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1. 发明专利

JP2011251857A Electrothermal supplying type organic hydride station 审中-公开
标题翻译：电热供应型有机氢气站
公开(公告)号：JP2011251857A
公开(公告)日：2011-12-15
申请号：JP2010125034
申请日：2010-05-31
申请人： Hitachi Ltd , Japan Petroleum Energy Center , Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , 一般財団法人石油エネルギー技術センター , 株式会社日立製作所
发明人： SEGAWA ATSUSHI , KOBAYASHI YUKIO , KONNO HIROBUMI , ISHIKAWA TAKAO , NOJIMA MASAFUMI , SHIMADA ATSUSHI
IPC分类号： C01B3/00 , C01B3/24 , C07C5/367 , C07C15/06 , F02M21/02 , H01M8/00 , H01M8/06 , H01M8/12
CPC分类号： Y02P20/123 , Y02T10/166 , Y02T10/32
摘要： PROBLEM TO BE SOLVED: To provide an electrothermal supplying type organic hydride station which can raise energy efficiency as the whole station.SOLUTION: The electrothermal supplying type organic hydride station includes: an electrothermal supplying device 8 which can alter a ratio of a heat amount and an electric amount to generate while generating heat and electricity; a dehydrogenation reaction vessel 2 in which heat is supplied from the electrothermal supplying device 8 and which performs a dehydrogenation reaction of an organic hydride; a hydrogen compressor 5 in which electricity is supplied from the electrothermal supplying device 8 and which compresses hydrogen taken out from the organic hydride; and a controller 11 which establishes a service condition of the electrothermal supplying device 8 based on an amount of electricity needed in the station, and starts simultaneously the dehydrogenation reaction vessel 2 and the hydrogen compressor 5.
摘要翻译：要解决的问题：提供能够提高整个站的能量效率的电热供给型有机氢化物站。电解供给型有机氢化物站包括：电热供给装置8，其可以改变在产生热量和电力时产生的热量和电量的比率; 脱氢反应容器2，其中从电热供应装置8供应热量并进行有机氢化物的脱氢反应; 氢压缩机5，其从电热供给装置8供给电力，压缩从有机氢化物取出的氢; 和控制器11，其基于站内所需的电量建立电热供应装置8的服务状态，同时开始脱氢反应容器2和氢压缩机5.版权所有（C）2012， JPO＆INPIT

