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1. 发明专利

JP2012066199A Method and device for separating hydrogen 有权
标题翻译：用于分离氢的方法和装置
公开(公告)号：JP2012066199A
公开(公告)日：2012-04-05
申请号：JP2010213773
申请日：2010-09-24
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： B01D53/22 , B01D71/02 , C01B3/56 , C22C5/04 , C22C27/02 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a method and device for separating hydrogen using a hydrogen separation membrane large in a hydrogen permeation rate, and excellent in hydrogen embrittlement resistance as well.SOLUTION: The method and device for separating hydrogen uses the hydrogen separation membrane formed of a V alloy containing W and Mo. The hydrogen separation membrane contains preferably ≤30 mol% of W, ≤30 mol% of Mo and a residual part of V. The hydrogen separation membrane contains particularly preferably 0.1-30 mol% of W, 0.1-30 mol% of Mo and the residual part of V. The hydrogen separation membrane contains further preferably 0.1-15 mol% of W, 0.1-15 mol% of Mo and the residual part of V. According to the method and device, hydrogen can be efficiently separated from various kinds of hydrogen-containing gases. Hydrogen can be efficiently separated from gas.
摘要翻译：要解决的问题：提供一种使用氢透过率大的氢分离膜分离氢的方法和装置，并且耐氢脆性优异。解决方案：用于分离氢的方法和装置使用由含有W和Mo的V合金形成的氢分离膜。氢分离膜优选含有≤30mol％的W，≤30mol％的Mo和残余部分的氢分离膜特别优选含有0.1-30mol％的W，0.1-30mol％的Mo和V的残余部分。氢分离膜进一步优选含有0.1-15mol％的W，0.1-15 Mo的摩尔％和V的残余部分。根据该方法和装置，氢可以有效地从各种含氢气体中分离出来。氢气可以有效地与气体分离。版权所有（C）2012，JPO＆INPIT

2. 发明专利

JP2011056485A Hydrogen separation membrane comprising v-w based alloy membrane and hydrogen separation method 有权
标题翻译：包含V-W基合金膜的氢分离膜和氢分离方法
公开(公告)号：JP2011056485A
公开(公告)日：2011-03-24
申请号：JP2009212550
申请日：2009-09-14
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , NISHII TAKUMI , SHIRASAKI YOSHINORI , YASUDA ISAMU , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： B01D71/02 , B01D53/22 , C01B3/56 , C22C27/02
摘要： PROBLEM TO BE SOLVED: To provide a new hydrogen separation membrane comprising a V-W based alloy, a hydrogen separation method by the hydrogen separation membrane, and a method of setting a hydrogen separation condition by a specified method.
SOLUTION: The V-W based alloy membrane and the hydrogen separation method by the V-W based alloy membrane are provided. For a condition for the separation of hydrogen by the V-W based alloy membrane, (b) the hydrogen pressure P of a hydrogen atmosphere to the V-W based alloy membrane and (c) a solid solution hydrogen amount C to the V-W based alloy membrane (a) at a temperature T are measured, and (d) a using temperature and hydrogen pressure conditions on the primary side and the secondary side are set by preparing a PCT curve for which the three elements are related on the basis of the actual measurement data of the temperature T, the hydrogen pressure P and the solid solution hydrogen amount C, obtaining the relation of the solid solution hydrogen amount C and the brittle fracture of the V-W based alloy membrane on the basis of the PCT curve, and evaluating a limit solid solution hydrogen amount relating to hydrogen-resistant brittleness.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种包含V-W基合金的新型氢分离膜，通过氢分离膜的氢分离方法和通过指定方法设定氢分离条件的方法。解决方案：提供V-W系合金膜和V-W系合金膜的氢分离方法。对于通过VW基合金膜分离氢的条件，（b）氢气氛的氢压力P向VW系合金膜，（c）为VW系合金膜的固溶氢量C（a ），并且（d）通过根据实际测量数据制备三元素相关的PCT曲线来设定初级侧和次级侧的使用温度和氢气压力条件温度T，氢压P和固溶氢量C，基于PCT曲线获得固溶氢量C与VW基合金膜的脆性断裂的关系，并评价极限固溶体与耐氢脆性相关的氢量。版权所有（C）2011，JPO＆INPIT

3. 发明专利

JP2012223754A Hydrogen separation membrane and manufacturing method therefor, and hydrogen manufacturing apparatus 有权
标题翻译：氢分离膜及其制造方法及氢制造装置
公开(公告)号：JP2012223754A
公开(公告)日：2012-11-15
申请号：JP2012067204
申请日：2012-03-23
申请人： Tokyo Gas Co Ltd , Nagoya Univ , Institute Of National Colleges Of Technology Japan , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： B01D71/02 , B01D53/22 , B01D69/10 , B01D69/12 , C01B3/56 , C22C5/04 , C22C27/02
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen separation membrane in which a middle layer for preventing the mutual diffusion between a base metallic layer and a coated metallic layer, and the oxidation of alloy components of the base metallic layer is formed at low cost, a manufacturing method therefor, and a hydrogen manufacturing apparatus provided therewith.SOLUTION: The hydrogen separation membrane 11 includes the base metallic layer 12 composed of a group 5A metal or its alloy, the middle layer 13 formed on the surface of the base metallic layer 12 and the coated metallic layer 14 formed on the middle layer 13; and the middle layer 13 is formed by anodic oxidation of the base metallic layer 12. The manufacturing method for the hydrogen separation membrane 11 has a step of forming the middle layer 13 by anodic oxidation of the base metallic layer 12 and a step of forming the coated metallic layer 14 on the middle layer 13, and the hydrogen manufacturing apparatus has the hydrogen separation membrane 11.
