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    • 3. 发明专利
    • Dye-sensitized solar battery, and dye-sensitized solar battery module
    • 透明的太阳能电池和透明的太阳能电池模块(DYE-SENSITIZED SOLAR BATTERY MODULE
    • JP2013239312A
    • 2013-11-28
    • JP2012110942
    • 2012-05-14
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Aisin Seiki Co Ltdアイシン精機株式会社
    • MORIBE MASAYAKATO NAOHIKOHIGUCHI KAZUODOI MASAKAZUMIZUMOTO KATSUYOSHITOYODA TATSUO
    • H01M14/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized solar battery using porphyrin-based dye, capable of further improving the durability.SOLUTION: A dye-sensitized solar battery module 10 comprises a plurality of dye-sensitized solar batteries 40. This dye-sensitized solar battery 40 comprises: a photoelectrode 20 having a porous semiconductor layer 24 including dye, on a transparent conductive substrate 14; a counter electrode 30 arranged so as to be opposed to the photoelectrode 20; and an electrolyte layer 26 including electrolytic solution intervening between the photoelectrode 20 and the counter electrode 30. The dye has a porphyrin structure. The electrolytic solution includes a guanidine compound. An anchor group, a substituent group, and an electron-donating functional group may be installed to this dye. In addition, the electrolytic solution may contain iodine-based ionic liquid, and contain guanidine thiocyanate as the guanidine compound.
    • 要解决的问题:提供使用卟啉系染料的染料敏化太阳能电池,能够进一步提高耐久性。解决方案:染料敏化太阳能电池模块10包括多个染料敏化太阳能电池40。 敏化太阳能电池40包括:在透明导电基板14上具有包含染料的多孔半导体层24的光电极20; 布置成与光电极20相对的对置电极30; 以及包含介于光电极20和对电极30之间的电解液的电解质层26.该染料具有卟啉结构。 电解液包括胍化合物。 可以向该染料安装锚定基团,取代基基团和给电子官能团。 此外,电解液可以含有碘基离子液体,并含有硫氰酸胍作为胍化合物。
    • 4. 发明专利
    • Solar battery
    • 太阳能电池
    • JP2013206901A
    • 2013-10-07
    • JP2012070741
    • 2012-03-27
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Aisin Seiki Co Ltdアイシン精機株式会社
    • IKUNO TAKASHIKATO NAOHIKOSUZUKI RYOITO MUTSUMIMIZUMOTO KATSUYOSHITOYODA TATSUO
    • H01L31/04
    • Y02E10/50
    • PROBLEM TO BE SOLVED: To further improve a power generation characteristic of a solar battery containing SnS.SOLUTION: A solar battery 10 according to the present invention comprises: a photoelectrode 12 having a translucent conductive substrate 14 with conductivity, a buffer layer 16 adjacent to the translucent conductive substrate 14 and transporting electrons, and a light absorption layer 18 containing SnS, adjacent to the buffer layer 16, and adsorbing light; a counter electrode 20; and a hole transport layer 22 formed between the photoelectrode 12 and the counter electrode 20. The translucent conductive substrate 14 has a Haze value in a range of 8% or more and 50% or less. Also, preferably, the translucent conductive substrate 14 has a surface roughness RMS value of a face adjacent to the buffer layer 16 in a range of 30 nm or more and 60 nm or less. Also, preferably, a surface roughness Ra value of the face adjacent to the buffer layer 16 is in a range of 150 nm or more and 250 nm or less.
