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    • 1. 发明专利
    • Liquid detergent composition for clothing
    • 液体洗涤剂组合物
    • JP2014141631A
    • 2014-08-07
    • JP2013155218
    • 2013-07-26
    • Kao Corp花王株式会社
    • KITA AYAKOYANAGISAWA YUKIMAKI MASATAKA
    • C11D17/08C11D1/29C11D1/72C11D1/722C11D1/86C11D3/43D06F35/00
    • PROBLEM TO BE SOLVED: To provide a liquid detergent composition for clothing, which exhibits sufficient detergency even when washing time is short.SOLUTION: The liquid detergent composition for clothing comprises (a) a nonionic surfactant represented by the general formula (1), (b) an anionic surfactant represented by the general formula (2), (c) an organic solvent having at least one hydroxyl group, and water, wherein a mass ratio, (b)/(a), of an amount of the (a) component blended and the amount of the (b) component blended is 0.5 or more but 10 or less. RO-(EO)H (1)[in the formula, Ris a hydrocarbon group having 8 to 18 carbon atoms; EO represents an ethyleneoxy group; m represents an average number of moles of addition in a range of 1 to 10]. RO-(AO)-(EO)-SOM (2) [in the formula, Rrepresents a hydrocarbon group having 8 to 22 carbon atoms; AO represents an alkyleneoxy group having 3 carbon atoms and/or an alkyleneoxy group having 4 carbon atoms; EO represents an ethyleneoxy group; p and q each independently represents an average number of moles of addition in a range of 0.5 to 5; and M represents a cation].
    • 要解决的问题:提供一种衣服用液体洗涤剂组合物,即使在洗涤时间短的情况下也显示出足够的去污力。溶液:衣服用液体洗涤剂组合物包含(a)由通式(1)表示的非离子表面活性剂,( b)由通式(2)表示的阴离子表面活性剂,(c)具有至少一个羟基的有机溶剂和水,其中(a)的量(b)/(a) )组分,并且(b)组分的混合量为0.5以上且10以下。 RO(EO)H(1)[式中,R为碳原子数为8〜18的烃基, EO表示乙烯氧基; m表示1〜10的平均加成摩尔数]。 RO-(AO) - (EO)-SOM(2)[式中,R表示碳原子数为8〜22的烃基, AO表示具有3个碳原子的亚烷基氧基和/或具有4个碳原子的亚烷基氧基; EO表示乙烯氧基; p和q各自独立地表示在0.5至5的范围内的平均加成摩尔数; M表示阳离子]。
    • 2. 发明专利
    • Washing method and granular detergent composition
    • 洗涤方法和颗粒洗涤剂组合物
    • JP2007077390A
    • 2007-03-29
    • JP2006220957
    • 2006-08-14
    • Kao Corp花王株式会社
    • KASAI KATSUHIKOYANAGISAWA YUKIMIZUSAWA KIMIHIRO
    • C11D3/37C08F28/02C11D1/22C11D17/06
    • C11D3/378
    • PROBLEM TO BE SOLVED: To provide a washing method by which an unpleasant factor and a physical load caused when carrying out washing by hand, i.e. the mental and physical loads are improved, and which is excellent in properties for preventing resoiling with mud particles; and to provide a granular detergent composition suitable for the method. SOLUTION: The method for washing a material to be washed in a washing bath containing an anionic surfactant, a builder for scavenging hardness components, an alkaline material and a sulfonic acid-based polymer which contains 50-100 mol% specific monomer unit based on the whole constituent monomer units and has 1,000,000-30,000,000 weight average molecular weight, comprises bringing the anionic surfactant the whole or a part of which is dissolved in the washing bath into contact with the material to be washed, and further bringing the resultant product into contact with the sulfonic acid-based polymer. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种洗涤方法,其中通过手动进行洗涤时引起的不愉快因素和物理负荷(即精神和物理负荷)得到改善,并且具有优异的用于防止用泥浆再开采的性质 粒子; 并提供适合该方法的颗粒状洗涤剂组合物。 解决方案:在含有阴离子表面活性剂的洗涤浴中洗涤材料的方法,用于清除硬度成分的助洗剂,碱性材料和含有50-100摩尔%特定单体单元的磺酸基聚合物的方法 基于整个构成单体单元,具有1,000,000-30,000,000重均分子量,包括使其全部或一部分溶解在洗涤槽中的阴离子表面活性剂与待洗涤材料接触,并进一步将所得产物 与磺酸基聚合物接触。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2010121045A
    • 2010-06-03
    • JP2008296268
    • 2008-11-20
    • Kao Corp花王株式会社
    • YANAGISAWA YUKIOSUMI TAKAHIRO
    • C11D3/37
    • PROBLEM TO BE SOLVED: To provide a detergent composition which exhibits a sufficient effect of preventing stains from reattaching in the washing condition such that the reattachment of stains is promoted due to a small amount of water used.
