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1. 发明专利

JP2000136391A METHOD FOR HYDROGENATING CRUDE OIL AND REFORMED CRUDE OIL 失效
公开(公告)号：JP2000136391A
公开(公告)日：2000-05-16
申请号：JP20566099
申请日：1999-07-21
申请人： IDEMITSU KOSAN CO
发明人： YOSHIDA MITSURU
IPC分类号： B01J23/85 , B01J23/88 , C10G35/04 , C10G45/02 , C10G67/02
摘要： PROBLEM TO BE SOLVED: To improve the qualities of kerosene and gas oil by hydrogenating crude oil through successive steps of hydrodemetallization, hydrocracking, and hydrodesulfurization, subjecting the hydrogenation product to gas/liquid separation, and hydrogenating the resultant gas-phase fluid. SOLUTION: Topped crude obtained by separating naphtha fraction from crude oil is subjected to hydrodemetallization at 300-450 deg.C under a hydrogen partial pressure of 30-200 kg/cm2G at a hydrogen/oil ratio of 200-2000 Nm3/kL in the presence of a catalyst comprising a silica carrier or the like and a metal selected from among metals of the groups 5, 6, 8, 9, and 10 and carried thereby, is then subjected to hydrocracking in the presence of a catalyst comprising an aluminosilicate/inorganic oxide carrier and Ni-Mo, etc., carried thereby, and is subjected to hydrodesulfurization at 300-450 deg.C at a hydrogen/oil ratio of 200-2,000 Nm3/kL in the presence of a catalyst comprising an alumina-titania carrier and a metal selected from among metals of the groups 5, 6, 8, 9, and 10 and carried thereby. Then, a gas-phase fluid separated in a high-temperature high-pressure separation vessel under a pressure 0-50 kg/cm2 lower than and at a temperature 0-100 deg.C lower than that in the hydrodesulfurization is hydrogenated under almost the same conditions as in the hydrodesulfurization, thus giving kerosene and gas oil.

2. 发明专利

JP2000086233A IRON-CONTAINING CRYSTALLINE ALUMINO-SILICATE 失效
公开(公告)号：JP2000086233A
公开(公告)日：2000-03-28
申请号：JP26158998
申请日：1998-09-16
申请人： IDEMITSU KOSAN CO
发明人： IINO AKIRA , YOSHIDA MITSURU , INAMURA KAZUHIRO
IPC分类号： B01J29/072 , C01B39/02 , C10G47/16 , C10G49/08
摘要： PROBLEM TO BE SOLVED: To obtain a catalyst component having high hydrogenation decomposition activity while maintaining the yield of intermediate fraction by controlling the content of inactive iron compd. calculated by the temp. rising programming reduction to a specified value or smaller and controlling the reduction peak temp. in a high temp. region to a specified value or higher. SOLUTION: The new iron-contg. crystalline aluminosilicate has the main compsn. expressed by the formula of aFe2O3.Al2O3.bSiO2.nH2O wherein n is 1 to 30; a and b satisfy 15 (-300×UD+8320) deg.C, wherein UD is the lattice const. (Å) of the crystal ranging from 24.20 to 24.40. This compd. is obtd. by subjecting a crystalline aluminosilicate having >=3.5 molar ratio of silica to alumina to steaming treatment, treating with a mineral acid, and treating by using iron sulfate in the presence of a mineral acid.