    • 要解决的问题:进一步提高含有SnS的太阳能电池的发电特性。解决方案:根据本发明的太阳能电池10包括:具有导电性的半透明导电基板14的光电极12,与 半透明导电基板14和输送电子,以及与缓冲层16相邻的含有SnS的光吸收层18,并吸附光; 对电极20; 以及形成在光电极12和对电极20之间的空穴传输层22.透光性导电性基板14的雾度值为8%以上且50%以下。 此外,优选地,半透明导电性基板14在30nm以上且60nm以下的范围内具有与缓冲层16相邻的面的表面粗糙度RMS值。 此外,优选地,与缓冲层16相邻的面的表面粗糙度Ra值在150nm以上且250nm以下的范围内。
    • 9. 发明专利
    • Dye-sensitized solar battery, dye-sensitized solar battery module and method of manufacturing organic dye
    • 透明的太阳能电池,透明的太阳能电池模块和制造有机染料的方法
    • JP2014053263A
    • 2014-03-20
    • JP2012198699
    • 2012-09-10
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Aisin Seiki Co Ltdアイシン精機株式会社
    • MOGI HIROFUMITANAKA HIROMITSUKATO NAOHIKOHIGUCHI KAZUODOI MASAKAZUMIZUMOTO KATSUYOSHITOYODA TATSUO
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To improve the durability of a dye-sensitized solar battery.SOLUTION: A dye-sensitized solar battery module 10 includes a plurality of dye-sensitized solar batteries 40. Each dye-sensitized solar battery 40 includes: a photoelectrode 20 including a porous semiconductor layer 24 containing an organic dye on a transparent conductive substrate 14; a counter electrode 30 arranged so as to be opposed to the photoelectrode 20; and an electrolyte layer 26 including an electrolyte interposed between the photoelectrode 20 and the counter electrode 30. The organic dye has a cyanophosphoric acid group as an anchor group. The electrolyte contains ionic liquid. It is preferred that this dye has an indoline skeleton, and that the electrolyte includes an imidazolium salt. This organic dye is produced by a method of manufacturing an organic dye of introducing a phosphoric acid ester group to a compound having the indoline skeleton and an aldehyde group in acetonitrile, and performing hydrolysis of a reactant resulting from the introduction in dichloromethane by alcohol.
    • 要解决的问题:提高染料敏化太阳能电池的耐久性。解决方案:染料敏化太阳能电池模块10包括多个染料敏化太阳能电池40.每个染料敏化太阳能电池40包括:光电极20 包括在透明导电基板14上含有有机染料的多孔半导体层24; 布置成与光电极20相对的对置电极30; 以及包含介于光电极20和对电极30之间的电解质的电解质层26.有机染料具有作为锚定基团的氰基磷酸基团。 电解液含有离子液体。 优选该染料具有二氢吲哚骨架,并且该电解质包括咪唑鎓盐。 该有机染料是通过在乙腈中将具有二氢吲哚骨架和醛基的化合物引入磷酸酯基的有机染料的制造方法制造的,并且通过醇在二氯甲烷中引入反应物进行水解。
    • 10. 发明专利
    • Dye-sensitized solar battery
    • 透明的太阳能电池
    • JP2014041967A
    • 2014-03-06
    • JP2012184342
    • 2012-08-23
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Aisin Seiki Co Ltdアイシン精機株式会社
    • MORIBE MASAYAKATO NAOHIKOHIGUCHI KAZUOKAMIYAMA KOJIMIZUMOTO KATSUYOSHITOYODA TATSUO
    • H01L31/04H01L31/06H01M14/00
    • Y02E10/542Y02E10/549
    • PROBLEM TO BE SOLVED: To further enhance a solar battery property in a dye-sensitized solar battery of solid type.SOLUTION: A dye-sensitized solar battery 40 comprises: a photoelectrode 20 having a transparent conductive substrate 14 and a porous semiconductor layer 24 provided on the substrate and having a pigment; a solid p-type semiconductor layer 26 at least partially filled in pores in the porous semiconductor layer 24; and a counter electrode 30 opposed to the photoelectrode 20 so that the solid p-type semiconductor layer 26 is arranged therebetween. The pore diameter distribution of the porous semiconductor layer 24 shows the maximum in a range of 160 nm to 1 μm. The difference in refraction index between a material forming the porous semiconductor layer 24 and a material forming the solid p-type semiconductor layer 26 is equal to or smaller than 1 in a light wavelength range of 400-1000 nm, otherwise a Rayleigh scattering cross section determined from refraction indexes of the materials is equal to or smaller than 0.1 in a light wavelength range of 400-1000 nm.
    • 要解决的问题:进一步提高固体型染料敏化太阳能电池的太阳能电池性能。解决方案:染料敏化太阳能电池40包括:具有透明导电基板14和多孔半导体层24的光电极20, 在基材上并具有颜料; 至少部分填充在多孔半导体层24中的孔中的固体p型半导体层26; 以及与光电极20相对的对置电极30,使得固体p型半导体层26位于它们之间。 多孔半导体层24的孔径分布在160nm〜1μm的范围内显示出最大值。 在形成多孔半导体层24的材料和形成固体p型半导体层26的材料之间的折射率差在400-1000nm的光波长范围内等于或小于1,否则瑞利散射截面 由材料的折射率确定在400-1000nm的光波长范围内等于或小于0.1。