2. 发明专利

JP2011251858A Heat exchange type organic hydride dehydrogenation system 有权
标题翻译：热交换型有机氢脱氢脱氢系统
公开(公告)号：JP2011251858A
公开(公告)日：2011-12-15
申请号：JP2010125041
申请日：2010-05-31
申请人： Hitachi Ltd , Japan Petroleum Energy Center , Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , 一般財団法人石油エネルギー技術センター , 株式会社日立製作所
发明人： SEGAWA ATSUSHI , KOBAYASHI YUKIO , KONNO HIROBUMI , ISHIKAWA TAKAO , NOJIMA MASAFUMI , SHIMADA ATSUSHI
IPC分类号： C01B3/26 , C07B61/00 , C07C5/367 , C07C15/06
摘要： PROBLEM TO BE SOLVED: To provide a heat exchange type organic hydride dehydrogenation system which can efficiently supply heat to dehydrogenation reaction.SOLUTION: Dehydrogenation catalyst plates 21A-21D are laminated with heat transfer plates 22A-22D and partition plates 23A and 23B. An MCH flow passage and a high temperature gas passage are composed to adjoin through each of the plates with such a laminate composition. A high temperature gas which flows in the high temperature gas passage can supply heat to dehydrogenation reaction in the MCH flow passage making each of plates as a member for heat exchange. When making the laminated structure, a surface area of a catalyst for dehydrogenation reaction and an area of a part concerning heat exchange can be composed to have an equal size. Therefore, heat transfer to dehydrogenation reaction can be performed efficiently. Moreover, a gap between the plates is narrowed, and thereby it also becomes possible to narrow a space for dehydrogenation reaction.
摘要翻译：要解决的问题：提供一种可有效地向脱氢反应提供热量的热交换型有机氢化物脱氢系统。脱氢催化剂板21A-21D层叠有传热板22A-22D和隔板23A和23B。 MCH流路和高温气体通道被构成为通过这些层压组合物与每个板相邻。在高温气体通道中流动的高温气体可以在MCH流路中向脱氢反应提供热量，使每个板作为热交换的构件。当制造层压结构时，用于脱氢反应的催化剂的表面积和与热交换有关的部分的面积可以构成为具有相同的尺寸。因此，可以有效地进行到脱氢反应的热传递。此外，板之间的间隙变窄，从而也可能缩小脱氢反应的空间。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2010279876A System for dehydrogenating organic hydride 审中-公开
标题翻译：脱氢有机液体系统
公开(公告)号：JP2010279876A
公开(公告)日：2010-12-16
申请号：JP2009133898
申请日：2009-06-03
申请人： Hitachi Ltd , Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , Petroleum Energy Center , 株式会社日立製作所 , 財団法人石油産業活性化センター
发明人： SEGAWA ATSUSHI , KOBAYASHI YUKIO , KONNO HIROBUMI , ISHIKAWA TAKAO
IPC分类号： B01J38/12 , B01J23/96 , C01B3/26
CPC分类号： Y02P20/584
摘要： PROBLEM TO BE SOLVED: To provide a method for operating a system for dehydrogenating organic hydride, in which system a special unit is not required but which system has excellent energy efficiency. SOLUTION: The method for dehydrogenating organic hydride to withdraw hydrogen comprises: a dehydrogenation step of performing a dehydrogenation reaction of the organic hydride at predetermined dehydrogenation temperature by using a dehydrogenation catalyst to withdraw hydrogen; and an activation step of bringing air into contact with the used dehydrogenation catalyst to activate the used dehydrogenation catalyst the activity of which is deteriorated owing to the coke stuck thereto. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于操作用于使有机氢化物脱氢的系统的方法，其中系统不需要特殊单元，但是哪个系统具有优异的能量效率。解决方案：将有机氢化物脱氢以脱氢的方法包括：通过使用脱氢催化剂在预定脱氢温度下进行脱氢反应以脱氢的脱氢步骤; 以及使空气与使用的脱氢催化剂接触的活化步骤，以活化所用的脱氢催化剂，其活性由于粘附在其上的焦炭而劣化。版权所有（C）2011，JPO＆INPIT

4. 发明专利

JP2014073922A Hydrogen supply system 审中-公开
标题翻译：氢供应系统
公开(公告)号：JP2014073922A
公开(公告)日：2014-04-24
申请号：JP2012221379
申请日：2012-10-03
申请人： Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , Hitachi Ltd , 株式会社日立製作所
发明人： SEGAWA ATSUSHI , IKI SUGURU , OKAZAKI JUNJI , NEMOTO NORIAKI , INADA KAZUHIRO , ISHIKAWA TAKAO , TAKAMURA TETSUO , FUSHIMI TOMOAKI
IPC分类号： C01B3/26
摘要： PROBLEM TO BE SOLVED: To improve durability of a reactor performing dehydrogenation reaction without enlarging the reactor.SOLUTION: An off-gas line GL1, which supplies off-gas to a dehydrogenation reactor 3, supplies a part or all of off-gas from a hydrogen purifier 8 to the dehydrogenation reactor 3, which makes it possible to perform dehydrogenation reaction under coexistence of hydrogen. Further, off-gas is gas from which dehydrogenation product could not be removed by the hydrogen purifier 8, out of hydrogen-containing gas from the dehydrogenation reactor 3. Therefore, by allowing the off-gas line GL1 to supply the off-gas to the dehydrogenation reactor 3 and making it possible to remove dehydrogenation product by the hydrogen purifier 8 again, hydrogen of a target amount can be obtained without enlarging the dehydrogenation reactor 3 even if removal efficiency in the hydrogen purifier 8 is low. Thus, durability of the reactor can be improved without enlarging the reactor which performs dehydrogenation reaction.
摘要翻译：要解决的问题：提高进行脱氢反应的反应器的耐久性，而不增加反应器。解决方案：向脱氢反应器3供应废气的废气管线GL1将一部分或全部废气从氢气净化器8到脱氢反应器3，这使得可以在氢共存下进行脱氢反应。此外，废气是来自脱氢反应器3的含氢气体从氢净化器8不能除去脱氢产物的气体。因此，通过使废气管线GL1将废气供给到脱氢反应器3，并且即使氢净化器8的除去效率低，也可以再次利用氢净化器8除去脱氢产物而不扩大脱氢反应器3的目标量的氢。因此，可以提高反应器的耐久性，而不会扩大进行脱氢反应的反应器。