摘要翻译：要解决的问题：提供一种氢分离膜，其中用于防止基底金属层和涂覆的金属层之间的相互扩散的中间层，并且基底金属层的合金成分的氧化形成为低成本，其制造方法以及与此相应的氢制造装置。解决方案：氢分离膜11包括由5A族金属或其合金构成的基底金属层12，形成在基底金属层12的表面上的中间层13和形成在中间的金属层14 层13; 中间层13由基底金属层12的阳极氧化形成。氢分离膜11的制造方法具有通过基底金属层12的阳极氧化形成中间层13的工序，以及形成中间层13上的涂覆金属层14，氢制造装置具有氢分离膜11.版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2011144088A Two-stage hydrogen separation type reformer 有权
标题翻译：两级氢分离式改型机
公开(公告)号：JP2011144088A
公开(公告)日：2011-07-28
申请号：JP2010007516
申请日：2010-01-15
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , NISHII TAKUMI , SHIRASAKI YOSHINORI , YASUDA ISAMU , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： C01B3/38 , B01D53/22 , B01D63/06 , B01D63/08 , B01D69/10 , B01D71/02 , C01B3/56
摘要： PROBLEM TO BE SOLVED: To obtain a hydrogen separation type reformer in which both of a Pd-alloy hydrogen separation membrane and a group 5A metal-alloy hydrogen separation membrane are used simultaneously to obtain the hydrogen recovery rate higher than those of the conventional reformers.
SOLUTION: The hydrogen separation type reformer is formed by arranging the hydrogen separation membrane on the outer peripheral surface of a boxy or cylindrical porous support or another support comprising a perforated plate, each of which plays a role in supporting the hydrogen separation membrane, and arranging a reforming catalyst layer on the outer periphery of the arranged hydrogen separation membrane. A hydrogen separation system is formed by arranging a plurality of the hydrogen separation type reformers in series. A two-stage hydrogen separation type reformer is characterized in that the Pd-alloy hydrogen separation membrane is used on the upstream side of the gas to be treated and the group 5A metal-alloy hydrogen separation membrane is used on the downstream side of the gas to be treated.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题为了获得氢分离型重整器，其中同时使用Pd合金氢分离膜和5A族金属合金氢分离膜，以获得高于常规改良者。解决方案：氢分离型重整器通过在氢氧化物或圆柱形多孔载体的外周表面上布置氢分离膜或者包括多孔板的另一载体来形成，每个载体起到支撑氢分离膜的作用并且在配置的氢分离膜的外周配置重整催化剂层。通过串联布置多个氢分离型重整器形成氢分离系统。两级氢分离型重整器的特征在于，在合成气体的上游侧使用Pd合金氢分离膜，在气体的下游侧使用5A族金属合金氢分离膜待处理版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2014133696A Two-stage hydrogen separation type reformer 有权
标题翻译：两级氢分离式改型机
公开(公告)号：JP2014133696A
公开(公告)日：2014-07-24
申请号：JP2014045870
申请日：2014-03-10
申请人： Tokyo Gas Co Ltd , 東京瓦斯株式会社 , Nagoya Univ , 国立大学法人名古屋大学 , Institute Of National Colleges Of Technology Japan , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , NISHII TAKUMI , SHIRASAKI YOSHINORI , YASUDA ISAMU , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： C01B3/38 , B01D53/22 , B01D69/10 , B01D69/12 , B01D71/02 , C01B3/56 , C01B32/50
CPC分类号： Y02C10/10
摘要： PROBLEM TO BE SOLVED: To obtain a hydrogen separation type reformer in which both of a Pd-based alloy hydrogen separation membrane and a group 5A metal alloy hydrogen separation membrane are used so that the hydrogen recovery rate higher than those of the conventional reformers can be obtained.SOLUTION: A two-stage hydrogen separation type reformer being the hydrogen separation type reformer is constituted so that the hydrogen separation membrane is disposed on the outer peripheral surface of a support, which plays a part in supporting the hydrogen separation membrane and comprises a cylindrical porous support or a perforated plate, and a reforming catalyst layer is disposed on the outer periphery of the hydrogen separation membrane. The Pd-based alloy hydrogen separation membrane is used on the upstream side of the gas to be treated and the V alloy or Ta alloy hydrogen separation membrane, which can be used without being fractured brittlely even under 0.10 MPa (1 atmosphere as absolute pressure) or higher, is used on the downstream side of the gas to be treated.
