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1. 发明专利

JP2010018775A Organic and inorganic composite material dispersion and method for its preparation 有权
标题翻译：有机和无机复合材料分散体及其制备方法
公开(公告)号：JP2010018775A
公开(公告)日：2010-01-28
申请号：JP2009049127
申请日：2009-03-03
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： TAKADA TETSUO , HARAGUCHI KAZUTOSHI
IPC分类号： C08L33/14 , B32B27/30 , C08F20/28 , C08K3/34 , C08K7/00 , C09D1/00 , C09D133/14 , C09K3/18 , C12M1/00
摘要： PROBLEM TO BE SOLVED: To provide an aqueous dispersion of an organic and inorganic composite material with an organic and inorganic composite material particles having a clay mineral and a macromolecular polymer forming a three-dimensional network, capable of easily controlling the composite structure and the particle size thereof and having the excellent coating film forming ability and bonding property with respect to a substrate stably dispersed in water, and to provide a preparation of the aqueous solution simply in a short time over a wide range of a clay mineral content.
SOLUTION: The organic and inorganic composite dispersion comprises (X) organic and inorganic composite material particles prepared by multiplexing (P) a polymer from (a) a monomer represented by formula (1): CH
2 =CR
1 -CO(OR
2 )
n OR
3 , and (B) one or more of inorganic materials selected from the group consisting of a water-swellable clay mineral and a silica dispersed in (C) an aqueous solution.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供有机和无机复合材料的水性分散体，其具有有机和无机复合材料颗粒，其具有形成三维网络的粘土矿物和大分子聚合物，能够容易地控制复合结构并且具有优异的涂膜形成能力和相对于稳定分散于水中的基材的粘结性能，并且在宽范围的粘土矿物质含量下简单地在短时间内提供水溶液的制备。有机和无机复合分散体包含（X）通过使（A）由式（1）表示的单体的聚合物（P）复合（P）制备的（X）有机和无机复合材料颗粒：CH 2 => >（B）一个或多个选自水溶胀性粘土矿物和分散在（C）水溶液中的二氧化硅）的无机材料。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2010001354A Organic/inorganic composite material including liquid crystalline compound 有权
标题翻译：有机/无机复合材料，包括液晶化合物
公开(公告)号：JP2010001354A
公开(公告)日：2010-01-07
申请号：JP2008160330
申请日：2008-06-19
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： MURATA KAZUTAKA , HARAGUCHI KAZUTOSHI
IPC分类号： C08L101/00 , C08K3/00 , C08K5/00 , G02F1/13
摘要： PROBLEM TO BE SOLVED: To provide an organic/inorganic composite material including a liquid crystalline compound being excellent in flexibility and stretching/contraction property and capable of reversibly largely varying orientation property and optical anisotropy by stretching/contraction.
SOLUTION: The organic/inorganic composite body including the liquid crystalline compound (C) in a three-dimensional network formed by combining a polymer of a radical polymerizable monomer (A) and a clay mineral (B), and in the organic/inorganic composite material, the radical polymerizable monomer (A) contains the radical polymerizable monomer (A1) represented by structural formula (1). (wherein, R
1 represents a hydrogen atom or a methyl group, R
2 represents a 1-5C alkylene group which may be branched, and R
3 represents a 1-4C alkyl group which may be branched, and provided that a total of the carbon number of R
2 and R
3 is 6 or less).
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提供一种包含柔软性和拉伸/收缩性优异的液晶性化合物的有机/无机复合材料，能够通过拉伸/收缩来大幅度地改变取向性和光学各向异性。解决方案：通过将可自由基聚合单体（A）和粘土矿物（B）的聚合物组合形成的三维网络中的液晶化合物（C）和有机物 /无机复合材料，自由基聚合性单体（A）含有结构式（1）表示的自由基聚合性单体（A1）。（其中，R SP 1表示氢原子或甲基，R SP 2表示可以是支链的1-5C亚烷基，R“3” SP>表示可以是支链的1-4C烷基，并且条件是R“SP”2 和R 3的总数为6以下）。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2009269971A Organic/inorganic complex gel 有权
标题翻译：有机/无机复合凝胶
公开(公告)号：JP2009269971A
公开(公告)日：2009-11-19
申请号：JP2008120308
申请日：2008-05-02
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： MURATA KAZUTAKA , HARAGUCHI KAZUTOSHI
IPC分类号： C08L57/00 , C08K3/34 , C08K5/00 , C08L33/14 , C08L33/26
