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    • 1. 发明专利
    • Silver halide photographic sensitive material
    • 银色摄影感光材料
    • JPS6191652A
    • 1986-05-09
    • JP21316284
    • 1984-10-11
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOMIYOSHI MASANOBUNAKATSUGAWA HIROSHIONODERA KAORU
    • G03C7/26G03C1/005G03C1/035G03C1/06G03C1/38G03C7/00G03C7/392
    • G03C1/035G03C2001/0357G03C2200/06
    • PURPOSE:To obtain a photographic sensitive material superior in sensitivity, storage stability with time lapse, etc., by incorporating specified monodispersed silver halide grains having [100] and [111] faces and an org. solvent having a dielectric constant not exceeding a specified value and high b.p., and a specified compd. in an emulsion layer. CONSTITUTION:At least one silver halide emulsion layer contains the monodispersed silver halide grains having a [100] face and a [111] face, and a ratio K of X-ray diffraction intensity F1 belonging to a [200] face/that F2 belonging to a face [222], that is, K=F1/F2, satisfying the following inequality, 3
    • 目的:通过引入具有[100]和[111]面的特定的单分散卤化银颗粒,获得具有优异的灵敏度,随时间流逝的储存稳定性的感光材料。 介电常数不超过规定值和高沸点的溶剂,以及规定的化合物。 在乳剂层中。 构成:至少一个卤化银乳剂层含有具有[100]面和[111]面的单分散卤化银颗粒,属于[200]面/ F2属的X射线衍射强度F1的比K 面对[222],即K = F1 / F2,满足以下不等式,3 <= K <= 600,高bp 组织 介电常数<6.0的溶剂,进而, 由式I表示,其中R 1 -R 3各自为H,卤素等; A1-A3中的每一个为N或式II的基团; R4与R1相同; X1,X2各自为OH或-NR5R6; 每个R 5,R 6为H,烷基,芳基等,或者各自可以彼此结合形成环,或(R 1 -R 4)和(R 5和R 6)中的一个或多个可以 结合起来形成戒指; n1-n3分别为0-3。 结果,可以获得灵敏度和储存稳定性优异的感光材料。
    • 2. 发明专利
    • Color photographic silver halide product
    • 彩色摄影银白炽灯产品
    • JPS593433A
    • 1984-01-10
    • JP11348782
    • 1982-06-29
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/26G03C7/392
    • G03C7/39208
    • PURPOSE:To improve the light fastness of a dye image by incorporating a specified compound into a dye image forming layer or its adjacent layer. CONSTITUTION:A compound represented by the formula (where R is H, alkyl or aryl, each of R1 and R2 is alkyl or aryl, X is alkylene or arylene, Z is O, S, sulfonyl, carbonyl or alkylene, and n is an integer of 1-20) is incorporated into a dye image forming layer and/or its adjacent layer by 5-300wt% of the amount of a coupler used. When no coupler is incorporated, the amount of the compound is 10-100g per 1mol silver halide.
    • 目的:通过将特定的化合物掺入染料成像层或其相邻层中来提高染料图像的耐光性。 构成:由式(其中R为H,烷基或芳基,R 1和R 2各自为烷基或芳基,X为亚烷基或亚芳基,Z为O,S,磺酰基,羰基或亚烷基,并且n为 1-20的整数)被染色图像形成层和/或其相邻层掺入所用成色剂量的5-300重量%。 当不加入偶合剂时,化合物的量为每1mol卤化银10-100g。
    • 3. 发明专利
    • Color photographic sensitive material
    • 彩色摄影感光材料
    • JPS58211147A
    • 1983-12-08
    • JP9514482
    • 1982-06-02
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/20G03C1/815G03C7/36G03C7/392
    • G03C7/39256
    • PURPOSE:To enhance light resistance of a dye image, by forming nonphotosensitive layers each contg. a benzotriazole type UV absorber on both sides of a silver halide emulsion layer located furthest from a support, and a nonphotosensitive layer contg. at least 2 kinds of UV absorbers located on the reverse side of the support. CONSTITUTION:A blue sensitive silver halide emulsion layer, a green sensitive silver halide emulsion layer, a red sensitive silver halide emulsion layer or the like plural silver halide emulsion layers are formed on a reflective support. Nonphotosensitive layers are formed on both sides of the emulsion layer located furthest from the support, and each contains a UV absorber having formula I in which R1, R2, R3 are each H, halogen, alkyl, aryl, alkoxy, aryloxy, alkenyl, nitro, or hydroxy, such as formulae II, III, or IV, and the other nonphotosensitive layer formed on the other side of the support contains at least 2 kinds of the absorbers of formula I to obtain the present color photographic sensitive material.