      SOLUTION: The detergent composition contains (a) a polymer composed of a constituting unit (A) of at least one monomer unit selected from a polyethylene glycol mono(meth)acrylate, methoxypolyethylene glycol (meth)acrylate, and polyethylene glycol monoallyl ether, the polyethylene glycol having an average polymerization degree of 1-200 and the like and a constituting unit (B) of a polymer having at least one monomer unit selected from a 1-22C alkyl (meth)acrylate, an alkenyl (meth)acrylate, an alkylvinyl ester, an alkenylvinyl ester, and benzyl (meth)acrylate which may have one hydroxyl group as a substituent and the like and (b) a smectite type clay mineral.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种洗涤剂组合物,其具有足够的防止污渍在洗涤条件下重新附着的效果,使得由于所用的少量水而促进污渍的重新附着。 洗涤剂组合物含有(a)由选自聚乙二醇单(甲基)丙烯酸酯,甲氧基聚乙二醇(甲基)丙烯酸酯和聚乙二醇单烯丙基酯的至少一种单体单元的构成单元(A) 乙醚,平均聚合度为1-200的聚乙二醇等,以及具有至少一个选自1-22℃(甲基)丙烯酸烷基酯,(甲基) 丙烯酸酯,烷基乙烯基酯,烯基乙烯基酯和可以具有一个羟基作为取代基的(甲基)丙烯酸苄酯等,(b)蒙脱石型粘土矿物。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2007051179A
    • 2007-03-01
    • JP2005235551
    • 2005-08-15
    • Kao Corp花王株式会社
    • MIZUSAWA KIMIHIROYANAGISAWA YUKIKASAI KATSUHIKO
    • C11D3/37C11D17/06
    • PROBLEM TO BE SOLVED: To provide a powdery detergent composition for clothes exhibiting high detergent power to sebum stain, mud stain and their composite stain while reducing the physical and mental load in hand washing, etc.
      SOLUTION: The powdery detergent composition for clothes contains (a) a polymer having a weight-average molecular weight of ≥1,000,000 and containing ≥70 wt.% monomer unit having a sulfonic acid group or its salt-type group and/or sulfuric acid group or its salt-type group in the polymer and (b) a polymer having a weight-average molecular weight of 1,000-300,000 and containing ≥50 mol% monomer unit in the polymer.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种在洗涤时减轻身体和精神负担的皮肤污渍,泥浆污渍及其复合污渍的具有高洗涤能力的衣物的粉末洗涤剂组合物。解决方案: 用于衣服的洗涤剂组合物包含(a)重均分子量≥1,000,000并且含有≥70重量%具有磺酸基团或其盐类基团和/或硫酸基团的单体单元或其盐 - 型聚合物,(b)聚合物中重均分子量为1000〜30000,含有≥50摩尔%的单体单元的聚合物。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Method of washing
    • 洗涤方法
    • JP2006199969A
    • 2006-08-03
    • JP2006044326
    • 2006-02-21
    • Kao Corp花王株式会社
    • YANAGISAWA YUKIKASAI KATSUHIKOIMAIZUMI YOSHINOBUKATSUTA HIROAKIOKI KAZUOTAKIGUCHI HITOSHIMASUDA TAKUYAYAMAGUCHI OSAMU
    • C11D3/37C11D3/39
    • PROBLEM TO BE SOLVED: To provide a method for improving the slip properties of a washing, when the washing is carried out by hand at home, to provide a method of washing, by which unpleasant factors such as (roughness) or (creaking) and physical feebleness can be reduced and hands and washings are cared, to provide a detergent composition for realizing the same, and to provide an agent for improving the slip properties. SOLUTION: This method for improving the slip properties of a washing in a washing liquid, which comprises causing an organic polymer having stringiness to be present in the washing liquid during washing. The washing liquid contains an organic polymer having stringiness and exhibits stringiness. A method of washing by hand which comprises the step of hand-washing a washing with a washing liquid obtained by diluting that washing liquid with water to more than a 1-fold to 1, 000-fold amount. A detergent composition which contains more than 0.1 wt.% organic polymer having an average molecular weight of 1,500,000 or higher and having stringiness. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种改善洗涤的滑移性的方法,当在家中手工进行洗涤时,提供一种洗涤方法,通过这种方法,诸如(粗糙度)或( 吱吱作响)和身体虚弱,可以减少手和洗涤液,以提供用于实现其的洗涤剂组合物,并提供用于改善滑动性能的试剂。 解决方案:用于改善洗涤液中洗涤物的滑爽性的方法,其包括使洗涤液中洗涤液中存在具有拉丝性的有机聚合物。 洗涤液含有具有拉丝性的有机聚合物,具有拉丝性。 一种手洗方法,其特征在于,将洗涤液用水稀释至1倍以上-1000倍以下的洗涤液进行洗涤。 一种洗涤剂组合物,其含有大于0.1重量%的平均分子量为1,500,000以上且具有拉丝性的有机聚合物。 版权所有(C)2006,JPO&NCIPI
