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    • 1. 发明专利
    • Polycarbonate resin composition and compact thereof
    • 聚碳酸酯树脂组合物及其紧凑性
    • JP2014129488A
    • 2014-07-10
    • JP2012288383
    • 2012-12-28
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • NAKAE MITSUGIMAKINO TAKESHI
    • C08L69/00B29C45/00B29C47/00B29K69/00C08K5/435C08K5/50
    • PROBLEM TO BE SOLVED: To provide a polycarbonate resin composition capable of being a compact excellent in transparency, antistatic properties, impact resistance and heat stability, and a compact thereof.SOLUTION: A polycarbonate resin composition contains 0.6 to 1.8 pts.mass of phosphonium salt represented by the general formula (1) relative to the 100 pts.mass of polycarbonate resin and substantially not-containing diglycerol fatty acid ester. In the formula (1): [(R)RP]/(RSO)(RSO)N, Rrepresents an alkyl group having a carbon number of 1 to 4, Rrepresents an alkyl group having a carbon number of 8 to 20, Rand Rrepresent a perfluoroalkyl group having a carbon number of 1 to 4, and Rand Rmay be identical or different.
    • 要解决的问题:提供一种能够具有透明性,抗静电性,耐冲击性和热稳定性优异的紧凑性的聚碳酸酯树脂组合物及其成型体。溶液:聚碳酸酯树脂组合物含有0.6〜1.8质量份的鏻盐 由通式(1)表示,相对于100重量份的聚碳酸酯树脂和基本上不含二甘油脂肪酸酯。 在式(1)中:[(R)RP] /(RSO)(RSO)N,R表示碳数为1至4的烷基,R表示碳数为8至20的烷基,兰德R 碳数为1〜4的全氟烷基,兰德·兰美相同或不同。
    • 2. 发明专利
    • Polycarbonate resin composition and molded article thereof
    • 聚碳酸酯树脂组合物及其成型品
    • JP2011132312A
    • 2011-07-07
    • JP2009291203
    • 2009-12-22
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • NOMURA MANABUSUGANO SUSUMUNAKAE MITSUGI
    • C08L69/00C08K5/17
    • C08L69/00C08K5/0066C08K5/17C08L23/0884C08L27/18C08L2666/04C08L2666/06
    • PROBLEM TO BE SOLVED: To provide a polycarbonate resin composition being excellent in impact-resistance, bending strength, flowability or the like, not exhibiting laminar peeling off after molding, having high chemical resistance and improved flame retardancy and to provide its molded article.
      SOLUTION: The polycarbonate resin composition includes 100 pts.mass of a resin component, which consists of (A) 60-95 mass% of an aromatic polycarbonate resin having a viscosity average molecular weight of 16,000-35,000, (B) 1-40 mass% of a polyolefin resin and/or a polyolefin elastomer containing an epoxy or glycidyl group in which the adding amount of a compound having an epoxy or glycidyl group is 3-30 mass%, (C) 0-39 mass% of a polyolefin resin (except a polyolefin resin with component (B)), and (D) 0.001-1 pt.mass of at least one kind selected from the group consisting of an aliphatic amine salt, an aromatic amine salt, ammonium hydroxide and a hydroxylamine salt, (E) 3-40 pts.mass of a phosphorus and/or a halogen flame retardant and (F) 0.05-5 pts.mass of a polymer containing fluorine, and the polycarbonate resin composition is melted and kneaded and the molded product of the polycarbonate resin composition is also provided.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供抗冲击性,弯曲强度,流动性等优异的成型后不显示层状剥离的聚碳酸酯树脂组合物,具有高耐化学性和改善的阻燃性,并提供其成型 文章。 解决方案:聚碳酸酯树脂组合物包含100质量份树脂组分,其由(A)60-95质量%的粘均分子量为16,000-35,000的芳族聚碳酸酯树脂,(B)1 -40质量%的聚烯烃树脂和/或含环氧基或缩水甘油基的聚烯烃弹性体,其中环氧或缩水甘油基的化合物的添加量为3-30质量%,(C)为0-39质量% 聚烯烃树脂(具有组分(B)的聚烯烃树脂除外)和(D)选自脂族胺盐,芳族胺盐,氢氧化铵和/或其混合物中的至少一种的0.001-1pt.mass 羟胺盐,(E)磷和/或卤素阻燃剂的3-40重量份和(F)含有氟的0.05-5重量份的聚合物,并将聚碳酸酯树脂组合物熔融并捏合 还提供了聚碳酸酯树脂组合物的产物。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Polycarbonate resin composition
