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1. 发明专利

JPS5944393A Thiophosphatidyl ethanolamine derivative, preparation thereof and agricultural and horticultural germicide 失效
标题翻译：硫代磷脂酰胺衍生物，其制备方法和农业和生物杀菌剂
公开(公告)号：JPS5944393A
公开(公告)日：1984-03-12
申请号：JP15385482
申请日：1982-09-06
申请人： Hokko Chem Ind Co Ltd
发明人： MARUMO SHINGO , WADA KOUJIROU , WADA TAKUO , HAMADA MITSUO
IPC分类号： A01N57/12 , C07F9/10 , C07F9/165
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:A thiophosphatidyl ethanolamine derivative of formula I (R and R
1 are alkyl or fatty acid residue).
EXAMPLE: 2-Oleoyl-3-palmitoyl-1-sn-thiophosphatidyl ethanolamine.
USE: An agricultural and horticultural germicide usable safely without giving phytotoxicity to crops.
PROCESS: A glycerol derivative of formula II is reacted with a dichloro(N-2,2,2- trichloroethoxycarbonyl-2-aminoethyl)thiophosphate of formula III in a solvent, e.g. tetrahydrofuran (THF), in the presence of a condensing agent, e.g. sodium hydride, to prepare an N-(2,2,2-trichloroethoxycarbonyl)thiophosphatidyl ethanolamine derivative of formula IV, which is then reacted with zinc in acetic acid to remove the protecting group of the amino group. Thus, the aimed compound of formula I is prepared.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：式I的硫代磷脂酰乙醇胺衍生物（R和R 1是烷基或脂肪酸残基）。实施例：2-油酰基-3-棕榈酰-1-硫代磷脂酰乙醇胺。用途：农业和园艺杀虫剂可安全使用，不对作物造成植物毒性。方法：将式II的甘油衍生物与式III的二氯（N-2,2,2-三氯乙氧基羰基-2-氨基乙基）硫代磷酸酯在溶剂如四氢呋喃（THF），在缩合剂的存在下，例如氢化钠，制备式Ⅳ的N-（2,2,2-三氯乙氧基羰基）硫代磷酰基乙醇胺衍生物，然后与乙酸中的锌反应，除去氨基的保护基。因此，制备目标化合物式I。

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