    • 6. 发明专利
    • Liquid detergent composition for clothing
    • 液体洗涤剂组合物
    • JP2014129462A
    • 2014-07-10
    • JP2012287714
    • 2012-12-28
    • Kao Corp花王株式会社
    • KITA AYAKOYANAGISAWA YUKIMAKI MASATAKA
    • C11D17/08C11D1/29C11D1/72C11D1/722C11D3/20C11D3/43
    • PROBLEM TO BE SOLVED: To provide a liquid detergent composition for clothing exhibiting sufficient detergency even with short washing time.SOLUTION: There is provided a liquid detergent composition manufactured by blending (a) a non-ion surfactant represented by the general formula (1), (b) an anionic surfactant represented by the general formula (2), and a specified quantity of (c) an organic solvent having one or more hydroxyl group in a molecule and water, and having a mass ratio between the blended quantity of the (a) component and the blended quantity of the (b) component, (b)/(a) of 0.4 to 10. RO-(EO)H (1), where Ris a hydrocarbon group having 8 to 18 carbon atoms, EO is an ethylene oxy group, m is an average addition molar number. RO-(EO)-(AO)-SOM (2), where Ris a hydrocarbon group having 8 to 22 carbon atoms, AO is an alkylene oxy group having 3 carbon atoms and/or an alkylene oxy group having 4 carbon atoms, EO is an ethylene oxy group, p and q are each an average addition molar number of 0.5 to 5 and M is a cation.
    • 本发明提供一种液体洗涤剂组合物,其通过将(a)由通式(1)表示的非离子表面活性剂, ,(b)由通式(2)表示的阴离子表面活性剂和规定量的(c)分子中具有一个以上羟基的有机溶剂和水,并且具有 (a)组分和(b)成分的混合量,(b)/(a)为0.4-10。RO-(EO)H(1),其中R为具有8至18个碳原子的烃基,EO 是乙烯氧基,m是平均加成摩尔数。 RO(EO) - (AO)-SOM(2),其中R是具有8至22个碳原子的烃基,AO是具有3个碳原子的亚烷基氧基和/或具有4个碳原子的亚烷基氧基,EO 是乙烯氧基,p和q各自为平均加成摩尔数为0.5〜5,M为阳离子。
    • 7. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2008222971A
    • 2008-09-25
    • JP2007067331
    • 2007-03-15
    • Kao Corp花王株式会社
    • YAMADA ISAOYANAGISAWA YUKI
    • C11D3/37C11D1/72C11D3/20C11D3/34C11D3/395D06L1/12D06L3/02
    • PROBLEM TO BE SOLVED: To provide a detergent composition for clothing which contains a specific polymer making difficult the re-attachment of soot stains or dust stains having been released from clothing i.e. preventing the clothing from being re-stained, and further a detergent composition for clothing which prevents re-staining even in use of clothing or towels having been treated with a softener in a rinse cycle.
      SOLUTION: The detergent composition comprises (a) a copolymer which has a constitutional unit derived from N-vinyl pyrolidone and a constitutional unit derived from N-vinyl imidazole in a mole ratio (N-vinyl pyrolidone/N-vinyl imidazole) in the copolymer of 10/90-50/50 and a weight average molecular weight of 10,000-100,000, (b) a nonionic surfactant containing a polyoxyalkylene alkyl ether and (c) a polyethylene glycol having a weight average molecular weight of 2,000-20,000.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种含有特定聚合物的衣物用洗涤剂组合物,其难以重新附着已经从衣服中释放的烟丝污渍或灰尘污渍,即防止衣物再染色,并且进一步 用于衣服的洗涤剂组合物,即使在使用在漂洗循环中用软化剂处理过的衣物或毛巾也可防止再染色。 解决方案:洗涤剂组合物包含(a)具有衍生自N-乙烯基吡咯烷酮的结构单元和以N-乙烯基吡咯烷酮/ N-乙烯基咪唑的N-乙烯基咪唑衍生的结构单元的共聚物, 在10 / 90-50 / 50和重均分子量为10,000-100,000的共聚物中,(b)含有聚氧化烯烷基醚的非离子表面活性剂和(c)重均分子量为2,000-20,000的聚乙二醇 。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2008189719A
    • 2008-08-21
    • JP2007023153
    • 2007-02-01
    • Kao Corp花王株式会社
    • YANAGISAWA YUKIMITSUYOSHI KUNIAKIUENO WATARUYAMADA ISAO
    • C11D1/83C11D1/72C11D3/12C11D3/37C11D17/06D06L1/12
    • C11D1/83C11D1/72C11D3/126
    • PROBLEM TO BE SOLVED: To provide a detergent composition capable of exhibiting sufficient preventing effects on soil redeposition under washing conditions resulting in promotion of the soil redeposition particularly because of a small amount of water used in order to prevent blackening of a material to be washed in washing carried out at home.
