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    • 1. 发明专利
    • Manufacturing method of solid detergent
    • 固体洗涤剂的制造方法
    • JP2014025013A
    • 2014-02-06
    • JP2012167804
    • 2012-07-27
    • Kao Corp花王株式会社
    • NONAKA NOBUHIROIMAIZUMI YOSHINOBUISHIMARU WAKANA
    • C11D11/00C11D1/68C11D3/33C11D3/37C11D3/395C11D17/06
    • PROBLEM TO BE SOLVED: To provide a solid detergent excellent in washability, solubility and storage stability, and to provide a manufacturing method thereof.SOLUTION: A manufacturing method of a solid detergent includes following process 1 and 2. Process 1: a process of mixing a compound (an A Component) represented by the following general formula (1) and a nonionic detergent (a B Component) having a melting point of 50 to 90°C at a higher temperature than the melting point of the B Component to obtain a mixture containing 10 to 90 mass% of the A Component and 1 to 50 mass% of the B Component, where R represents a hydrocarbon group having 1 to 12 carbon atoms and M, M, Mrepresents each independently one kind selected from a hydrogen atom, an alkali metal, ammonium, alkanolamine and alkylamine. Process 2: a process of obtaining a granule of the mixture obtained in process 1.
    • 要解决的问题:提供洗涤性,溶解性和储存稳定性优异的固体洗涤剂,并提供其制造方法。溶液:固体洗涤剂的制造方法包括以下处理1和2.方法1:混合过程 在下述通式(1)表示的化合物(A成分)和比B成分的熔点高的熔点为50〜90℃的非离子型洗涤剂(B成分),得到 含有10〜90质量%的A成分和1〜50质量%的B成分的混合物,其中R表示碳原子数1〜12的烃基,M,M,M分别独立地表示选自氢原子, 碱金属,铵,链烷醇胺和烷基胺。 方法2:获得在方法1中获得的混合物颗粒的方法。
    • 3. 发明专利
    • Method for producing high bulk density detergent granules
    • 用于生产高密度密度洗涤剂颗粒的方法
    • JP2011026583A
    • 2011-02-10
    • JP2010147330
    • 2010-06-29
    • Kao Corp花王株式会社
    • KAWAMOTO KENICHIROIMAIZUMI YOSHINOBUKAMEI TAKASHI
    • C11D11/00B01J2/00B01J2/10B01J2/12B01J2/14C11D1/14C11D3/10C11D17/06
    • C11D17/065C11D1/146C11D3/10C11D11/0082
    • PROBLEM TO BE SOLVED: To produce detergent granules having a good yield of high-density detergent granules with a required grain size using a base granules obtained by a method free from spray drying, for carrying a surfactant composition and the surfactant composition containing an anionic surfactant. SOLUTION: The method for producing detergent granules having a bulk density of not less than 650 g/L comprises the following steps 1-3. Step 1: a step wherein starting material powders having an oil absorption capacity of not less than 0.4 mL/g are mixed. Step 2: a step wherein water or an aqueous binder solution is added to the powder mixture obtained in the step 1 and a base granules are prepared using a low-shear granulator. Step 3: a step wherein the base granules obtained in the step 2 is mixed with a surfactant composition containing an anionic surfactant and water. COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:为了生产具有所需晶粒尺寸的高密度洗涤剂颗粒的洗涤剂颗粒,使用通过不经喷雾干燥的方法获得的基础颗粒,用于承载表面活性剂组合物和含有 阴离子表面活性剂。 解决方案:堆积密度不小于650g / L的洗涤剂颗粒的制备方法包括以下步骤1-3。 步骤1:将具有不小于0.4mL / g的吸油量的原料粉末混合的步骤。 步骤2:向步骤1中获得的粉末混合物中加入水或粘合剂水溶液的步骤,并使用低剪切制粒机制备基础颗粒。 步骤3:将步骤2中获得的基础颗粒与含有阴离子表面活性剂和水的表面活性剂组合物混合的步骤。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Composite powder
    • 复合粉
    • JP2009155573A
    • 2009-07-16
    • JP2007338041
    • 2007-12-27
    • Kao Corp花王株式会社
    • KUME TOSHIMASAOKI KAZUOHASUMI KIJIIMAIZUMI YOSHINOBU
    • C11D3/08C11D3/12C11D17/06