5. 发明专利

JP2014073923A Hydrogen purification system and hydrogen feeding system 审中-公开
标题翻译：氢气净化系统和氢气进料系统
公开(公告)号：JP2014073923A
公开(公告)日：2014-04-24
申请号：JP2012221381
申请日：2012-10-03
申请人： Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , Hitachi Ltd , 株式会社日立製作所
发明人： SEGAWA ATSUSHI , IKI SUGURU , OKAZAKI JUNJI , NEMOTO NORIAKI , INADA KAZUHIRO , ISHIKAWA TAKAO , TAKAMURA TETSUO , FUSHIMI TOMOAKI
IPC分类号： C01B3/50 , C01B3/26
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen purification system in which the miniaturization of the whole of a hydrogen feeding system can be achieved, and the hydrogen feeding system.SOLUTION: The hydrogen purification system 120 comprises: a compressor 21 making a hydrogen-containing gas into a high pressure state; and a cooler 23 making the hydrogen-containing gas into a cool state. The hydrogen-containing gas is made into the cool state by the coolant 23 after made in to the high pressure state by the compressor 21, thus is made into a state where the gas can be fed to FCV 30 as the feed destination of the external part of the system. Further, a gas-liquid separator 24 performs the gas-liquid separation of the hydrogen-containing gas in either state of the high pressure state by the compressor 21 or the cool state by the coolant 23, thus can increase the purity of the hydrogen-containing gas. In this way, the compressor 21 and the cooler 23 required for hydrogen feed obviate a separately provided personal apparatus or reduces the same to refine hydrogen, and the miniaturization of the whole of the system can be achieved.
摘要翻译：要解决的问题：提供一种氢气净化系统，其中可以实现氢供给系统的整体的小型化和氢气供给系统。解决方案：氢气净化系统120包括：制造含氢的气体进入高压状态; 以及使含氢气体成为冷却状态的冷却器23。在由压缩机21制成高压状态之后，通过冷却液23将含氢气体制成冷态，由此成为能够作为外部的进给目的地的气体供给到FCV 30的状态系统的一部分。此外，气液分离器24通过压缩机21进行高压状态的任一状态下的含氢气体的分液或冷却液23的冷却状态的气液分离，含气。以这种方式，用于氢气进料所需的压缩机21和冷却器23避免单独提供的个人装置或减少氢气，从而可以实现整个系统的小型化。

