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    • 2. 发明专利
    • Heat-curable composition, varnish of the same, and heat-cured product of the same
    • 热固性组合物,其相容性和相同的热固化产物
    • JP2012107196A
    • 2012-06-07
    • JP2011170088
    • 2011-08-03
    • Jfe Chemical CorpJfeケミカル株式会社
    • NAKAO HIROAKITAKEMURA KAZUYA
    • C08G73/08
    • C08G73/0683C08G14/06C08G73/0233C08L61/34C09D161/34C09D179/02C09D179/04
    • PROBLEM TO BE SOLVED: To provide a heat-curable composition containing a benzoxazine-based compound, which has superior solubility in solvents, heat resistance and flame retardancy, to provide a varnish of the same, and to provide a heat-cured product of the varnish.SOLUTION: The heat-curable composition contains mixed benzoxazine-based compounds comprising a plurality of benzoxazine-based compounds in a specific ratio and an organic solvent dissolving the mixed benzoxazine-based compounds. The heat-cured product is obtained by heating and curing a varnish of the composition. The benzoxazine-based composition, the varnish of the composition, and the heat-cured product of the varnish are used for electronic materials such as laminated plates, adhesives or sealing agents.
    • 要解决的问题:提供含有苯并恶嗪类化合物的热固化性组合物,其具有优异的溶剂溶解性,耐热性和阻燃性,以提供其清漆,并提供热固化 清漆的产品。 解决方案:热固化性组合物含有以特定比例含有多种苯并恶嗪类化合物的混合苯并恶嗪类化合物和溶解混合苯并恶嗪类化合物的有机溶剂。 通过加热和固化组合物的清漆来获得热固化产物。 基于苯并恶嗪的组合物,组合物的清漆和清漆的热固化产物用于电子材料如层压板,粘合剂或密封剂。 版权所有(C)2012,JPO&INPIT
    • 3. 发明专利
    • Method for producing porous polyimide membrane
    • 生产多孔聚酰胺薄膜的方法
    • JP2012107144A
    • 2012-06-07
    • JP2010258211
    • 2010-11-18
    • Jfe Chemical CorpJfeケミカル株式会社Tokyo Metropolitan Univ公立大学法人首都大学東京
    • KANEMURA KIYOSHIMUNAKATA YUICHINAKAO HIROAKI
    • C08J9/26
    • PROBLEM TO BE SOLVED: To provide a method for inexpensively producing a large-area porous polyimide membrane [three-dimensionally ordered macroporous (3DOM) polyimide membrane] having three-dimensionally ordered open fine cells in good reproducibility by using a present polyimide film-producing installation or the like.SOLUTION: The method for producing the porous polyimide membrane includes a step for producing varnish by mixing a polyamic acid or a polyimide, silica particles and a solvent, or producing a varnish by polymerizing the polyamic acid or the polyimide in the solvent in which the silica particles are dispersed, a step for producing a polyimide-silica composite membrane by finishing the imidation after forming the membrane of the varnish produced in the foregoing step on a base plate, and a step for removing the silica in the polyimide-silica composite membrane produced in the foregoing step, wherein, particles having 1.0-1.1 of sphericity, ≤1.5 of a particle diameter distribution index (d/d) and 100-2,000 nm of an average diameter are used as the silica particles, and the mass ratio of the silica/polyimide in the polyimide-silica composite membrane is 2-6.
    • 要解决的问题:提供一种通过使用本发明的聚酰亚胺,以良好的再现性廉价地制造具有三维有序的开放细孔的大面积多孔聚酰亚胺膜[三维有序大孔(3DOM)聚酰亚胺膜]的方法 制膜设备等。 解决方案:多孔聚酰亚胺膜的制造方法包括通过混合聚酰胺酸或聚酰亚胺,二氧化硅颗粒和溶剂来制备清漆的步骤,或通过在溶剂中聚合聚酰胺酸或聚酰亚胺来制备清漆 二氧化硅颗粒分散的方法,在基板上形成上述步骤中制备的清漆的膜之后,通过完成酰亚胺化生产聚酰亚胺 - 二氧化硅复合膜的步骤和除去聚酰亚胺二氧化硅中的二氧化硅的步骤 在上述步骤中制备的复合膜,其中,具有球形度为1.0-1.1的颗粒,≤1.5的粒径分布指数(d 25 / d 75 )和100-2,000nm的平均直径用作二氧化硅颗粒,并且二氧化硅/聚酰亚胺在聚酰亚胺 - 二氧化硅复合膜中的质量比为2-6。 版权所有(C)2012,JPO&INPIT
    • 4. 发明专利
    • Polyimide and polyimide film
    • 聚酰亚胺和聚酰亚胺膜
    • JP2012077285A
    • 2012-04-19
    • JP2011150803
    • 2011-07-07
    • Jfe Chemical CorpJfeケミカル株式会社
    • NAKAO HIROAKIINOUE YOHEIKOBAYASHI MASANORI
    • C08G73/10H05K1/03
    • C08G73/1053C08G73/1042C08G73/1046C08G73/105C08G73/1067C08G73/1071C08J5/18C08J2379/08
    • PROBLEM TO BE SOLVED: To provide a polyimide film having a linear thermal expansion coefficient similar to copper, and having high elasticity and excellent steam permeability without impairing heat resisting properties.SOLUTION: This polyimide film comprises polyimide obtained by reacting component (I): aromatic diamine expressed by 9,9 bis(4-aminophenylene) which may have a substituent selected from a group comprising a halogen atom, a nitrogen atom-containing group, a 1-12C linear or branched alkyl group or alkoxy group, 2-12C linear or branched alkenyl group, a hydroxy group, a nitrile group, a nitro group, a carboxy group, an amide group and a 6-12C aromatic group, on a ring respectively independently, with component (II): 3,3', 4,4'-biphenyltetracarboxylic acid dianhydride, pyromellitic dianhydride, p-phenylene diamine and 4,4'-diaminodiphenyl ether; wherein, component (I):component (II)=0.1-10.0 mol%:99.9-90.0 mol%.
    • 要解决的问题:提供具有类似于铜的线性热膨胀系数并且具有高弹性和优异的蒸汽渗透性而不损害耐热性的聚酰亚胺膜。 解决方案:该聚酰亚胺膜包含通过使由9,9双(4-氨基亚苯基)表示的组分(I):芳族二胺与选自卤素原子,含氮原子的取代基 基团,1-12C直链或支链烷基或烷氧基,2-12C直链或支链烯基,羟基,腈基,硝基,羧基,酰胺基和6-12C芳族基团 分别独立地为环,与组分(II):3,3',4,4'-联苯四羧酸二酐,均苯四酸二酐,对苯二胺和4,4'-二氨基二苯醚; 其中,组分(I):组分(II)= 0.1-10.0mol%:99.9-90.0mol%。 版权所有(C)2012,JPO&INPIT