摘要翻译：要解决的问题为了获得使用Pd基合金氢分离膜和5A族金属合金氢分离膜两者的氢分离型重整器，使得比常规重整器高的氢回收率可以是得到的溶液。作为氢分离型重整器的两级氢分离型重整器构成为使氢分离膜配置在支撑氢分离膜的部分的支撑体的外周面上，圆柱形多孔载体或多孔板，并且重整催化剂层设置在氢分离膜的外周。 Pd系合金氢分离膜用于待处理气体的上游侧以及V合金或Ta合金氢分离膜，即使在0.10MPa（绝对压力为1个大气压）下也能够脆性地使用，或更高，用于待处理气体的下游侧。

6. 发明专利

JP2012031021A Method of estimating hydrogen permeation rate, hydrogen manufacturing device, and method of operating the same 有权
标题翻译：计算氢气渗透速率的方法，氢制造装置及其操作方法
公开(公告)号：JP2012031021A
公开(公告)日：2012-02-16
申请号：JP2010172964
申请日：2010-07-30
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： C01B3/56 , B01D53/22 , B01D71/02 , G01N15/08
摘要： PROBLEM TO BE SOLVED: To provide a method capable of accurately predicting a hydrogen permeation rate of a hydrogen permeable film, a hydrogen manufacturing device employing the same, and a method of operating the same.SOLUTION: In this method of estimating a hydrogen permeation rate of a hydrogen separation film in a hydrogen separation process of supplying a material gas to a primary chamber and extracting hydrogen having permeated the hydrogen separation film from a secondary chamber, a relationship between a chemical potential difference Δμ of hydrogen between the primary chamber and the secondary chamber obtained from hydrogen partial pressure Pin the primary chamber, hydrogen partial pressure Pin the secondary chamber, and temperatures T thereof, and a hydrogen permeation rate J is previously obtained, and the hydrogen permeation rate when the hydrogen partial pressure in the primary chamber and that in the secondary chamber are assumed to be P'and P', respectively is obtained from the relationship. Gas pressure values and temperatures of the primary chamber and the secondary chamber are controlled so that a product J*A with a value J estimated by the method is set at a target hydrogen extraction amount.
摘要翻译：要解决的问题：提供能够准确地预测氢渗透膜的氢渗透速率的方法，使用该方法的氢制造装置及其操作方法。解决方案：在用于将原料气体供应到初级室并从第二室提取渗透了氢分离膜的氢气的氢分离过程中，估计氢分离膜的氢气渗透速率的方法中，在主室中由氢气分压P 1 获得的主室和次室之间的氢的化学势差Δμ，氢分压P 2 ，并且预先获得其温度T和氢渗透速率J，并且假设主室中的氢分压和次室中的氢分压为从该关系中分别获得P' 1 和P' 2 。控制主室和次室的气压值和温度，使得通过该方法估计的具有值J的乘积J * A被设定为目标氢提取量。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2011143375A Hydrogen separation system using 5a group metallic hydrogen separation membrane 有权
标题翻译：使用5A组金属氢分离膜的氢分离系统
公开(公告)号：JP2011143375A
公开(公告)日：2011-07-28
申请号：JP2010007613
申请日：2010-01-16
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , NISHII TAKUMI , SHIRASAKI YOSHINORI , YASUDA ISAMU , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： B01D61/58 , B01D53/22 , B01D69/10 , B01D71/02
CPC分类号： Y02C10/10
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen separation system providing a hydrogen recovery higher than in conventional reformers, by using both a Pd-based alloy hydrogen separation membrane and a 5A group metal alloy hydrogen separation membrane.