6. 发明专利

JP2011251916A System for dehydrogenating organic hydride 有权
标题翻译：脱氢有机液体系统
公开(公告)号：JP2011251916A
公开(公告)日：2011-12-15
申请号：JP2010125043
申请日：2010-05-31
申请人： Hitachi Ltd , Jx Nippon Oil & Energy Corp , Jx日鉱日石エネルギー株式会社 , 株式会社日立製作所
发明人： SEGAWA ATSUSHI , IKI SUGURU , KONNO HIROBUMI , ISHIKAWA TAKAO , NOJIMA MASAFUMI , SHIMADA ATSUSHI
IPC分类号： C07C5/367 , C01B3/02 , C01B3/26 , C07C15/06 , C25B1/04 , F02M21/02 , H01M8/06 , H01M8/12
CPC分类号： Y02E60/366 , Y02E70/10 , Y02E70/20 , Y02P20/133 , Y02T10/166 , Y02T10/32
摘要： PROBLEM TO BE SOLVED: To provide a system for dehydrogenating an organic hydride, which system can effectively utilize electricity generated by its cogeneration device and can be made compact.SOLUTION: A cogeneration device 8 generates heat, and can supply the resulting heat to the dehydrogenation reaction of MCH (methylcyclohexane). Thus, hydrogen resulting from the dehydrogenation of MCH can be supplied. The cogeneration device 8 generates electricity and can supply the water electrolysis device 12 with the electricity generated thereby. Thus, the electricity generated by the cogeneration device 8 can effectively be utilized by further producing hydrogen using the electricity generated by the cogeneration device 8. The amount of hydrogen supplied in the system as a whole can be increased due to obtainment of not only hydrogen resulting from the dehydrogenation of MCH but also hydrogen produced by the water electrolysis device 12 can be obtained.
摘要翻译：要解决的问题：为了提供一种用于使有机氢化物脱氢的系统，该系统可以有效地利用其热电联产装置产生的电力并且可以制造得紧凑。解决方案：热电联产装置8产生热量，并将所得热量提供给MCH（甲基环己烷）的脱氢反应。因此，可以提供由MCH的脱氢产生的氢。热电联供装置8发电，能够向水电解装置12供给由此产生的电力。因此，通过使用热电联供装置8产生的电力进一步产生氢，可以有效地利用热电联产装置8产生的电力。由于不仅获得氢气，所以在系统中提供的氢总量可以增加，可以得到MCH的脱氢，也可以得到由水电解装置12产生的氢。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2013120506A Apparatus, method, and program for supporting energy selection 有权
标题翻译：用于支持能源选择的装置，方法和程序
公开(公告)号：JP2013120506A
公开(公告)日：2013-06-17
申请号：JP2011268458
申请日：2011-12-08
申请人： Hitachi Ltd , 株式会社日立製作所
发明人： NOJIMA MASAFUMI , ISHIKAWA TAKAO
IPC分类号： G06Q50/06 , G06Q50/26
摘要： PROBLEM TO BE SOLVED: To provide an energy selection support apparatus capable of selecting raw fuel based on an assumption of using green power.SOLUTION: An energy selection support apparatus stores an amount of energy demand for each future date; stores an amount of available energy, which is an amount of purchasable energy, from each energy supplier for each future date; allows amounts of energy demand in future dates to be entered and stores the same; predicts weather data or obtains predicted weather data for the future dates that has been entered; reviews the amount of available energy from each energy supplier who supplies energy transformed from natural energy based on the predicted weather data and stores revised amount of available energy; and determines energy suppliers and corresponding amounts of available energy to be purchased therefrom for each future date such that the sum of the amounts of available energy from a plurality of energy suppliers is at least equal to the entered amount of energy demand.
摘要翻译：要解决的问题：提供一种能够基于使用绿色电力的假设来选择原料燃料的能量选择支持装置。解决方案：能量选择支持装置存储每个未来日期的能量需求量; 从每个能源供应商的每个未来日期存储一定量的可用能源，即可购买能源的数量; 允许在未来日期输入能量需求量并存储相同; 预测天气数据或获取未来日期的预测天气数据; 根据预测的天气数据，审查从能源转换的能源供应商的可用能源数量，并存储修订的可用能源数量; 并且确定在每个将来的日期中要从其购买的能量供应商和相应的可用能量的量，使得来自多个能源供应商的可用能量的总和至少等于输入的能量需求量。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2013084360A Membrane-electrode assembly, and device for organic hydride production 审中-公开
标题翻译：膜电极组件和有机水生产装置
公开(公告)号：JP2013084360A
公开(公告)日：2013-05-09
申请号：JP2011221674
申请日：2011-10-06
申请人： Hitachi Ltd , 株式会社日立製作所
发明人： HIRAE TAKAYUKI , ISHIKAWA TAKAO
IPC分类号： H01M8/00 , B01D61/00 , H01M4/86 , H01M8/02 , H01M8/10
CPC分类号： C25B3/04 , C25B11/04 , C25B11/0442