3. 发明专利

JPH11349961A HYDROGENATION FOR HEAVY HYDROCARBON OIL 失效
公开(公告)号：JPH11349961A
公开(公告)日：1999-12-21
申请号：JP9722899
申请日：1999-04-05
申请人： IDEMITSU KOSAN CO
发明人： YOSHIDA MITSURU , IINO AKIRA
IPC分类号： B01J23/88 , B01J29/16 , C10G45/06 , C10G45/08 , C10G47/16 , C10G47/18 , C10G47/20 , C10G65/12
摘要： PROBLEM TO BE SOLVED: To provide a producing method capable of producing in high yield gasoline fraction, kerosene and gas oil fraction and lubricant base materials having good quality and high additional value by efficient catalytic hydrogenation of low-grade heavy hydrocarbon oils. SOLUTION: This method is hydrotreating of at least one heavy hydrocarbon oil selected from heavy gas oil, cracked gas oil, vacuum gas oil, coker gas oil visbreaker gas oil and solvent deashaliting oil and comprises lightening of the heavy hydrocarbon oil in which steps (A) hydrodesulfurization and hydrodenitrification of heavy hydrocarbon oil in the presece of an amorphous hydrogenation catalyst, (B) hydrogenolysis of the resultant hydrocarbon oil from the above mentioned A step in the presence of a zeolite-based hydrogenolysis catalyst and (C) hydrodesulfurization of the resultant hydrocarbon oil from the above mentioned B step in the presence of the amorphous hydrogenation catalyst are sequentially performed.

4. 发明专利

JP2000265176A HYDRODESULFURIZATION OF LIGHT OIL FRACTION 失效
公开(公告)号：JP2000265176A
公开(公告)日：2000-09-26
申请号：JP7408499
申请日：1999-03-18
申请人： IDEMITSU KOSAN CO
发明人： IINO AKIRA , YOSHIDA MITSURU
IPC分类号： B01J29/16 , C10G45/04 , C10G45/06 , C10G45/10 , C10G45/12
摘要： PROBLEM TO BE SOLVED: To provide a method for the hydrodesulfurization of light oil fraction so as to ensure the sulfur content of the resultant desulfurized light oil to be

5. 发明专利

JP2000204380A DESULFURIZATION PROCESS FOR LIGHT OIL AND SYSTEM FOR THE SAME 失效
公开(公告)号：JP2000204380A
公开(公告)日：2000-07-25
申请号：JP349799
申请日：1999-01-08
申请人： IDEMITSU KOSAN CO
发明人： SUZUKI YASUYUKI , IINO AKIRA , YOSHIDA MITSURU
IPC分类号： C10G7/00 , C10G7/06 , C10G45/02 , C10G45/04 , C10G45/72 , C10G67/02
摘要： PROBLEM TO BE SOLVED: To efficiently produce sufficiently desulfurized light oil and desulfurized vacuum gas oil having excellent decomposing properties in fluid cat- cracker. SOLUTION: This desulfurization system for light oil installs a topping plant 10, vacuum distilling plant 20, vacuum light oil desulfurizer 30 and light oil desulfurizer 50, and the vacuum gas oil VGO obtained from the vacuum distilling plant 20 is processed in the vacuum light oil desulfurizer 30 to obtain the desulfurized vacuum gas oil VHLGO and this desulfurized vacuum gas oil VHLGO is mixed in the mixer 70 with straight light oil LGO from the topping plant 10 and desulfurized again in the light oil desulfurizer 50.

6. 发明专利

JP2000198990A HYDROGENATION PROCESS FOR GAS OIL FRACTION 失效
公开(公告)号：JP2000198990A
公开(公告)日：2000-07-18
申请号：JP76299
申请日：1999-01-05
申请人： IDEMITSU KOSAN CO
发明人： YOSHIDA MITSURU
IPC分类号： C10L1/04 , C10G45/08 , C10G45/12 , C10G45/50 , C10G47/12 , C10G47/16 , C10L1/08
摘要： PROBLEM TO BE SOLVED: To provide a hydrogenation process for a gas oil fraction wherein a high-quality gas oil having a low sulfur content and a low polycyclics aromatics content is efficiently prepared. SOLUTION: In the presence of a hydrogenation catalyst, a gas oil fraction is mixed with a hydrocarbon oil, which has a higher boiling point than the gas oil fraction, as a diluent and hydrogenated, or a hydrogenated product is vapor-liquid separated to obtain a vapor-phase fluid which is further hydrogenation modified to prepare a gas oil having a sulfur content of 50 wt.ppm or smaller and a polycyclic aromatics content of 1 vol.% or smaller. The hydrogenation treatment is chosen from hydrodenitrification, hydrogenolysis, nuclear hydrogenation and hydrodesulfurization, and the hydrogenation catalyst is chosen from catalysts wherein metals belonging to group 6, 8, 9 or 10 of the periodic table is carried on amorphous inorganic oxide supports and zeolite-containing catalysts.