    • 目的:为了增强染料影像的耐光性,通过形成非感光层, 位于离支撑体最远的卤化银乳剂层两侧的苯并三唑型UV吸收剂,以及非感光层。 位于支架背面的至少2种紫外线吸收剂。 构成:在反射性载体上形成蓝色感光卤化银乳剂层,绿色感光卤化银乳剂层,红色感光卤化银乳剂层等多个卤化银乳剂层。 在距离载体最远的乳剂层的两侧形成非感光层,并且各自含有具有式I的UV吸收剂,其中R 1,R 2,R 3各自为H,卤素,烷基,芳基,烷氧基,芳氧基,烯基,硝基 或羟基,例如式II,III或IV,并且在载体的另一侧上形成的另一非光敏层含有至少2种式I的吸收剂,以获得本发明的感光材料。
    • 4. 发明专利
    • Silver halide color photographic product
    • 银色彩色摄影产品
    • JPS595246A
    • 1984-01-12
    • JP11464182
    • 1982-06-30
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA ISAO
    • G03C7/26G03C7/32G03C7/392
    • G03C7/39232
    • PURPOSE:To improve resistance to light fading of a yellow dye image, by adding a specified compd. to a layer contg. a specified yellow dye or pigment and/or its adjacent layer. CONSTITUTION:A compd. having formula II in which R9 is H, alkyl, or aryl; R10, R11 are each alkyl; X is alkylene or arylene; and Y is alkylene (B) is added to a silver halide emulsion layer contg. a yellow dye having formula I and/or its adjacent layer formed on a support (A). In formula I , R1 is alkyl, alkenyl, aryl, or a heterocyclic group; R2 is halogen, alkoxy, or aryloxy; R3-R5 are each H, halogen, alkyl, alkenyl, alkoxy, aryl, or the like; R6 is H or alkyl; R7, R8 are each unsubstd. alkyl or alkyl substd. by a solubilizing group, but the case where R6 is methyl and R7, R8 are each ethyl is excluded. As a result, deviation of color balance due to light fading of three dyes can be improved.
    • 目的:通过添加指定的化合物来提高黄色染料影像的抗光衰。 到一层 指定的黄色染料或颜料和/或其相邻层。 构成: 式II其中R9为H,烷基或芳基; R 10,R 11各自为烷基; X是亚烷基或亚芳基; 和Y是亚烷基(B)加入到卤化银乳剂层中。 具有式I和/或其相邻层的黄色染料形成在载体(A)上。 在式I中,R 1是烷基,烯基,芳基或杂环基; R2是卤素,烷氧基或芳氧基; R3-R5各自为H,卤素,烷基,烯基,烷氧基,芳基等; R6是H或烷基; R7,R8均未取代。 烷基或烷基。 通过增溶基团,但不包括R6为甲基且R7,R8各为乙基的情况。 结果,可以提高三种染料的光褪色引起的色平衡的偏差。
    • 5. 发明专利
    • Emulsified dispersion
    • 乳化分散体
    • JPS59215378A
    • 1984-12-05
    • JP8959183
    • 1983-05-21
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORUINAHATA HIDEKI
    • G03C7/26B01J13/00C09K3/00G03C1/06G03C1/815
    • G03C1/8155
    • PURPOSE: To provide an emulsified dispersion of an ultraviolet ray absorber which contains a mixt. of specified two types of ultraviolet ray absorbers and oil drops contg. a high-boiling solvent, gives a consistently high ultraviolet ray absorption effect even at high temp. and high humidity when applied to photographic products.
