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    • 3. 发明专利
    • Manufacturing method and continuous manufacturing apparatus of a substrate for generating carbon nanotubes
    • 用于生产碳纳米管的基板的制造方法和连续制造装置
    • JP2014094856A
    • 2014-05-22
    • JP2012246952
    • 2012-11-09
    • Hitachi Zosen Corp日立造船株式会社
    • IMASAKA SATOSHIINOUE TETSUYA
    • C01B31/02B01J23/745B01J37/02
    • PROBLEM TO BE SOLVED: To provide a manufacturing method and a continuous manufacturing apparatus of a substrate for generating carbon nanotubes each capable of reducing the manufacturing cost and abbreviating the manufacturing process.SOLUTION: In the provided method for manufacturing a substrate 1 for generating carbon nanotubes possessing a substrate 2, an intermediate layer 3 formed atop the substrate 2, and a catalyst layer 4 formed atop the intermediate layer 3, a mixed solution 34 obtained by mixing an intermediate layer precursor solution 3' and a catalyst layer precursor solution 4' and phase-separable into the intermediate layer precursor solution 3' forming a lower phase and the catalyst layer precursor solution 4' forming an upper phase is coated atop the substrate 2, and after the mixed solution 34 coated atop the substrate 2 has been phase-separated into a lower phase 3' and an upper phase 4', the intermediate layer 3 and the catalyst layer 4 are formed by drying the mixed solution phase-separated into the lower phase 3' and upper phase 4'.
    • 要解决的问题:提供一种用于生成碳纳米管的基板的制造方法和连续制造装置,每个碳纳米管能够降低制造成本并缩短制造工艺。解决方案:在所提供的用于生产碳纳米管的基板1的制造方法 具有基板2,在基板2的上方形成的中间层3和形成在中间层3顶部的催化剂层4,将中间层前体溶液3'和催化剂层前体溶液4'混合而得到的混合溶液34和 相分离成形成下层的中间层前体溶液3',形成上层的催化剂层前体溶液4'涂布在基板2的顶部,在涂布在基板2上方的混合溶液34已经相分离 进入下相3'和上相4',中间层3和催化剂层4通过干燥混合物形成 溶液相分离成下相3'和上相4'。
    • 5. 发明专利
    • Method for manufacturing counter electrode of dye-sensitized solar battery, method for manufacturing dye-sensitized solar battery and dye-sensitized solar battery
    • 用于制造透明太阳能电池的计数器电极的方法,用于制造透明的太阳电池和透明的太阳能电池的方法
    • JP2013065418A
    • 2013-04-11
    • JP2011202497
    • 2011-09-16
    • Toin Gakuen学校法人桐蔭学園Hitachi Zosen Corp日立造船株式会社
    • MIYASAKA TSUTOMUIKEGAMI KAZUYUKIOKUMURA TAKUROSUGIO TAKESHIINOUE TETSUYA
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a counter electrode of a dye-sensitized solar battery which has a high catalyst performance even if platinum is not used for the counter electrode, and which allows the dye-sensitized solar battery with the counter electrode to achieve a high battery performance, a method for manufacturing such a dye-sensitized solar battery, and a dye-sensitized solar battery.SOLUTION: The method is one for manufacturing a counter electrode 2 of a dye-sensitized solar battery which has a photoelectrode 5 including a transparent conductive substrate 1 on which a semiconductor porous film 4 is formed, a counter electrode 2 including a counter electrode substrate 21 on which a carbon layer 22 is formed, on which a catalyst film is formed, and an electrolytic layer 3 disposed between the electrodes 2 and 5. In the method, the carbon layer 22 is formed by preparing a paste of a carbon solution with carbon powder dissolved in a solvent, and applying or printing the paste of the carbon solution to the counter electrode substrate 21, and baking it. Then, the carbon layer 22 is immersed in a p-type semiconductor precursor solution, and baked. Thus, p-type semiconductor fine particles 23 are held by the carbon layer 22, and the catalyst film is formed.