摘要： PROBLEM TO BE SOLVED: To provide a membrane-electrode assembly which can offer a high energy efficiency even in the case of producing an organic hydride in one stage by use of a single device, and a device for organic hydride production.SOLUTION: The membrane-electrode assembly comprises: a cathode catalyst layer 22; an anode catalyst layer 23; and a solid polymer electrolyte film 21 disposed between the cathode and anode catalyst layers. The cathode catalyst layer 22 includes a catalyst metal 24 for making a material to be hydrogenated a hydride, and a carrier 25 thereof. The carrier 25 has, on its own surface, a functional group 27 capable of weakening the wettability for the material to be hydrogenated. In the device for organic hydride production, the membrane-electrode assembly is used.
摘要翻译：要解决的问题：提供即使在通过使用单个装置在一个阶段中生产有机氢化物的情况下也能够提供高能量效率的膜电极组件和用于生产有机氢化物的装置。膜电极组件包括：阴极催化剂层22; 阳极催化剂层23; 以及设置在阴极和阳极催化剂层之间的固体聚合物电解质膜21。阴极催化剂层22包括用于使氢化物氢化的催化剂金属24及其载体25。载体25在其自身的表面上具有能够削弱待氢化材料的润湿性的官能团27。在用于生产有机氢的装置中，使用膜 - 电极组件。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2011058446A Engine using hydrogen, dehydrogenation reactor, and method for manufacturing the same 审中-公开
标题翻译：使用氢的发动机，脱氢反应器及其制造方法
公开(公告)号：JP2011058446A
公开(公告)日：2011-03-24
申请号：JP2009210227
申请日：2009-09-11
申请人： Hitachi Ltd , 株式会社日立製作所
发明人： SANO SATOSHI , TOGASHI MORINORI , ISHIKAWA TAKAO , SHIMADA ATSUSHI
IPC分类号： F02M27/02 , C01B3/26 , F01N5/02 , F02M21/02
CPC分类号： Y02T10/16 , Y02T10/32
摘要： PROBLEM TO BE SOLVED: To efficiently transmit heat energy carried by exhaust gas to a fuel side which is low temperature fluid in a dehydrogenation reactor forming hydrogen from fuel such as gasoline by using heat of exhaust gas of an engine.
SOLUTION: In the dehydrogenation reactor 21, fluid channels 51 in which fuel is introduced and exhaust gas channels 52 in which exhaust gas is introduced are alternately laminated in a plurality of layers, metal porous bodies 61 (61a, 61b, 61c) are filled in the exhaust gas channels 52, and an average pore diameter of the metal porous body is smaller at a downstream side (61c) than an upstream side (61a) in a view of an exhaust gas flow direction.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：通过使用发动机的排气的热，有效地将排气所携带的热能传递到来自通过汽油等燃料形成氢的脱氢反应器中的低温流体的燃料侧。解决方案：在脱氢反应器21中，引入燃料的流体通道51和引入废气的废气通道52交替层叠在多层中，金属多孔体61（61a，61b，61c）在排气流路52中填充有排气通道52，并且在排气流动方向上，在下游侧（61c）比金属多孔体的平均孔径小于上游侧（61a）。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2010174766A Hydrogen engine system 审中-公开
标题翻译：氢发动机系统
公开(公告)号：JP2010174766A
公开(公告)日：2010-08-12
申请号：JP2009018945
申请日：2009-01-30
申请人： Hitachi Ltd , 株式会社日立製作所
发明人： SANO SATOSHI , TOGASHI MORINORI , ISHIKAWA TAKAO , SHIMADA ATSUSHI
IPC分类号： F02M27/02 , C01B3/26
摘要： PROBLEM TO BE SOLVED: To provide an engine system reducible in the size a system and high in hydrogen gas formation capacity by efficiently collecting exhaust heat from an engine and progressing a dehydrogenation reaction in a reactor.
SOLUTION: The engine system using hydrogen generated by the reaction of exhaust gas and fuel includes an exhaust gas channel in which exhaust gas flows, the reactor disposed in the exhaust gas channel and carrying catalysts, a high temperature pre-heater disposed in the exhaust gas channel at an upstream of the reactor, and a pre-heater disposed in the exhaust gas channel at a downstream of the reactor. Fuel passes through in order of the pre-heater, the high temperature pre-heater, and the reactor.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：通过有效地收集来自发动机的废热并且在反应器中进行脱氢反应来提供可缩小系统尺寸和高氢气形成能力的发动机系统。解决方案：使用由废气和燃料反应产生的氢气的发动机系统包括废气流动的废气通道，设置在废气通道中的反应器和承载催化剂，设置在废气通道中的高温预热器反应器上游的废气通道，以及设置在反应器下游的废气通道中的预热器。燃料按预热器，高温预热器和反应器的顺序通过。版权所有（C）2010，JPO＆INPIT

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