      CONSTITUTION: The emulsified dispersion of an ultraviolet ray absorber contains a mixt. of ultraviolet ray absorbers consisting of 15W45wt% compd. of formula I (where R
      1 and R
      2 are 1W4C alkyl; X is H, halogen, CH
      3 , C
      2 H
      5 , OCH
      3 , OC
      2 H
      5 or aryl) (e.g. a compd. of formula II) and 8W15wt% compd. of formula III(where R
      3 and R
      4 are alkyl; the alkyl groups in them have at least 9 carbon atoms in total; Y is H, halogen, CH
      3 , C
      2 H
      5 , OCH
      3 , OC
      2 H
      5 or aryl) (e.g. a compd. of formula IV) and oil drops which contains a high-boiling solvent (e.g. dibutyl phthalate or triphenyl phosphate). The dispersion which contains a mixt. of ultraviolet ray absorbers of formulas I and II gives a consistent ultraviolet ray absorption effect even at high temp. and high humidity when applied to photographic products.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:提供含有混合物的紫外线吸收剂的乳化分散体。 指定两种类型的紫外线吸收剂和油滴。 高沸点溶剂,即使在高温下也能得到始终如一的高的紫外线吸收效果。 和高湿度,适用于摄影产品。 构成:紫外线吸收剂的乳化分散体含有混合物。 的紫外线吸收剂由15-45wt%的化合物组成。 (其中R 1和R 2是1-4C烷基; X是H,卤素,CH 3,C 2 H 5,OCH 3,OC 2 H 5或芳基)(例如式II的化合物)和8-15重量%的化合物。 (其中R 3和R 4是烷基;它们中的烷基总共具有至少9个碳原子; Y是H,卤素,CH 3,C 2 H 5,OCH 3,OC 2 H 5或芳基)(例如式IV的化合物) 和含有高沸点溶剂(例如邻苯二甲酸二丁酯或磷酸三苯酯)的油滴。 包含混合物的分散体。 式I和II的紫外线吸收剂即使在高温下也具有一致的紫外线吸收效果。 和高湿度,适用于摄影产品。
    • 6. 发明专利
    • Photosensitive silver halide material
    • 感光银卤素材料
    • JPS59105646A
    • 1984-06-19
    • JP21617782
    • 1982-12-09
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/34G03C7/30G03C7/388
    • G03C7/3006
    • PURPOSE:To improve the resistances to light, heat and moisture with good balance and to improve image retentivity at high temp. and high humidity by dispersing and incorporating a specific cyan coupler by using a specific org. solvent having a high b.p. in a silver halide emulsion layer. CONSTITUTION:One of the cyan coupler expressed by the formula I is dispersed and incorporated by using one of the org. solvent having a high b.p. expressed by the formula II in a silver halide emulsion layer in a silver halide photosensitive material provided with at least one silver halide emulsion layer on a base. The dispersion stability of the cyan coupler incorporated in said layer is thus improved and good image retentivity is maintained and provided for a long period of time. In the formula, R1 denotes an alkyl group or aryl group, R2-R6 note a hydrogen atom, halogen atom, hydroxyl group, nitro group, cyano group, alkyl group, etc. and Z1 denotes a hydrogen atom or the group that can be eliminated when the coupler reacts with the oxidized product of an arom. primary amine color developing agent. R7 and R8 denote an alkyl group, alkenyl group or aryl group.
