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    • 5. 发明专利
    • Preparation of microcapsule
    • 微生物的制备
    • JPS58189030A
    • 1983-11-04
    • JP7384782
    • 1982-04-28
    • Kanzaki Paper Mfg Co Ltd
    • AOYANAGI SHIYOUJIKURODA TAKIOIRII SHINSUKEMIYAKE AKIRA
    • B01J13/16B41M5/165
    • B01J13/16B41M5/165
    • PURPOSE:To obtain a capsule extremely narrow in particle size distribution, by a method wherein a hydrophobic liquid containing polyvalent isocyanate is emulsified and dispersed in a hydrophilic solution of an unsaturated monocarboxylic acid type copolymer and a coating film is formed to each formed liquid particle to coat the same. CONSTITUTION:Unsaturated monocarboxylic acid type monomers such as acrylic acid, metharylic acid or the like are subjected to copolymerization in a combined form to prepare 20-98mol% copolymer which is in turn contained in a hydrophilic medium used in producing a capsule to prepare a hydrophilic solution. On the other hand, polyvalent isocyanate such as m-phenylene dissocyanate is added to a hydrophobic liquid such as cotton seed oil or hydrogenated terphenyl in a ratio of 0.02-60:1. In the next step, the aforementioned hydrophobic liquid is emulsified and dispersed in the unsaturated monocarboxylic copolymer-containing hydrophilic solution and polyvalent isocyanate is polymerized at the interface of a liquid droplet to form a synthetic high molecular film which is in turn applied to the surface of the hydrophobic liquid.
    • 目的:为了获得粒度分布非常窄的胶囊,通过将含有多价异氰酸酯的疏水性液体乳化分散在不饱和一元羧酸型共聚物和涂膜的亲水性溶液中,形成液体粒子至 大衣也一样。 构成:将不饱和一元羧酸类单体如丙烯酸,甲基丙烯酸等以组合的形式进行共聚合,制备20-98mol%的共聚物,该共聚物又包含在用于生产胶囊的亲水介质中以制备亲水 解。 另一方面,将多异氰酸酯如间苯二异氰酸酯以0.02-60:1的比例加入疏水性液体如棉籽油或氢化三联苯中。 在下一步骤中,将上述疏水性液体乳化分散在含不饱和一元羧酸共聚物的亲水性溶液中,多价异氰酸酯在液滴的界面处聚合,形成合成高分子膜, 疏水液体。