摘要： PROBLEM TO BE SOLVED: To provide a gel sufficiently exhibiting functional properties of ionic liquids such as nonvolatility, flame retardancy and ionic conductivity and having sufficient strength, elasticity, flexibility and stretchability usable in various applications.
SOLUTION: An organic/inorganic complex gel sufficiently exhibiting functional properties of ionic liquids while keeping the strength, elasticity, flexibility and stretchability of a gel is produced by including an ionic liquid (C) in a three-dimensional network formed by complexing a polymer of a radically polymerizable monomer (A) and a clay mineral (B).
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供足够显示离子液体的功能性质的凝胶，例如非挥发性，阻燃性和离子导电性，并且具有可用于各种应用的足够的强度，弹性，柔韧性和拉伸性。解决方案：通过在通过络合形成的三维网络中包含离子液体（C），产生充分显示离子液体的功能性质同时保持凝胶的强度，弹性，柔性和拉伸性的有机/无机复合凝胶可自由基聚合的单体（A）和粘土矿物（B）的聚合物。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2009149759A Preparation of cationic organic-inorganic composite hydrogel 有权
标题翻译：阳离子有机无机复合水凝胶的制备
公开(公告)号：JP2009149759A
公开(公告)日：2009-07-09
申请号：JP2007328519
申请日：2007-12-20
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08F2/44 , C08F292/00
摘要： PROBLEM TO BE SOLVED: To provide a preparation of a novel organic-inorganic composite hydrogel having not only high dynamic physical properties but also low water swellable properties. SOLUTION: The preparation of an organic-inorganic composite hydrogel with a three-dimensional network of the sodium pyrophosphate-containing water swellable clay mineral (B) and an organic polymer (A) obtained by copolymerization of a (meth)acrylamide or a derivative thereof and a polymerizable monomer having a quaternary ammonium base, comprises a step of preparing a homogeneous solution containing a (meth)acrylamide or a derivative thereof, a sodium pyrophosphate-containing water swellable clay mineral (B) and water (C), and adding a polymerizable monomer having a quaternary ammonium base simultaneously with a polymerization initiator or after addition of a polymerization initiator. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供不仅具有高动态物理性能，而且具有低水膨胀性能的新型有机 - 无机复合水凝胶的制备。解决方案：制备具有含焦磷酸钠的水可溶胀粘土矿物（B）和通过（甲基）丙烯酰胺或（甲基）丙烯酰胺共聚合获得的有机聚合物（A））的三维网络的有机 - 无机复合水凝胶其衍生物和具有季铵碱的可聚合单体包括制备含有（甲基）丙烯酰胺或其衍生物，含焦磷酸钠的水可溶胀粘土矿物（B）和水（C）的均匀溶液的步骤，并在聚合引发剂中加入具有季铵碱的可聚合单体，或加入聚合引发剂。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2009046532A Method for producing organic-inorganic composite hydrogel 有权
标题翻译：生产有机无机复合水凝胶的方法
公开(公告)号：JP2009046532A
公开(公告)日：2009-03-05
申请号：JP2007211315
申请日：2007-08-14
申请人： Dic Corp , Dic株式会社 , Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： MIYAMOTO MASANORI , HARAGUCHI KAZUTOSHI
IPC分类号： C08F2/44
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an organic-inorganic composite hydrogel by which the amount of a residual monomer can be made as small as possible without deteriorating high elasticity and toughness of a produced organic-inorganic composite hydrogel, and to further provide a method for producing an organic-inorganic composite hydrogel excellent in transparency and in deformation resistance at high temperature.
SOLUTION: The method for producing the organic-inorganic composite hydrogel includes preparing an aqueous dispersion in which a (meth)acrylamide-based monomer and a water-swellable clay mineral are dispersed in water or a liquid mixture of water and an organic solvent, and polymerizing the monomer in a polymerization temperature range of 40-100°C in the absence of a polymerization catalyst.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：为了提供一种制备有机 - 无机复合水凝胶的方法，其中残留单体的量可以制得尽可能小，而不会降低生产的有机 - 无机复合水凝胶的高弹性和韧性，并进一步提供一种在高温下透明性和耐变形性优异的有机 - 无机复合水凝胶的制造方法。解决方案：制备有机 - 无机复合水凝胶的方法包括制备水分散体，其中（甲基）丙烯酰胺类单体和水溶胀性粘土矿物分散在水中或水和有机物的液体混合物中溶剂，并在不存在聚合催化剂的情况下在40-100℃的聚合温度范围内使单体聚合。版权所有（C）2009，JPO＆INPIT