    • PROBLEM TO BE SOLVED: To provide a composite powder having improved storage stability of alkali metal silicate, and to provide a zeolite compounding cleaner composition comprising the composite powder. SOLUTION: The composite powder having an average particle size of 1 to 1,000 μm consists of alkali metal silicate particles (A) having an average particle size of 1 to 200 μm, of 25 to 90 mass%, and clay mineral particles (B) having an average particle size of 0.01 to 50 μm, of 10 to 75 mass%. The zeolite compounding cleaner composition containing the composite powder is also provided. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有改善的碱金属硅酸盐的储存稳定性的复合粉末,并提供包含复合粉末的沸石复合清洁剂组合物。 平均粒径为1〜1000μm的复合粉末由平均粒径为1〜200μm的碱金属硅酸盐粒子(A)为25〜90质量%,粘土矿物粒子( B)平均粒径为0.01〜50μm,为10〜75质量%。 还提供了含有复合粉末的沸石复合清洁剂组合物。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Additive for powder clothes detergents
    • 添加剂用于粉末衣物洗涤剂
    • JP2009144116A
    • 2009-07-02
    • JP2007325656
    • 2007-12-18
    • Kao Corp花王株式会社
    • ASADA TADANOBUIMAIZUMI YOSHINOBU
    • C11D17/06C11D3/04C11D3/08C11D3/12C11D3/37C11D7/10C11D7/14C11D7/22
    • PROBLEM TO BE SOLVED: To provide an additive for powder clothes detergents obtained by granulating an alkali metal silicate together with a carboxylic acid-based polymer, a water-soluble inorganic salt, and at need, a small amount of an aluminosilicate, and reduced in the generation of a water-insoluble matter.
      SOLUTION: The additive for powder clothes detergents contains an alkali metal silicate (A) having a composition, of which the anhydride is expressed by formula (I): xM
      2 O-ySiO
      2 -zMeO, wherein M shows Na and/or K, Me shows Ca and/or Mg, y/x=0.5-4.0, z/x=0-1.0 and Mg/Ca in MeO is 0-10, average particle size is 1-50 μm; a carboxylic acid-based polymer (B), of which the weight-average molecular weight is 1,000-300,000; a water-soluble inorganic salt (C), of which the solubility in 100 g of water at 20°C is 1 g or more and average particle size is 1-400 μm, provided that the component (A) is excluded; and 0-5 wt.% of an aluminosilicate (D).
      COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供通过将羧酸基聚合物,水溶性无机盐和需要少量铝硅酸盐与碱金属硅酸盐一起制粒而获得的粉末衣物洗涤剂添加剂, 并减少了不溶于水的物质的产生。 解决方案:粉末洗涤剂添加剂含有具有组成的碱金属硅酸盐(A),其中酸酐由式(I)表示:xM O-ySiO 其中M表示Na和/或K,Me表示Ca和/或Mg,y / x = 0.5-4.0,z / x = 0-1.0,MeO中的Mg / Ca为0-10 ,平均粒径为1-50μm; 羧酸类聚合物(B),其重均分子量为1000〜300,000; 只要不排除组分(A),其水溶性无机盐(C)的溶解度在100g水中,在20℃下为1g以上,平均粒径为1-400μm。 和0-5重量%的硅铝酸盐(D)。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Slipping property-improving agent granulate for washing
    • 拖车用品改良剂用于洗涤剂
    • JP2005248141A
    • 2005-09-15
    • JP2004145636
    • 2004-05-14
    • Kao Corp花王株式会社
    • KATSUTA HIROAKIIMAIZUMI YOSHINOBU
    • D06L1/12C11D3/12C11D17/06
    • PROBLEM TO BE SOLVED: To provide a slipping property-improving agent granulate for washing which maintains improved slipping properties between objects to be washed and makes hand-washing easy by ready washability with weak force or by an increase in a scrubbing speed (the number of scrubbing per time) of objects to be washed regardless of whether objects to be washed are kept soaking or not without causing imperfect dissolution or adhesion to clothes of potassium metaphosphate, and a detergent composition comprising the slipping property-improving agent granulate for washing.