    • 目的:提高光,热,湿度的平衡性,提高高温下的图像保持性。 和高湿度,通过使用特定的组织分散和结合特定的青色成色剂。 溶剂具有高的沸点 在卤化银乳剂层中。 构成:由式I表示的青色成色剂之一通过使用其中一种组分分散并合并。 溶剂具有高的沸点 在卤化银感光材料中的卤化银乳剂层中由式II表示,在卤化银感光材料中在基底上提供至少一个卤化银乳剂层。 因此,结合在所述层中的青色成色剂的分散稳定性得到改善,并且保持良好的图像保持性并提供长时间。 式中,R1表示烷基或芳基,R2-R6表示氢原子,卤素原子,羟基,硝基,氰基,烷基等,Z1表示氢原子或可以为 当成色剂与芳香族的氧化产物反应时被消除。 伯胺显色剂。 R 7和R 8表示烷基,烯基或芳基。
    • 7. 发明专利
    • Silver halide photosensitive material
    • 银红色光敏材料
    • JPS59149348A
    • 1984-08-27
    • JP2432183
    • 1983-02-15
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/26G03C1/06G03C7/388G03C7/392
    • G03C7/39232
    • PURPOSE:To prevent color mixing and fog by adding a nondiffusible hydroquinone derivative to a silver halide emulsion layer and a nonphotosensitive hydrophilic colloidal layer and fine oil drops contg. a specified high-boiling solvent. CONSTITUTION:A silver halide emilsion layer and a nonphotosensitive hydrophilic colloidal layer contain a nondiffusible hydroquinone deriv. and fine oil drops contg. a high-boiling org. solvent represented by formula I in which R1, R2 are each alkyl, alkenyl, or aryl, and the total C number of them is 18-36. Especially preferable compds. of formula I are represented by formula II in which R3 is a straight or branched nonyl, decyl, or the like group. Desirable nondiffusible hydroquinone derivs. to be used in this invention are represented by formula III in which R4, R5 are each H or alkyl, and R6-R9 are each H or halogen.
    • 目的:通过向卤化银乳剂层和非感光亲水性胶体层和精细油滴中加入不溶性氢醌衍生物来防止混色和雾化。 指定的高沸点溶剂。 构成:卤化银废物层和非感光亲水胶体层含有不扩散的氢醌衍生物。 和精油滴 高沸点组织 由式Ⅰ表示的溶剂,其中R 1,R 2各自为烷基,烯基或芳基,其总C数为18-36。 特别优选的compds。 式I的化合物由式II表示,其中R 3是直链或支链壬基,癸基等。 理想的不扩散氢醌衍生物。 用于本发明的式III表示,其中R 4,R 5各自为H或烷基,且R 6 -R 9各自为H或卤素。
    • 8. 发明专利
    • Silver halide photosensitive material
    • 银红色光敏材料
    • JPS59114541A
    • 1984-07-02
    • JP22530182
    • 1982-12-21
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/26G03C7/30G03C7/36G03C7/388
    • G03C7/3005G03C7/3885
    • PURPOSE: To obtain the titled material improved in color fastness to light, of a yellow dye image by forming a silver halide emulsion layer contg. a specified coupler for forming a yellow dye image and a high boiling org. solvent on a support.
      CONSTITUTION: A coupler for forming a yellow dye image having formula I (R
      1 is alkyl or aryl; R
      2 is aryl; X is H or a group releasable by reaction with the oxidized product of an aromatic primary amine color developing agent) is dissolved in 0.1W300wt% (based on the coupler) high-boiling solvent having formula II in which R
      3 , R
      4 are each nonyl, decyl, or undecyl. A silver halide emulsion is obtained by finely dispersing thin soln. into a dispersion medium, such as an aq. soln. of gelatin, and then, dispersing silver halide grains. A support is coated with said emulsion. to form a silver halide emulsion layer, and on this layer, blue, green, and red sensitive emulsion layers are formed.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过形成卤化银乳剂层,获得黄色染料图像的耐光色牢度的标题材料。 用于形成黄色染料图像和高沸点组合物的指定成色剂。 溶剂在支架上。 构成:用于形成具有式I(R 1为烷基或芳基; R 2为芳基; X为H或可通过与芳族伯胺显色剂的氧化产物反应释放的基团)的黄色染料图像的成色剂溶解于0.1 -300重量%(基于成色剂)具有式II的高沸点溶剂,其中R 3,R 4各自为壬基,癸基或十一烷基。 通过细分散薄溶胶获得卤化银乳剂。 成为分散介质,例如水溶液。 SOLN。 的明胶,然后分散卤化银颗粒。 用所述乳液涂覆载体。 形成卤化银乳剂层,在该层上形成蓝色,绿色和红色感光乳剂层。
    • 9. 发明专利
    • Photosensitive silver halide material
    • 感光银卤素材料
    • JPS59105645A
    • 1984-06-19
    • JP21617682
    • 1982-12-09
    • Konishiroku Photo Ind Co Ltd
    • SASAKI MASAOONODERA KAORU
    • G03C7/34G03C7/30G03C7/388G03C7/392
    • G03C7/3005G03C7/3885
    • PURPOSE: To improve the resistances to light, heat and moisture with good balance and to improve image retentivity at high temp. and high humidity by dispersing and incorporating a specific cyan coupler by using a specific org. solvent having a high b.p. in a silver halide emulsion layer.