6. 发明专利

JP2008280208A Porous body 有权
标题翻译：多孔体
公开(公告)号：JP2008280208A
公开(公告)日：2008-11-20
申请号：JP2007125508
申请日：2007-05-10
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： MURATA KAZUTAKA , HARAGUCHI KAZUTOSHI
IPC分类号： C01B33/44 , C08F2/44
摘要： PROBLEM TO BE SOLVED: To provide a porous body which has excellent adsorption capability, has a large surface area usable as an adsorption material or a separation/filter material, has a pore diameter of submicromer size, and is formed by using a layered clay mineral. SOLUTION: The porous body has pores (a) each isolated by a layer formed of a layered clay mineral (A) and each having a pore diameter of 20-500 nm. In the porous body, the layer formed of the layered clay mineral (A) has a thickness of 3-100 nm and fine pores (b) each having a pore diameter of COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供吸附能力优异的多孔体，具有可用作吸附材料或分离/过滤材料的大的表面积，具有亚微米尺寸的孔径，并且通过使用层状粘土矿物。解决方案：多孔体具有孔（a），每个孔由层状粘土矿物（A）形成的层分离，每个孔具有20-500nm的孔径。在多孔体中，由层状粘土矿物（A）形成的层的厚度为3〜100nm，通过表面积测定测定的孔径为20nm的细孔（b）。版权所有（C）2009，JPO＆INPIT

7. 发明专利

JP2008247961A Polymer gel complex and method for producing the same 审中-公开
标题翻译：聚合物凝胶复合物及其制造方法
公开(公告)号：JP2008247961A
公开(公告)日：2008-10-16
申请号：JP2007087573
申请日：2007-03-29
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI , RI KANGUN
IPC分类号： C08L101/14 , C08K3/22 , C08K3/34
摘要： PROBLEM TO BE SOLVED: To provide a polymer gel material having high elastic modulus, strength, mechanical toughness and controlled low swelling property and excellent in whiteness and paramagnetism. SOLUTION: The invention provides a polymer gel complex obtained by complexing a polymer gel comprising (A) a polymer derived from a water-soluble organic monomer and (B) a water swellable clay mineral with (C) a metal oxide in a finely dispersed state, and a method for producing the complex. The gel of the invention has excellent mechanical properties controlled over a wide range and a controlled low swelling property and is excellent in whiteness, paramagnetism, etc. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有高弹性模量，强度，机械韧性和受控的低溶胀性能以及优异的白度和顺磁性的聚合物凝胶材料。解决方案：本发明提供了一种聚合物凝胶络合物，其通过使聚合物凝胶络合，其包含（A）衍生自水溶性有机单体的聚合物和（B）水溶胀性粘土矿物与（C）金属氧化物的聚合物凝胶，细分散状态，以及该复合体的制造方法。本发明的凝胶具有优异的机械性能，可在宽范围内控制，控制低溶胀性，白度，顺磁性等优异。版权所有（C）2009，JPO＆INPIT