SOLUTION: In the hydrogen separation system, the hydrogen separation membrane is disposed on the outer peripheral face of a support body consisting of a casing-like or a cylindrical porous support body or a support body consisting of a perforated plate serving for supporting the hydrogen separation membrane, and a plurality of hydrogen separation reformers formed by arranging a reforming catalyst layer are serially arranged on the outer periphery of the hydrogen separation membrane. The hydrogen separation membrane uses the Pd-based alloy hydrogen separation membrane on the upstream of the treating object gas, and the 5A group metal alloy hydrogen separation membrane on the downstream of the treating object gas.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：通过使用Pd基合金氢分离膜和5A族金属合金氢分离膜，提供比常规重整器高的氢回收率的氢分离系统。解决方案：在氢气分离系统中，氢分离膜设置在由壳体或圆柱形多孔支撑体或由用于支撑的多孔板组成的支撑体的支撑体的外周面上氢分离膜和通过配置重整催化剂层形成的多个氢分离重整器连续排列在氢分离膜的外周。氢分离膜在处理对象气体的上游使用Pd基合金氢分离膜，在处理对象气体的下游使用5A族金属合金氢分离膜。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2010240637A HYDROGEN SEPARATING SYSTEM USING Nb MEMBRANE AND PERIODIC TABLE 5A GROUP METAL ALLOY MEMBRANE 审中-公开
标题翻译：使用Nb膜和周期表5A的氢分离系统组合金属合金膜
公开(公告)号：JP2010240637A
公开(公告)日：2010-10-28
申请号：JP2010007428
申请日：2010-01-15
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , Tokyo Gas Co Ltd , 国立大学法人名古屋大学 , 東京瓦斯株式会社 , 独立行政法人国立高等専門学校機構
发明人： KUROKAWA HIDETO , NISHII TAKUMI , SHIRASAKI YOSHINORI , YASUDA ISAMU , MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI , MATSUMOTO YOSHIHISA
IPC分类号： B01D53/22 , B01D71/02 , C01B3/38 , C01B3/56
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen producing system for separating hydrogen from a gas of low-concentration hydrogen with a small difference of partial pressure of hydrogen making use of the characteristic of a Nb membrane, and to provide a hydrogen producing system for reforming methane in a gas of low-concentration hydrogen containing methane of high temperature and producing and separating hydrogen from the obtained reformed gas with a small difference of partial pressure of hydrogen. SOLUTION: The system is for separating hydrogen using the Nb membrane from the gas of low-concentration hydrogen at room temperature and atmospheric pressure generated from a generator of the gas of low-concentration hydrogen at room temperature. The hydrogen separating system includes (a) the Nb membrane, (b) a heating means equipped with a burner, (c) a means for supplying the upstream side of the Nb membrane with the gas of low-concentration hydrogen at room temperature and (d) a means for recovering hydrogen in the downstream side of the Nb membrane. The hydrogen separating system is for selectively separating hydrogen from the gas of low-concentration hydrogen by heating the Nb membrane to 300-500°C with (b) the heating means equipped with a burner under (e) the condition that the solid solubility of hydrogen in the Nb membrane C(H/M) is 0.26 or lower. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种利用Nb膜的特征，以小的氢分压差从低浓度氢气中分离氢的氢气制备系统，并提供产氢用于在含有高温甲烷的低浓度氢气的气体中重整甲烷的系统，并从所获得的重整气体中分离氢并以较小的氢分压差。
解决方案：该系统用于在室温下从低浓度氢气中分离氢气，室温下由低浓度氢气发生器产生的大气压。氢分离系统包括（a）Nb膜，（b）装有燃烧器的加热装置，（c）在室温下向Nb膜的上游侧供应低浓度氢气的装置和 d）在Nb膜的下游侧回收氢的方法。氢分离系统用于通过将Nb膜加热至300-500℃来选择性地从低浓度氢气中分离出氢气，（b）在（e）下配备有燃烧器的加热装置，条件是固体溶解度 Nb膜C（H / M）中的氢为0.26以下。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2010221168A Hydrogen separation device and hydrogen separation method 审中-公开
标题翻译：氢分离装置和氢分离方法
公开(公告)号：JP2010221168A
公开(公告)日：2010-10-07
申请号：JP2009073130
申请日：2009-03-25
申请人： Institute Of National Colleges Of Technology Japan , Nagoya Univ , 国立大学法人名古屋大学 , 独立行政法人国立高等専門学校機構
发明人： MORINAGA MASAHIKO , YUGAWA HIROSHI , NANBU TOMONORI
IPC分类号： B01D53/22 , B01D65/00 , B01D71/02 , C01B3/56
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen separation device whose durability is improved by suppressing the generation of a hole in a palladium-based separation membrane.
