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    • 2. 发明专利
    • ESTIMATING METHOD FOR AL CONCENTRATION IN MOLTEN STEEL
    • JPH08297110A
    • 1996-11-12
    • JP12723995
    • 1995-04-27
    • KAWASAKI STEEL CO
    • YAMAGUCHI RYUSUKEKUROSE YOSHIKAZU
    • G01N27/411G01N33/20
    • PURPOSE: To estimate the Al concentration in molten steel by obtaining the correlation between the Al concentration and oxygen potential in the molten steel in advance, and measuring the oxygen potential in the molten steel with an oxygen concentration battery using a solid electrolyte. CONSTITUTION: Molten steel having the Al concentration 0-65×10 % is prepared, and the electromotive force of the molten steel is obtained by an oxygen concentration battery using a solid electrolyte. The correlation between the electromotive force and the Al concentration in the molten steel is obtained as a regression straight line. The electromotive force is considered as the oxygen potential, the correlation of the electromotive force against the Al concentration in the molten steel is very similar to the straight line, and the Al concentration in the molten steel can be practically easily estimated from it. The difference between the Al concentration estimated from the regression straight line and the actually measured value is about the Al concentration ±6×10 % at the maximum. The Al concentration can be accurately estimated according to this correlation.
    • 3. 发明专利
    • METHOD FOR CONTROLLING ULTIMATE CARBON CONCENTRATION OF MOLTEN STEEL BY RG DEGASSING
    • JPH07166228A
    • 1995-06-27
    • JP31146593
    • 1993-12-13
    • KAWASAKI STEEL CO
    • YAMAGUCHI RYUSUKEHIWASA SHOICHI
    • C21C7/10
    • PURPOSE:To smelt an extra-low carbon steel with a high hit rate without superdecarburization by an RH degassing treatment. CONSTITUTION:A waste gas quantity is measured by using a gas flow meter disposed in a waste gas duct during the decarburization treatment of molten steel in a vacuum chamber. The carbon concn. at the point of this time is estimated from a difference in the waste gas flow rate which is a difference between the measured waste gas quantity and the actual waste gas quantity at the time of ending the decarburization by the latest RH degassing treatment. Sampling of the molten steel is executed and the carbon concn. [C1] is measured by an analysis in the stage when the estimated carbon concn. falls below 50ppm. A coefft. Kc1 of a decarburization speed is determined in accordance with a correlative relation between the carbon concn.[C] of the molten steel in a region below the carbon concn. of 50ppm previously determined from the measured carbon concn. [C1] and the coefft. KC of the decarburization speed. The treatment time (t) from the point of the time of sampling and until the end point of the decarburization is determined by the equation: t=-1n([Cr]/[Cl])/KC1 using the coefft. KC1 of the decarburization speed, the measured carbon concn. [C1] described above and the objective ultimate carbon concn. [CT].