    • 解决的问题:为了提供一种即使铂不用于对电极也具有高催化剂性能的染料敏化太阳能电池的对电极的制造方法,并且允许染料敏化太阳能电池 与对电极实现高电池性能,制造这种染料敏化太阳能电池的方法和染料敏化太阳能电池。 解决方案:该方法是用于制造染料敏化太阳能电池的对电极2的方法,该染料敏化太阳能电池具有包括其上形成有半导体多孔膜4的透明导电基板1的光电极5,包括计数器的对电极2 在其上形成有碳层22的电极基板21,形成有催化剂膜的电极层21和设置在电极2和5之间的电解质层3.在该方法中,通过制备碳 溶解在溶剂中的碳粉末,将碳溶液的糊料涂布或印刷到对电极基板21上,并进行烘烤。 然后,将碳层22浸渍在p型半导体前体溶液中,并进行烘烤。 因此,p型半导体微粒23被碳层22保持,形成催化剂膜。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Method for forming photocatalyst film in dye-sensitized solar battery, and dye-sensitized solar battery
    • 在透明太阳能电池中形成光催化薄膜的方法和透明的太阳能电池
    • JP2012156071A
    • 2012-08-16
    • JP2011015855
    • 2011-01-28
    • Hitachi Zosen Corp日立造船株式会社
    • SUGIO TAKESHIINOUE TETSUYA
    • H01M14/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a method for forming a photocatalyst film in a dye-sensitized solar battery which allows the further enhancement of the electron conductivity from a pigment to a transparent conductive film to improve the battery performance, and to provide a dye-sensitized solar battery.SOLUTION: The method for forming, in a dye-sensitized solar battery having a transparent electrode 1, a counter electrode, an electrolytic layer disposed between the electrodes, and a photocatalyst film 4 disposed on the side of the transparent electrode 1 between the electrodes, the photocatalyst film 4 comprises: forming a porous film by applying a mixture including conductive nitride microparticles 41 and titanium oxide microparticles 44 to a surface of the transparent electrode 1, and then burning the transparent electrode with the mixture.
    • 要解决的问题:提供一种在染料敏化太阳能电池中形成光催化剂膜的方法,其能够进一步提高从颜料到透明导电膜的电子传导性,从而提高电池性能,并提供 染料敏化太阳能电池。 解决方案:在具有透明电极1的染料敏化太阳能电池中形成对电极,设置在电极之间的电解质层和设置在透明电极1侧的光催化剂膜4之间的方法 电极,光催化剂膜4包括:通过将包含导电氮化物微粒41和氧化钛微粒44的混合物施加到透明电极1的表面,然后用该混合物燃烧透明电极来形成多孔膜。 版权所有(C)2012,JPO&INPIT
    • 7. 发明专利
    • Vapor deposition apparatus
    • 蒸气沉积装置
    • JP2012021194A
    • 2012-02-02
    • JP2010160158
    • 2010-07-15
    • Hitachi Zosen Corp日立造船株式会社
    • DAIKU HIROYUKIINOUE TETSUYA
    • C23C14/24H01L51/50H05B33/10
    • PROBLEM TO BE SOLVED: To provide a vapor deposition apparatus preventing degradation in the quality of a vapor-deposited film by preventing degradation in a vapor deposition material even during a continuous operation.SOLUTION: The vapor deposition apparatus vaporizes a vapor deposition material L filled in an evaporation container 11 and vapor-deposits the vaporized material on a substrate held in the vapor deposition container. The vapor deposition apparatus includes: a container holder 12 for holding and cooling the evaporation container 11; a heating device 15 for heating a surface portion of the vapor deposition material L by a heating lamp 16 and a reflecting plate 17; and a laser beam sensor 19 for detecting the surface position of the vapor deposition material L, wherein the container holder 12 is constituted of a loading part 21 for supporting a bottom part of the evaporation container 11, and an outer peripheral part 23 which covers a side portion of the evaporation container 11 and to which the heating lamp 16 and the reflecting plate 17 are attached. The vapor deposition apparatus further includes: an elevating/lowering device 14 for elevating/lowering the loading part 21; and a control device 9 which controls, based on the surface position of the vapor deposition material L detected by the laser beam sensor 19, the elevating/lowering device 14 to thereby maintain the heating lamp 16 and the reflecting plate 17, and the surface position at the predetermined distance.
    • 要解决的问题:提供一种气相沉积装置,即使在连续操作期间也防止气相沉积材料的劣化,从而防止气相沉积膜的质量下降。 解决方案:气相沉积设备使填充在蒸发容器11中的气相沉积材料L蒸发,并将气化沉积在保持在气相沉积容器中的基底上。 蒸镀装置具备容器保持部12,其容纳并冷却蒸发容器11; 用于通过加热灯16和反射板17加热气相沉积材料L的表面部分的加热装置15; 以及用于检测气相沉积材料L的表面位置的激光束传感器19,其中容器保持器12由用于支撑蒸发容器11的底部的装载部分21和覆盖蒸发容器11的底部的外周部分23构成。 蒸发容器11的侧面部分,并且加热灯16和反射板17安装在该侧部分上。 蒸镀装置还具备升降装载部21的升降装置14, 以及控制装置9,其基于由激光束传感器19检测的蒸镀材料L的表面位置,升降装置14,从而保持加热灯16和反射板17以及表面位置 在预定距离处。 版权所有(C)2012,JPO&INPIT
    • 8. 发明专利
    • Method of forming buffer layer in dye-sensitized solar cell
    • 形成缓冲层在透明太阳能电池中的方法
    • JP2011142028A
    • 2011-07-21
    • JP2010002441
    • 2010-01-08
    • Hitachi Zosen Corp日立造船株式会社
    • SUGIO TAKESHIINOUE TETSUYA
    • H01M14/00
    • H01G9/2031H01G9/2059H01L51/0027Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a method of forming a buffer layer in a dye-sensitized solar cell, the method using as a substrate a material weak to high temperature such as a synthetic resin.