8. 发明专利

JP2008156406A Heat-conducting material 有权
标题翻译：导热材料
公开(公告)号：JP2008156406A
公开(公告)日：2008-07-10
申请号：JP2006344162
申请日：2006-12-21
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI
IPC分类号： C09K5/08 , C08K3/34 , C08K5/00 , C08L33/26 , H01L23/36
摘要： PROBLEM TO BE SOLVED: To provide a highly safe heat-conducting material having not only good heat conductivity, but also excellent compressibility and adhesiveness to a base material, and hardly causing liquid leakage.
SOLUTION: The heat-conducting material has a structure obtained by binding (A) a polymer gel member with (B) a heat-radiating member, wherein the polymer gel member contains (E) a thermoconductive medium in a three-dimensional network formed by compounding (C) a water-swellable clay mineral with (D) a polymer of a (meth)acrylamide-based compound. The heat-conducting material having mechanical toughness and hardly causing liquid leakage is obtained by sticking the polymer gel having the three-dimensional network comprising the polymer of the acrylamide-based compound and the water-swellable clay mineral to a heat-radiating member to laminate them.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种高度安全的导热材料，其不仅具有良好的导热性，而且对基材具有优异的压缩性和粘合性，并且几乎不引起液体渗漏。导热材料具有通过将（A）聚合物凝胶构件与（B）散热构件结合而获得的结构，其中聚合物凝胶构件包含（E）三维导热介质通过将（C）水溶胀性粘土矿物与（D）（甲基）丙烯酰胺类化合物的聚合物混合而形成的网络。具有机械韧性并且几乎不引起液体渗漏的导热材料通过将具有包含丙烯酰胺类化合物和水溶胀性粘土矿物的聚合物的具有三维网络的聚合物凝胶粘贴到散热构件而获得，他们。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2007177014A Borate group-containing allylamine polymer 审中-公开
标题翻译：含硼酸基的聚氨酯聚合物
公开(公告)号：JP2007177014A
公开(公告)日：2007-07-12
申请号：JP2005374741
申请日：2005-12-27
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08F30/06
摘要： PROBLEM TO BE SOLVED: To provide a polymer having new sugar chain recognition ability which contains allylamine borate units in the polymer skeleton.
SOLUTION: A borate group-containing allyl monomer obtained by reacting allylamine with an inexpensive boric acid is homopolymerized or copolymerized with a different monomer to obtain a borate group-containing allylamine polymer having sugar chain recognition ability which contains a borate group in the molecule and has inherent viscosity of 0.1-6 dL/g. The polymer can be highly biocompatible because it is hydrophilic and is excellent in sugar chain recognition ability. Further, the content of boron can be made higher than that in a conventional hydrophilic copolymer of phenylboric acid.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供在聚合物骨架中含有烯丙胺硼酸酯单元的具有新的糖链识别能力的聚合物。解决方案：将烯丙胺与廉价的硼酸反应得到的含硼酸酯基的烯丙基单体与不同的单体进行均聚或共聚，得到含有硼酸酯基的具有糖链识别能力的含有硼酸酯基的烯丙胺聚合物，其中含有硼酸根基团分子，其特性粘度为0.1-6 dL / g。聚合物由于是亲水性的并且具有优异的糖链识别能力，因此可以具有高生物相容性。此外，硼的含量可以比常规的苯基硼酸的亲水性共聚物的含量高。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2007125762A Polymer gel laminate and its manufacturing method 审中-公开
标题翻译：聚合物凝胶层压板及其制造方法
公开(公告)号：JP2007125762A
公开(公告)日：2007-05-24
申请号：JP2005319436
申请日：2005-11-02
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： TAKEHISA KAN , HARAGUCHI KAZUTOSHI
IPC分类号： B32B27/30 , B32B27/20
摘要： PROBLEM TO BE SOLVED: To provide a polymer gel laminate capable of preventing the drying of a polymer gel having a three-dimensional reticulated structure, which is constituted of an amide group-containing polymer and a clay mineral, over a long time. SOLUTION: A polymer gel can be utilized while ensuring the excellent physical properties of the polymer gel by the polymer gel laminate having a laminated structure of a layer comprising a polymer gel having a three-dimensional reticulated structure constituted of the amide group-containing polymer and the clay mineral and a layer comprising a flexible member with a steam permeability of 100 g/m 2 /24 hr×100 μm or below. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够长时间防止由含酰胺基聚合物和粘土矿物构成的具有三维网状结构的聚合物凝胶的聚合物凝胶层压体。解决方案：可以使用聚合物凝胶，同时通过具有层叠结构的聚合物凝胶层压体来确保聚合物凝胶的优异物理性能，所述层压结构包含具有由酰胺基团形成的三维网状结构的聚合物凝胶，含水聚合物和粘土矿物，以及包含蒸气渗透率为100g / m 2 / 24hr×100μm以下的柔性构件的层。版权所有（C）2007，JPO＆INPIT

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