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    • 4. 发明专利
    • Cell for regeneration of reducible solvent and chemical decontamination method using said cell
    • 用于再生可再生溶剂的细胞和使用固体细胞的化学去除方法
    • JPS58180284A
    • 1983-10-21
    • JP6229882
    • 1982-04-16
    • Hitachi Eng Co LtdHitachi Ltd
    • SUMIDA NOBUOITOU HISAOSAITOU TAKASHIKOBAYASHI MASATOFURUYA YASUMASA
    • C02F1/469C02F1/46G21C19/30G21C19/307G21F9/00G21F9/06G21F9/28
    • PURPOSE: To obtain a cell for regeneration of a reducible soln. having excellent regeneration efficiency, by disposing a cathode made of a high hydrogen voltage conductive sealing material so as to contact with the surface of diaphragm which segments an anode chamber and a cathode chamber.
      CONSTITUTION: An electrochemical cell 3 is divided to an anode chamber 31 and a cathode chamber 32, and a diaphragm 33 adhered tightly with a porous cathode electrode 8 and an anode electrode 9 on a cation exchange membrance 7 is incorporated between the chambers 31 and 32. An electric power source 10 is connected to the electrodes 8, 9. A deareation tank 11 is provided to remove the dissolved oxygen in decontaminating liquid in addition to the above for the purpose of improving reduction efficiency. The liquid is bubbled in the tank 11 by using a gas cylinder 12. The liquid to be decontaminated is fed through a feed port 13 into the decontamination device. The eluate of the decontamination stage is removed with a filtering and desalting device 14.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:获得可还原溶胶再生细胞。 通过将由高氢压导电密封材料构成的阴极配置成与分隔阳极室和阴极室的隔膜的表面接触而具有优异的再生效率。 构成:电化学电池3被分成阳极室31和阴极室32,并且在室31和32之间并入有在多孔阴极8和阳极交换膜7上的阳极9紧密粘合的隔膜33 电源10连接到电极8,9上。为了提高还原效率,除了上述以外,还提供除气槽11除去去污液体中的溶解氧。 通过使用气瓶12将液体鼓泡在罐11中。待净化的液体通过进料口13进入去污装置。 去污阶段的洗脱液用过滤和脱盐装置14去除。
    • 6. 发明专利
    • Method for removing dye using electrolytic oxidation method
    • 使用电解氧化方法去除染色体的方法
    • JPS58217688A
    • 1983-12-17
    • JP10064982
    • 1982-06-14
    • Hitachi Eng Co LtdHitachi Ltd
    • SUMIDA NOBUOKATAOKA ICHIROUITOU HISAOSAITOU TAKASHIFURUYA YASUMASA
    • C25F3/00C25D1/04
    • PURPOSE: To oxidatively dissolving oxide and to regenerate a liquid, by a method wherein a liquid contacted with the oxide on the surface of a metal is subjected to electrolytic oxidation on an anode and the redox potential of the liquid is moved to a noble direction from a Fermi level.
      CONSTITUTION: An object to be washed having oxide on the surface of the matrix metal thereof, for example, a stainless steel pipe is immersed in the liquid containing, for example, an oxidizing agent in an electrolytic tank. The oxidizing agent is one having redox level at a more noble position, for example, a solution containing Mn
      2+ , Cr
      3+ , Ag
      + , Cl
      - , I
      - and Br
      - , when electrolytic oxidation is carried out in this state, the redox level of the liquid is moved to a direction more noble than the Fermi level of the oxide and the potential in the oxide is moved to the solution side to dissolve the oxide.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:为了将氧化物氧化并再生液体,通过与金属表面的氧化物接触的液体在阳极上进行电解氧化并使液体的氧化还原电位从高温方向向 费米等级。 构成:将其基体金属表面上具有氧化物的被洗涤物体,例如不锈钢管浸入包含例如电解槽中的氧化剂的液体中。 氧化剂是在更高贵位置具有氧化还原电位的氧化剂,例如含有Mn 2+,Cr 3+,Ag +,Cl - ,I - 和Br - >,当在该状态下进行电解氧化时,液体的氧化还原电位移动到比氧化物的费米能级更高的方向,并且将氧化物中的电位移动到溶液侧以溶解氧化物。
    • 10. 发明专利
    • Electrolytic cell
    • 电解槽
    • JPS58221289A
    • 1983-12-22
    • JP10215282
    • 1982-06-16
    • Hitachi Eng Co LtdHitachi Ltd
    • SUMIDA NOBUOKATAOKA ICHIROUITOU HISAOSAITOU TAKASHIFURUYA YASUMASA
    • C25F7/00C25B3/00C25B9/00C25F7/02
    • PURPOSE: To prevent the decrease in electrolytic efficiency by providing an intermediate liquid chamber between an anode chamber and a cathode chamber, and removing the oxidative material generated in the anode chamber during electrolysis in the intermediate liquid chamber.
      CONSTITUTION: An intermediate liquid chamber 5 is provided between an anode chamber 2 and a cathode chamber 8 in an electrolytic cell used in the stage of dissolving away the oxide sticking to the surface of a metallic material by using the soln. reduced by electrolysis. A titanium plate plated with platinum is put in the chamber 2 and a porous glassy carbon electrode is put in the chamber 8. 0.1M oxalic acid is put in the chamber 2 and 0.002M ethylenediaminetetraacetic acid in the chamber 8 to control to 6.5pH. 0.1M citric acid is put in the chamber 5. The oxidative or reducing material diffused from the counter electrode chambers into the chamber 5 is removed by deaerating the chamber 5, and the fluctuation of the pH is suppressed by adding a buffer beforehand.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:通过在阳极室和阴极室之间设置中间液体室,并且在中间液体室中电解期间去除在阳极室中产生的氧化物质,以防止电解效率降低。 构成:中间液体室5设置在阳极室2和阴极室8之间,该电解槽用于通过使用溶胶将粘附在金属材料表面上的氧化物溶解掉的阶段。 通过电解减少。 将镀有铂的钛板放入室2中,并将多孔玻璃碳电极放入室8中。将0.1M草酸放入室2中,并将0.002M乙二胺四乙酸放入室8中以控制为6.5pH。 将0.1M柠檬酸放入室5中。通过对室5进行脱气来除去从反电极室扩散到室5中的氧化还原材料,并通过预先添加缓冲液来抑制pH的波动。