7. 发明专利

JPH0598270A CATALYTIC HYDROGENATION OF HEAVY HYDROCARBON OIL 失效
公开(公告)号：JPH0598270A
公开(公告)日：1993-04-20
申请号：JP26187191
申请日：1991-10-09
申请人： IDEMITSU KOSAN CO
发明人： YOSHIDA MITSURU , II KENICHI , KASHIMA KAZUHIRO
IPC分类号： B01J29/16 , C10G45/02 , C10G47/16 , C10G65/12 , C10G69/00
摘要： PURPOSE:To provide the title process by which a naphtha fraction and a kerosene and gas oil fraction can be efficiently produced from a heavy hydrocarbon oil in high yields. CONSTITUTION:The title process comprises hydrodemetallizing a heavy hydrocarbon oil, hydrocracking the product, and hydrodesulfurizing and hydrodenitrogenating the hydrocracking product.

8. 发明专利

JP2005213512A Hydrogenation treatment of crude oil 有权
标题翻译：原油加氢处理
公开(公告)号：JP2005213512A
公开(公告)日：2005-08-11
申请号：JP2005044685
申请日：2005-02-21
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： YOSHIDA MITSURU , OTA NOBUYUKI
IPC分类号： B01J23/28 , B01J23/88 , B01J29/08 , C10G7/00 , C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/10 , C10G45/12 , C10G65/12 , C10G65/14 , C10G65/16 , C10L1/04
CPC分类号： C10G65/12 , C10G45/02 , C10G65/16
摘要： PROBLEM TO BE SOLVED: To provide a method for hydrogenation treatment of crude oil, capable of increasing production of kerosene and light oil which have good quality and are stable, by collective hydrodesulfurization of the crude oil or naphtha fraction-removed crude oil. SOLUTION: The method comprises hydrogenation treatment of the crude oil or the naphtha-removed crude oil by using, as the catalyst, (1) (a) a group 6, 8, 9 or 10 metal carried on an alumina-boria carrier, (2) (b) a group 6, 8, 9 or 10 metal carried on a carrier comprising iron-containing aluminosilicate, or (3) a combination of the (a) catalyst and the (b) catalyst. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：通过原油或石脑油馏分去除原油的集体加氢脱硫，提供能够提高质量和稳定性的煤油和轻油的生产原油的氢化处理方法。解决方案：该方法包括使用作为催化剂的（1）（a）在氧化铝 - 氧化硼上承载的第6,8,9或10族金属对原油或去除石脑油的原油进行氢化处理载体，（2）（b）在含有铁的硅铝酸盐的载体上携带的第6,8,9或10族金属，或（3）（a）催化剂和（b）催化剂的组合。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2004263117A Catalytic hydrogenation method for crude oil 审中-公开
标题翻译：原油加氢催化加氢方法
公开(公告)号：JP2004263117A
公开(公告)日：2004-09-24
申请号：JP2003056733
申请日：2003-03-04
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： YOSHIDA MITSURU
IPC分类号： B01J23/88 , B01J21/06 , B01J23/882 , B01J27/19 , B01J29/04 , B01J29/076 , B01J29/88 , C10G45/02 , C10G47/18 , C10G47/20 , C10G65/12
CPC分类号： B01J35/1061 , B01J21/06 , B01J21/063 , B01J23/882 , B01J29/041 , B01J29/042 , B01J29/045 , B01J29/076 , B01J2229/18 , B01J2229/37 , C10G45/02 , C10G47/20 , C10G65/12
摘要： PROBLEM TO BE SOLVED: To provide a catalytic hydrogenation method and a method for producing an ultralow sulfur kerosene or gas oil from a product oil, which can produce the ultralow sulfur kerosene or gas oil having a sulfur content of less than 10 ppm and greatly improve the quality of the kerosene or gas oil in the obtained product oil when conducting a catalytic hydrogenation of crude oil or a crude oil from which naphtha fraction and a lighter fraction than the naphtha fraction are removed, as a whole.
SOLUTION: When conducting the catalytic hydrogenation of crude oil or the crude oil from which the naphtha fraction and the lighter fraction than the naphtha fraction are removed as a whole, wherein the catalytic hydrogenation comprises a step of hydrodemetallization, a step of hydrocracking, and a step of hydrodesulfurization, the catalytic hydrogenation is characterized by using as a hydrocracking catalyst a catalyst which is obtained by supporting at least one metal selected from the metals belonging to 6, 8, 9, and 10 groups in the periodic table on a catalyst carrier that is composed of a zeolite wherein ultrafine particles of a titanium group metal oxide is compounded with its mesopore inner surface.
COPYRIGHT: (C)2004,JPO&NCIPI
摘要翻译：要解决的问题：提供催化氢化方法和从产物油制备超低硫煤油或瓦斯油的方法，其可以生产硫含量小于10ppm的超低硫煤油或瓦斯油并且大大提高了所得产物油中的原油或粗油的催化氢化作用，从而从中除去石脑油馏分和比石脑油馏分更轻的馏分，从而大大提高了所得产物油中的煤油或瓦斯油的质量。解决方案：当进行原油或原油的催化氢化时，石脑油馏分和比石脑油馏分整体去除的轻馏分的原油，其中催化氢化包括加氢脱金属步骤，加氢裂化步骤和加氢脱硫的步骤，催化氢化的特征在于使用催化剂作为加氢裂化催化剂，催化剂是通过将选自金属属于6,8,9和10族的金属中的至少一种金属担载在由沸石组成的催化剂载体，其中钛族金属氧化物的超细颗粒与其中孔内表面复合。版权所有（C）2004，JPO＆NCIPI

