合性烯属不饱和 化合物和成分(C),光聚合引发剂。 版权所有(C)2006,JPO&NCIPI

    • 8. 发明专利
    • Transferring material, its manufacturing method, and transferred product
    • 传输材料及其制造方法和转让产品
    • JP2004042607A
    • 2004-02-12
    • JP2003114818
    • 2003-04-18
    • Kuraray Co LtdNippon Fine Chem Co LtdOike Ind Co Ltd尾池工業株式会社日本精化株式会社株式会社クラレ
    • KITANO TAKAHIROSUZUKI KOICHIKUBO KEIJIOGUSHI MASAYASUTERADA KAZUTOSHIKAWABATA TSUNEOKOJIMA MASAKI
    • B44C1/17B32B7/06B32B27/30
    • PROBLEM TO BE SOLVED: To provide a transferring material, which has a uniform hardened resin layer having no "repellency", "pinhole", etc., and to provide its manufacturing method, and to provide a transferred product obtained by using the transferring material.
      SOLUTION: The transferring material having a mold-releasing base film and a transferring layer provided thereon includes a component (A) of thermoadhesive polymer on the transferring layer, a component (B) of ethylene unsaturated compound polymerizeable by activated energy rays, and a component (C) of polymerization initiator. The transferring material includes at least one layer of thermoadhesive hardened resin layers composed of the hardening resin compositions, which satisfies the relationships given by the following equations (1), (2): 0.1≤(Awt)/((Awt)+(Bwt))≤0.6 (1), 0.4≤(Bwt)/((Awt)+(Bwt))≤0.9 (2), where (Awt) shows an amount (weight part) of the component (A), and (Bwt) shows an amount (weight part) of the component (B), and includes the thermoadhesive hardened resin layer on the uppermost surface on the other side of the mold-releasing base film.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供具有不具有“排斥性”的均匀的硬化树脂层,“针孔”等的转印材料,并提供其制造方法,并提供通过使用得到的转印产品 转移材料。 解决方案:具有脱模基膜和转印层的转印材料包括转印层上的热粘合性聚合物的成分(A),能够通过活性能量射线聚合的乙烯不饱和化合物的成分(B) 和聚合引发剂的组分(C)。 转印材料包括由硬化树脂组合物组成的至少一层热粘合性硬化树脂层,其满足下列等式(1),(2)给出的关系:0.1≤(Awt)/((Awt)+(Bwt ))≤0.6(1),0.4≤(Bwt)/((Awt)+(Bwt))≤0.9(2)其中(Awt)表示成分(A)的量(重量份) )表示组分(B)的量(重量份),并且在脱模底膜的另一侧的最上表面上包含热粘合性硬化树脂层。 版权所有(C)2004,JPO
    • 9. 发明专利
    • Polyelectrolyte membrane for solid polymer fuel cell, membrane-electrode assembly, and fuel cell
    • 用于固体聚合物燃料电池,膜电极组件和燃料电池的聚电解质膜
    • JP2010067526A
    • 2010-03-25
    • JP2008234014
    • 2008-09-11
    • Kuraray Co Ltd株式会社クラレ
    • ONO TOMOHIRONAKAI SHINJINAKANO TAKESHIKUBO KEIJISUGO NOZOMI
    • H01M8/02C08J5/22H01B1/06H01B13/00H01M8/10
    • Y02E60/523
    • PROBLEM TO BE SOLVED: To provide a polyelectrolyte membrane for a solid polymer fuel cell economical, environment-friendly, excellent in moldability as well as excellent in flexibility and durability, and to provide a membrane-electrode assembly as well as a solid polymer fuel cell using the polyelectrolyte membrane. SOLUTION: The polyelectrolyte membrane for a solid polymer fuel cell as well as a membrane-electrode assembly and a solid polymer fuel cell using the same have a polymer block (A) with an aromatic vinyl based compound unit as a main repetition unit and a flexible polymer block (B) as constituent elements, with a mass ratio of the polymer block (A) and the polymer block (B) of 65:35 to 10:90, the polymer block (A) containing a block copolymer with an ion-conductive group as a main constituent, with a 100% modulus of 15 MPa in a tensile test at conditions of 25°C or less and a pulling rate of 500 mm/min, a break strength of 15 MPa or more, and a breaking elongation of 300% or more. COPYRIGHT: (C)2010,JPO&INPIT
    • 解决的问题:为了提供经济,环保,成型性优异,柔软性和耐久性优异的固体高分子型燃料电池用聚电解质膜,提供膜电极接合体以及固体 聚合物燃料电池使用聚电解质膜。 解决方案:用于固体聚合物燃料电池的聚电解质膜以及使用其的固体聚合物燃料电池具有聚合物嵌段(A)和芳族乙烯基类化合物单元作为主要重复单元 和作为构成元素的柔性聚合物嵌段(B),聚合物嵌段(A)和聚合物嵌段(B)的质量比为65:35〜10:90,含有嵌段共聚物的聚合物嵌段(A) 作为主要成分的离子传导性基团,在25℃以下的拉伸试验和500mm / min的拉伸速度下的100%模量为15MPa,断裂强度为15MPa以上, 断裂伸长率在300%以上。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Method for manufacturing laminate including activation energy beam-cured resin layer
    • 包括活化能量光束固化树脂层的层压板的制造方法
    • JP2003019759A
    • 2003-01-21
    • JP2001209332
    • 2001-07-10
    • Kuraray Co Ltd株式会社クラレ
    • KITANO TAKAHIROSUZUKI KOICHIKUBO KEIJIOGUSHI MASAYASUTERADA KAZUTOSHI
    • B32B37/00B32B27/08C08L33/10C09D4/00C09D5/00B29D9/00
    • PROBLEM TO BE SOLVED: To realize the manufacturing of a laminate composed of an activation energy beam-cured resin layer formed on a base, then further, a thermoplastic resin layer, a heat-curable resin layer or another activation energy bean-cured resin layer laminated, as upper layers, on the activation energy beam-cured resin layer, using satisfactory interlayer adhesion properties. SOLUTION: The laminate including the activation energy beam-curable resin layer is structured of an activated beam-curable layer composed of an activation energy beam-curable composition formed on the base, and the upper layers such as a thermoplastic resin composition, a heat-curable resin composition or another activated energy beam-curable composition are laminated on the uncured activation energy beam-curable layer. In addition, the activation energy beam-curable layer is cured by irradiating it with an activated energy beam. Thus the laminate is manufactured by forming the activation energy beam-cured resin layer.
    • 要解决的问题为了实现由形成在基底上的活化能量束固化树脂层构成的层压体的制造,然后进一步制造热塑性树脂层,热固性树脂层或另一种活化能豆固化树脂层 作为上层,在活化能束固化树脂层上层压,使用令人满意的层间粘合性能。 解决方案:包括活化能量束固化树脂层的层压体由在基体上形成的活化能量束固化性组合物和由热塑性树脂组合物,热塑性树脂组合物等上层构成的活化光束固化层构成, 可固化树脂组合物或另一种活化能量束固化组合物层压在未固化的活化能束可固化层上。 此外,活化能量束固化层通过用活化能量束照射来固化。 因此,通过形成活化能量束固化树脂层来制造层压体。