      SOLUTION: The slipping-improving agent granulate for washing comprises potassium metaphosphate. The detergent composition comprises the slipping-improving agent granulate for washing and a solubilizing agent. The detergent composition comprises the slipping-improving agent granulate for washing.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种用于洗涤的滑动性改进剂颗粒,其在待洗涤物体之间保持改善的滑动性能,并且通过弱力即可洗涤性或通过提高洗涤速度使洗手容易( 不管洗涤物是否保持浸泡,而不引起不适当的溶解或粘附到偏磷酸钾的衣物上,洗涤物体的洗涤次数,以及包含用于洗涤的滑动性改善剂颗粒的洗涤剂组合物 。 解决方案:用于洗涤的滑爽改进剂颗粒包括偏磷酸钾。 洗涤剂组合物包含用于洗涤的滑爽改进剂颗粒和增溶剂。 洗涤剂组合物包含用于洗涤的滑爽改进剂颗粒。 版权所有(C)2005,JPO&NCIPI
    • 7. 发明专利
    • Solid detergent composition
    • 固体洗涤剂组合物
    • JP2014148660A
    • 2014-08-21
    • JP2013154016
    • 2013-07-24
    • Kao Corp花王株式会社
    • ISHIMARU WAKANAIMAIZUMI YOSHINOBUONODA KEIICHINONAKA NOBUHIRO
    • C11D3/33C11D3/08C11D3/20C11D3/37C11D3/39C11D3/395C11D7/14C11D7/18C11D7/26C11D11/00C11D17/06
    • C11D3/33C11D3/3761C11D7/3245
    • PROBLEM TO BE SOLVED: To provide an extrusion granule low in fine particle ratio, fracture load, i.e. having little stickiness and excellent flowability even when the content of GDA is high, a manufacturing method of the same, a solid detergent composition, use of the solid detergent composition, a coloring suppression method for suppressing coloring of the solid detergent composition.SOLUTION: There is provided an extrusion granule containing 25 to 90 mass% of a compound (A component) represented by the general formula (1) and 3 to 50 mass% of a polymer (B component) containing a constitutional unit derived from carboxylic acid having an active unsaturated group having 3 to 6 carbon atoms or a salt thereof, and having the total content of the A component and the B component in the granule of 28 to 95 mass%. In the formula (1), R represents a hydrocarbon group having 1 to 12 carbon atoms, M, Mand Meach independently represent one kind selected from a hydrogen atom, an alkali metal, ammonium, alkanol ammonium and alkylammonium.
    • 要解决的问题:为了提供即使当GDA含量高时,即使GDA含量高的微粒比率,断裂负荷即粘性小,流动性优异的挤出颗粒,其制造方法,固体洗涤剂组合物,使用 固体洗涤剂组合物,抑制固体洗涤剂组合物着色的着色抑制方法。本发明提供一种挤出颗粒,其含有25〜90质量%的通式(1)表示的化合物(A成分)和3〜50 含有来自具有3〜6个活性不饱和基团的羧酸的结构单元或其盐的聚合物(B成分)的质量%,其颗粒中的A成分和B成分的总含量 28〜95质量%。 在式(1)中,R表示碳原子数1〜12的烃基,M,Mand Meach独立地表示选自氢原子,碱金属,铵,链烷醇铵和烷基铵的一种。
    • 8. 发明专利
    • Pigment granule
    • 颜料颗粒
    • JP2014108952A
    • 2014-06-12
    • JP2012264595
    • 2012-12-03
    • Kao Corp花王株式会社
    • HORIBATA TATSUYAMATSUMOTO SHIGEIMAIZUMI YOSHINOBUMORIOKA MISAKO
    • A61K8/81A61K8/02A61K8/49A61Q19/10
    • PROBLEM TO BE SOLVED: To provide a pigment granule by which a detergent can be prevented from being colored while being stored and coloring of foam can be quickly developed during washing, a manufacturing method of the same, the detergent including the pigment granule, and a method of coloring foam during washing.SOLUTION: [1] A pigment granule comprises a pigment, a polyvinyl pyrrolidone, and a polyvinyl alcohol. The pigment granule includes the polyvinyl pyrrolidone whose viscosity characteristic value (K value) is 25 or less. [2] A detergent includes the pigment granule. [3] A manufacturing method of the pigment granule comprises a step of mixing (a) powder including a pigment, (b) a polyvinyl pyrrolidone solution, and (c) a polyvinyl alcohol solution to granulate. [4] A method of coloring foam during washing uses the pigment granule.
    • 要解决的问题:提供一种颜料颗粒,其可以防止洗涤剂在储存时着色,并且可以在洗涤期间快速显现泡沫的着色,其制备方法,包括颜料颗粒的洗涤剂和 在洗涤期间着色泡沫的方法。溶液:[1]颜料颗粒包含颜料,聚乙烯吡咯烷酮和聚乙烯醇。 颜料颗粒包括粘度特性值(K值)为25以下的聚乙烯吡咯烷酮。 [2]洗涤剂包括颜料颗粒。 颜料颗粒的制造方法包括混合(a)包含颜料的粉末,(b)聚乙烯吡咯烷酮溶液和(c)聚乙烯醇溶液进行颗粒化的步骤。 洗涤时泡沫的着色方法使用颜料颗粒。