SOLUTION: On the basis of the knowledge that metal particles generated by reducing metal oxide particles stuck to the surface of the palladium-based separation membrane strongly react with the palladium-based separation membrane and are diffused from each other and thus holes are generated, the hydrogen separation device includes a hydrogen separation membrane which sections a primary side space and a secondary side space and includes palladium or a palladium alloy, a gas-to-be-separated supply means for supplying a gas to be separated, which contains hydrogen, to the primary side space, and an oxygen supply means for causing oxygen to be contained in the gas to be separated inside the primary side space when separating the hydrogen from the gas to be separated by the hydrogen separation membrane.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决的问题：提供通过抑制钯基分离膜中的孔的产生而提高其耐久性的氢分离装置。解决方案：基于粘附在钯基分离膜表面上的还原性金属氧化物颗粒产生的金属颗粒与钯基分离膜强烈反应并彼此扩散的知识，因此孔是氢分离装置包括：氢分离膜，其分隔一次侧空间和二次侧空间，并且包括钯或钯合金，用于供给待分离气体的待分离供气装置，其包含氢，一次侧空间，以及氧供给装置，用于在从氢分离膜分离氢气和待分离气体时，在一次侧空间内分离含气气体。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2013231245A Surface-treated carbon fiber and carbon fiber-resin composite material 审中-公开
标题翻译：表面处理碳纤维和碳纤维树脂复合材料
公开(公告)号：JP2013231245A
公开(公告)日：2013-11-14
申请号：JP2012103416
申请日：2012-04-27
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所 , Tokyo Institute Of Technology , 国立大学法人東京工業大学 , Nagaoka Univ Of Technology , 国立大学法人長岡技術科学大学 , Institute Of National Colleges Of Technology Japan , 独立行政法人国立高等専門学校機構
发明人： HOTTA YUJI , SATO KIMIYASU , TANAKA JUNZO , IKOMA TOSHIYUKI , XU ZHEFENG , TAGAYA MOTOHIRO , MOTOZUKA SATOSHI , MORINAGA MASAHIKO
IPC分类号： D01F9/14 , C08K7/06 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a carbon fiber that has a surface treated by mechanochemical treatment and can be used as a fiber for reinforcing a composite material, and to provide a carbon fiber-resin composite material.SOLUTION: The surface-treated carbon fiber is obtained by charging a carbon fiber into a container for mechanochemical treatment so that a volume ratio of the carbon fiber becomes 0.001 or more and 0.99 or less with respect to the volume 1 of the container for the mechanochemical treatment, and subjecting the carbon fiber to the mechanochemical treatment. The carbon fiber-resin composite material is obtained by charging a carbon fiber and a resin material into the container for the mechanochemical treatment so that a volume ratio of the carbon fiber becomes 0.001 or more and 0.99 or less and a volume ratio of the resin material becomes 0.01 or more and 0.99 or less with respect to the volume 1 of the container for the mechanochemical treatment, and subjecting the carbon fiber and the resin material to the mechanochemical treatment.
摘要翻译：要解决的问题：提供一种通过机械化学处理进行表面处理并可用作增强复合材料的纤维并提供碳纤维 - 树脂复合材料的碳纤维。溶液：表面处理的碳纤维通过将碳纤维装入用于机械化学处理的容器中，使碳纤维的体积比相对于用于机械化学处理的容器的体积1为0.001以上且0.99以下，并且将碳纤维机械化学处理。碳纤维树脂复合材料通过将碳纤维和树脂材料装入用于机械化学处理的容器中而获得，使得碳纤维的体积比变为0.001以上且0.99以下，树脂材料的体积比相对于用于机械化学处理的容器的体积1为0.01以上且0.99以下，对碳纤维和树脂材料进行机械化处理。

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