    • 聚碳酸酯树脂组合物
    • JP2012077265A
    • 2012-04-19
    • JP2010226504
    • 2010-10-06
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • NOMURA MANABUSUGANO SUSUMUNAKAE MITSUGI
    • C08L69/00C08K5/00C08L23/04C08L23/26
    • PROBLEM TO BE SOLVED: To provide a polycarbonate resin composition capable of attaining compatibility between excellent shock resistance and excellent chemical resistance by covering a defect of an aromatic polycarbonate resin, not causing laminar peeling after molding even in the case of a thin molding, and having high fusion strength with an acrylic resin or a polycarbonate resin.SOLUTION: The polycarbonate resin composition contains: (A) a 50-98 mass% aromatic polycarbonate resin partially having hydroxy groups as molecular chain terminal groups, wherein the hydroxy group content in the whole terminal groups is 10-80 mol%, and having a viscosity average molecular weight of 11,000-30,000; (B) 1-30 mass% polyolefin resin and/or polyolefin elastomer containing an epoxy group or a glycidyl group; and (C) 1-40 mass% polyethylene resin whose melt index (MI) is
    • 解决问题:提供一种通过覆盖芳香族聚碳酸酯树脂的缺陷,能够获得优异的耐冲击性和优异的耐化学性之间的相容性的聚碳酸酯树脂组合物,即使在成型时也不造成层状剥离 并且与丙烯酸树脂或聚碳酸酯树脂具有高的熔融强度。 解决方案:聚碳酸酯树脂组合物含有:(A)部分具有羟基作为分子链端基的50-98质量%芳族聚碳酸酯树脂,其中整个末端基团的羟基含量为10-80摩尔% 粘均分子量为11,000〜30,000; (B)含有环氧基或缩水甘油基的1-30质量%聚烯烃树脂和/或聚烯烃弹性体; 和(C)熔体指数(MI)<5g / 10min的1-40质量%聚乙烯树脂。 版权所有(C)2012,JPO&INPIT
    • 5. 发明专利
    • Red enhancing glasses and resin molding for goggles
    • 红色增强玻璃和树脂模具的GOGGLES
    • JP2010204383A
    • 2010-09-16
    • JP2009049732
    • 2009-03-03
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • NAKAE MITSUGISATO KOJI
    • G02C7/10G02B5/22G02B5/30G02C7/12
    • PROBLEM TO BE SOLVED: To provide a resin molding for glasses and goggles, which enhances red and orange and can be used for glasses, goggles or the like as a resin lens. SOLUTION: The resin molding is obtained by molding a resin composition containing 100 pts.mass of transparent resin and 0.002 to 0.015 pts.mass of anthraquinone-based dye and has a visible light transmittance of 20 to 50%, a transmittance of 10 to 45% at 540 to 560 nm, a transmittance of 70 to 90% at 650 nm. Furthermore, the resin molding has a transmittance of ≥60% at 620 nm and enhances red and orange. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种增强红色和橙色并可用于眼镜,护目镜等作为树脂透镜的玻璃和护目镜用树脂模制品。 解决方案:通过模塑含有100质量份透明树脂和0.002-0.015质量份蒽醌类染料的树脂组合物,可见光透射率为20〜50%,透光率为 在540至560nm处为10至45%,在650nm处透射率为70至90%。 此外,树脂成型体在620nm处具有≥60%的透光率,并且增强红色和橙色。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Polycarbonate resin composition and method for producing the same
    • 聚碳酸酯树脂组合物及其制造方法
    • JP2009084550A
    • 2009-04-23
    • JP2008121488
    • 2008-05-07
    • Idemitsu Kosan Co LtdNagoya Institute Of Technology出光興産株式会社国立大学法人 名古屋工業大学
    • NAKAE MITSUGIYAMADA YASUJIKOIDE SHIGEHIRO