10. 发明专利

JP2002045698A PROCESS FOR HYDROGENATION TREATMENT OF HYDROCARBON 失效
公开(公告)号：JP2002045698A
公开(公告)日：2002-02-12
申请号：JP2001084055
申请日：2001-03-23
申请人： PETROLEUM ENERGY CENTER FOUND , IDEMITSU KOSAN CO
发明人： YOSHIDA MITSURU , IINO AKIRA
IPC分类号： B01J27/19 , B01J32/00 , B01J35/10 , B01J37/02 , C10G45/08 , C10G65/04
摘要： PROBLEM TO BE SOLVED: To provide a hydrocarbon hydrogenation treatment process which enables reduction in sulfur content and nitrogen content of cracked gas oil obtained by subjecting hydrocarbons to hydrogenation treatment. SOLUTION: This hydrogenation treatment process involves (1) using a hydrogenation treatment catalyst consisting of a demetallization catalyst placed on the upstream side and two different desulfurization catalysts placed on the downstream side, one of which is used in the first stage of two-stage desulfurization and the other of which is used in the second stage of the two- stage desulfurization, wherein: (2) the desulfurization catalyst, which is placed on the downstream side and used in the second stage, contains a refractory inorganic oxide used as a carrier, nickel and molybdenum, each used as an active metal, and also phosphorus used as another component; (3) in the preparation process of the desulfurization catalyst used in the second stage, when the active metals are deposited on the carrier, a water-soluble organic compound having a >=150 deg.C boiling point or decomposition point is used; and (4) the desulfurization catalyst used in the second stage has a 60-150 Å average pore size.

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