      SOLUTION: The method of forming the buffer layer 5 arranged between a transparent electrode and a photocatalyst film in the dye-sensitized solar cell provided with the transparent electrode, a counter electrode, an electrolyte layer arranged between the both electrodes, and the photocatalyst film arranged between the both electrodes and further toward a transparent electrode side is a method of forming the buffer layer by supplying mixture solution made by mixing metal alkoxide in alcohol solution by 0.03 to 5 mass% on the surface of the transparent electrode 1 rotated by a rotating pedestal 2 and coating it in a spin coating method, and then, sintering it with irradiation of laser light.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供在染料敏化太阳能电池中形成缓冲层的方法,该方法使用合成树脂等弱至高温的材料作为基底。 解决方案:在设置有透明电极,对电极,布置在两个电极之间的电解质层的染料敏化太阳能电池中,形成布置在透明电极和光催化剂膜之间的缓冲层5的方法,以及 布置在两个电极之间并且进一步朝向透明电极侧的光催化剂膜是通过将透明电极1的金属醇盐与醇溶液中的金属醇盐混合0.03〜5质量%混合而形成缓冲层的方法, 旋转底座2,以旋涂法涂布,然后用激光照射烧结。 版权所有(C)2011,JPO&INPIT
    • 9. 发明专利
    • Photoelectric conversion element and its manufacturing method
    • 光电转换元件及其制造方法
    • JP2009218152A
    • 2009-09-24
    • JP2008062376
    • 2008-03-12
    • Hitachi Zosen Corp日立造船株式会社
    • SUGIO TAKESHIINOUE TETSUYA
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a photoelectric conversion element with high power generation efficiency though using solidified electrolyte, and doing without a short-circuit prevention layer.
      SOLUTION: In the photoelectric conversion element with an electrode 1 to be a negative electrode and a counter electrode 4 as a positive electrode arranged in opposition, the electrode 1 has a transparent conductive film 3 formed on one face of an electrode-use transparent substrate 2, while the counter electrode 4 has a solid electrolyte layer 8 on the surface of a brush-like carbon nanotube group 7 provided on one face of a substrate 5 for the counter electrode through a conductive adhesive layer 6, and further, has a photocatalyst film 11 dyed with photosensitized dye 9 formed on a surface of the layer 8.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种通过使用固化的电解质制造具有高发电效率的光电转换元件的方法,并且不进行短路防止层。 解决方案:在电极1为负极的光电转换元件和相对配置的正电极对置电极4中,电极1具有形成在电极使用的一个面上的透明导电膜3 透明基板2,而对电极4在通过导电粘合剂层6设置在用于对电极的基板5的一个表面上的刷状碳纳米管组7的表面上具有固体电解质层8,并且还具有 用形成在层8的表面上的光敏染料9染色的光催化剂膜11.版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Recycling method for valuable metal
    • 有价值金属的回收方法
    • JP2009185389A
    • 2009-08-20
    • JP2009114703
    • 2009-05-11
    • Hitachi Zosen Corp日立造船株式会社
    • YANO ATSUSHIDAIKU HIROYUKIINOUE TETSUYA
    • C22B7/00B09B3/00C22B3/04C22B3/44C22B11/00C22B58/00
    • Y02P10/234
    • PROBLEM TO BE SOLVED: To provide a recycling method for valuable metals which achieves efficient extraction, recovery and regeneration of In (indium) and Ag (silver) as electrode materials from waste products of flat panel displays such as a liquid crystal display panel or plasma display, can be utilized as an economically and environmentally effective means and has a large propagation effect on display production aiming at cost reduction. SOLUTION: The recycling method for valuable metals includes: immersing the waste flat panel display into an HNO 3 solution; filtering the solution to separate the solution containing In and Ag from a residue; adding KCl or NaCl to the In/Ag-containing solution to obtain an In-containing solution and AgCl precipitate; concentrating the In-containing solution to prepare the solution having a prescribed In concentration; spraying the prepared In-containing solution onto a substrate to form an In-containing transparent film on the substrate; and burning the AgCl precipitate to recover Ag. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种有价值的金属的回收方法,其实现了作为电极材料的In(铟)和Ag(银)的有效提取,回收和再生,从平板显示器的诸如液晶显示器 面板或等离子体显示器,可以用作经济上和环境上有效的手段,并且为了降低成本而对显示器生产具有很大的传播效果。

      解决方案:有价值金属的回收方法包括:将废平面显示器浸入HNO 3 SBS溶液中; 过滤溶液以将含有In和Ag的溶液与残留物分离; 向含In / Ag的溶液中加入KCl或NaCl,得到含In溶液和AgCl沉淀物; 浓缩含In溶液以制备具有规定In浓度的溶液; 将制备的含In溶液喷涂到基材上,以在基材上形成含In透明膜; 并燃烧AgCl沉淀物以回收Ag。 版权所有(C)2009,JPO&INPIT