    • C08G64/42
    • PROBLEM TO BE SOLVED: To provide a polycarbonate (PC) resin composition with high transparency and improved rigidity and scratch resistance and a method for producing the polycarbonate (PC) resin composition. SOLUTION: The PC resin composition is produced by chemically binding (A) an inorganic oxide particle with a mean primary particle size of 100 nm or less to (B) a PC resin via (C) a coupling agent represented by the following formula (1) or (2). The method for producing the PC resin composition comprises adding the component (A) and the component (C) into an organic solvent solution of a terminal chloroformate group-containing PC oligomer under acidic conditions, mixing them, and then adding divalent phenol for condensation reaction. In general formula (1): HN(R 3 )-(CH 2 ) m -M 1 (R 1 ) x (OR 2 ) 3-x (1), M 1 denotes a tetravalent metallic element, R 1 , R 2 , and R 3 each independently denotes a group selected from a hydrogen atom, a 1-4C lower alkyl group, and a phenyl group, m denotes an integer between 2 and 8 representing the number of chains of a methylene group, and x denotes 0, 1, or 2. In general formula (2): HS-(CH 2 ) n -M 2 (R 1 ) y (OR 2 ) 3-y (2), M 2 denotes a tetravalent metallic element, R 4 and R 5 each independently denotes a group selected from a hydrogen atom, a 1-4C lower alkyl group and a phenyl group, n denotes an integer between 2 and 8 representing the number of chains of a methylene group, and y denotes 0, 1, or 2. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决问题的方法:提供高透明度,刚性和耐划伤性提高的聚碳酸酯(PC)树脂组合物和聚碳酸酯(PC)树脂组合物的制造方法。 解决方案:PC树脂组合物通过(C)由下列化合物代表的偶联剂将(A)平均一次粒径为100nm以下的无机氧化物颗粒与(B)PC树脂进行化学结合 式(1)或(2)。 制备PC树脂组合物的方法包括在酸性条件下将组分(A)和组分(C)加入到含末端含氯甲酸酯基的PC低聚物的有机溶剂溶液中,混合,然后加入用于缩合反应的二元酚 。 在通式(1)中:HN(R 3 SP 3) - (CH 2 SB 2) -M SP 1 ( 1 (OR SP&gt; 2&lt; SP&gt; SP>表示四价金属元素,R SP 1,R SP 2,R SP 3各自独立地表示选自氢原子, 1-4C低级烷基和苯基,m表示2至8之间的整数,表示亚甲基的链数,x表示0,1或2.通式(2)中:HS-( (S (R 1 SP> 2 )3-y (2),M 2 表示四价金属元素,R SP&gt; 4&lt; SP& > 5 各自独立地表示选自氢原子,1-4C低级烷基和苯基的基团,n表示2至8之间的整数,表示亚甲基的链数,y表示 0,1或2.版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Polycarbonate resin composition
    • 聚碳酸酯树脂组合物
    • JP2006104329A
    • 2006-04-20
    • JP2004292475
    • 2004-10-05
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • NAKAE MITSUGIISHIKAWA YASUHIRO
    • C08L69/00C08J7/04C08L71/10
    • PROBLEM TO BE SOLVED: To provide a PC resin composition which has excellent transparency and excellent adhesiveness to coatings. SOLUTION: This polycarbonate resin composition is characterized by comprising (A) 98.5 to 60 mass% of a polycarbonate resin and (B) 1.5 to 40 mass% of a phenoxy resin represented by the general formula (1) [X is, for example, -Ph-C(CH 3 ) 2 -Ph-; Y is, for example, H; (n) is a polymerization degree], wherein the total amount of the components (A) and (B) is 100 mass%, and having a difference of COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有优异的透明性和优异的涂料密合性的PC树脂组合物。 该聚碳酸酯树脂组合物的特征在于,包含(A)98.5〜60质量%的聚碳酸酯树脂和(B)1.5〜40质量%的由通式(1)表示的苯氧基树脂[X为, 例如-Ph-C(CH 3 SB 3)SB 2 -Ph-; Y是例如H; (A)和(B)的总量为100质量%,组分(A)的折射率与组分(A)的折射率之差<0.005时,聚合度 (B)。 版权所有(C)2006,JPO&NCIPI