      SOLUTION: The detergent composition comprises (a) a nonionic surfactant containing a polyoxyalkylene alkyl ether having 4-8 average addition molar number of an alkylene oxide, (b) an anionic surfactant (without containing a fatty acid and a salt thereof) and (c) ≥3 wt.% of a clay mineral represented by general formula (I): [Si
      8 (Mg
      a Al
      b )O
      20 (OH)
      4 ]
      X- -Me
      X+ (I) (wherein, 0 4 ). The weight ratio [(a)/(b)] of the component (a) to the component (b) is >1 to
    • 待解决的问题:提供一种洗涤剂组合物,其能够在洗涤条件下对土壤再沉积具有足够的预防作用,导致促进土壤再沉积,特别是因为为了防止材料变黑而使用少量的水 在家洗涤洗涤。 洗涤剂组合物包含(a)含有具有4-8平均加成摩尔数的环氧烷的聚氧化烯烷基醚的非离子表面活性剂,(b)阴离子表面活性剂(不含脂肪酸及其盐) 和(c)≥3重量%的由通式(I)表示的粘土矿物:[Si 8 )O(S)(I)(其中,0 1至<5。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2010065116A
    • 2010-03-25
    • JP2008232135
    • 2008-09-10
    • Kao Corp花王株式会社
    • UENO WATARUKUBOTA TERUOHASUMI KIJIYANAGISAWA YUKI
    • C11D3/12C11D1/83C11D3/08C11D17/06
    • PROBLEM TO BE SOLVED: To provide a high bulk density detergent composition having good dispersibiility in water at low temperature, high detergency, and abilities to prevent darkening of substance to be washed such as clothes (darkening prevention ability) and to impart flexibility to clothes, by using granulated clay having a particular range of swelling power.
      SOLUTION: The detergent composition comprises: (A) a granulated clay of 1-30 wt.% containing (a) a clay mineral of more than 70 wt.% in the granulated clay, and having swelling power of 10-30 mL/2g; (b) a nonionic surfactant of 0.5-20 wt.%; (c) an anionic surfactant (excluding fatty acid salts) of 0.5-20 wt.%; (d) an alkali agent of 1-60 wt.% (provided that the contents of the crystalline and non-crystalline alkali metal silicates, respectively, is not more than 6 wt.%); and (e) an aluminosilicate of 1-50 wt.%.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种在低温下具有良好分散性的高体积密度洗涤剂组合物,高洗涤性和防止衣物等被洗涤物质变暗的能力(防晕能力),赋予柔软性 通过使用具有特定范围的溶胀力的颗粒状粘土来进行衣服。 洗涤剂组合物包括:(A)1-30重量%的颗粒状粘土,其含有(a)超过70重量%的粘土矿物,其粒度为10-30 毫升/ 2G; (b)0.5-20重量%的非离子表面活性剂; (c)0.5-20重量%的阴离子表面活性剂(不包括脂肪酸盐); (d)1-60重量%的碱剂(分别为结晶态和非结晶性碱金属硅酸盐的含量不超过6重量%); 和(e)1-50重量%的硅铝酸盐。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Detergent composition
    • 洗涤剂组合物
    • JP2010001421A
    • 2010-01-07
    • JP2008162994
    • 2008-06-23
    • Kao Corp花王株式会社
    • MITSUYOSHI KUNIAKIYANAGISAWA YUKI
    • C11D3/12C11D1/83C11D3/37D06M11/79D06M15/263
    • PROBLEM TO BE SOLVED: To provide a dirt transfer inhibitor capable of developing enough dirt readhesion prevention effectiveness at washing conditions in homes, particularly at washing conditions easy to promote the dirt readhesion because of a little usage of water as used in drum type washers, and to provide a detergent composition containing the inhibitor.
      SOLUTION: This dirt transfer inhibitor comprises a modified smectite clay mineral produced by catalytically treating an acrylic acid polymer and a smectite clay mineral in the presence of an aqueous medium.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种能够在家庭中的洗涤条件下,特别是在易于促进由于在鼓式中使用的水的少量使用而引起的污物再现性的洗涤条件下能够发挥足够的污垢再次粘附防止效果的污垢转移抑制剂 垫圈,并提供含有抑制剂的洗涤剂组合物。 解决方案:该污垢转移抑制剂包括通过在水介质的存在下催化处理丙烯酸聚合物和蒙脱石粘土矿物而制备的改性蒙脱石粘土矿物。 版权所有(C)2010,JPO&INPIT