      CONSTITUTION: One of the cyan coupler expressed by the formula I is dispersed and incorporated by using one of the org. solvent having a high b.p. expressed by the formula II in a silver halide emulsion layer in a silver halide photosensitive material provided with at least one silver halide emulsion layer on a base. The dispersion stability of the cyan coupler incorporated in said layer is thus improved and image retentivity is improved without spoiling the photographic characteristic of the formed dye image. In the formula R
      1 denotes an alkyl group or aryl group, R
      2 WR
      6 denote respectively a hydrogen atom, halogen atom, hydroxyl group, nitro group, etc. and Z
      1 denotes a hydrogen atom or the group that can be eliminated when the coupler reacts with the oxidized product of an arom. primary amine color developing agent. R
      7 and R
      8 denote an alkyl group, alkenyl group or aryl group.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:提高光,热,湿度的平衡性,提高高温下的图像保持性。 和高湿度,通过使用特定的组织分散和结合特定的青色成色剂。 溶剂具有高的沸点 在卤化银乳剂层中。 构成:由式I表示的青色成色剂之一通过使用其中一种组分分散并合并。 溶剂具有高的沸点 在卤化银感光材料中的卤化银乳剂层中由式II表示,在卤化银感光材料中在基底上提供至少一个卤化银乳剂层。 因此,结合在所述层中的青色成色剂的分散稳定性得到改善,并且改善了图像保持性,而不损害所形成的染料图像的照相特性。 式中,R 1表示烷基或芳基,R 2 -R 6分别表示氢原子,卤素原子,羟基,硝基等,Z1表示氢原子或者当成色剂与 芳香的氧化产物。 伯胺显色剂。 R 7和R 8表示烷基,烯基或芳基。
    • 10. 发明专利
    • Silver halide photosensitive material
    • 银红色光敏材料
    • JPS5971050A
    • 1984-04-21
    • JP18261182
    • 1982-10-18
    • Konishiroku Photo Ind Co Ltd
    • NISHIJIMA TOYOKISASAKI MASAOONODERA KAORU
    • G03C1/85G03C1/815G03C7/392G03C7/396
    • G03C7/39208G03C7/396
    • PURPOSE:To improve a white ground and to prevent a static mark by providing a layer contg. a UV absorbent, a layer contg. a fluorescent whitening agent and a layer capturing said agent on a substrate. CONSTITUTION:A layer contg. a fluorescent whitening agent is provided in the position nearer than the layer contg. a UV absorbent provided in the position furthest from a substrate among the layers contg. the UV absorbent and a compd. capturing the whitening agent is incorporated in the layer contg. the UV absorbent provided in the furthest position and/or the layer provided in the position further from said layer. The layer contg. the whitening agent and the layer capturing the same are separately formed but the white ground is more improved if both layers are provided in the nearest possible position. Polyvinyl pyrolidone and its copolymer are preferred as the compd. capturing the whitening agent.
    • 目的:改善白色的地面,并通过提供一个层次来防止静态标记。 紫外线吸收剂,层 荧光增白剂和在基材上捕获所述试剂的层。 构成:一层 荧光增白剂设置在比接续层更靠近的位置。 紫外线吸收剂设置在层间最远离衬底的位置。 紫外线吸收剂和化合物 捕获美白剂被并入层间连接。 设置在最远位置的UV吸收剂和/或设置在更远离所述层的位置的层。 层次约束 分别形成美白剂和捕获它的层,但如果两层设置在最接近的可能位置,则白色地面更好。 聚乙烯吡咯烷酮及其共聚物作为化合物是优选的。 捕获美白剂。