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    • 3. 发明专利
    • Preparation method of block copolymer, block copolymer prepared thereby and application thereof
    • 嵌段共聚物的制备方法,其制备的嵌段共聚物及其应用
    • JP2009074093A
    • 2009-04-09
    • JP2008281655
    • 2008-10-31
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • MATSUTANI HIROSHIKAWAI HIROMASATO HARUAKITACHIKI HIDEYASUTAKASAKI TOSHIHIKOKUMAKI TAKASHIMARUYAMA KOJIKATOGI SHIGEKI
    • C09J153/00C08G61/08C09J7/00C09J165/00
    • C08G61/08C09J165/00
    • PROBLEM TO BE SOLVED: To provide a preparation method capable of readily synthesizing a homogeneous block copolymer even by using two metathesis-polymerizable monomers that greatly differ in their structures and/or polarities, and to use the block copolymer obtained thereby as an adhesive etc. for circuit connection in electric or electronic components of semiconductor packages etc.
      SOLUTION: The method for preparing the block copolymer comprises the step of carrying out a metathesis polymerization of a metathesis-polymerizable unsaturated monocyclic compound (A) with a metathesis-polymerizable unsaturated polycyclic compound (B) by the use of a metal-carbene complex catalyst (C), wherein the metathesis polymerization is conducted by first mixing and reacting the whole amount of the unsaturated monocyclic compound (A) with the whole amount of the necessary metal-carbene complex catalyst (C) and subsequently adding the unsaturated polycyclic compound (B) to the resulting mixture to carry out a reaction. The block copolymer obtained by the preparation method and the use of the block copolymer are also provided.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供即使通过使用它们的结构和/或极性大不相同的两种易位化可聚合单体也可以容易地合成均匀的嵌段共聚物的制备方法,并且使用由此获得的嵌段共聚物作为 粘合剂等用于半导体封装等的电气或电子部件中的电路连接。解决方案:制备嵌段共聚物的方法包括以下步骤:将易位聚合的不饱和单环化合物(A)的易位聚合与 易位聚合性不饱和多环化合物(B),其中通过首先将全部量的不饱和单环化合物(A)与全部量的不饱和单环化合物 必要的金属 - 碳烯配合物催化剂(C),然后将不饱和多环化合物(B)加入到所得混合物t中 o进行反应。 还提供了通过制备方法获得的嵌段共聚物和嵌段共聚物的用途。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Ultrafine silica particle having uniform diameter, and method for manufacturing the same
    • 具有均匀直径的超细二氧化硅颗粒及其制造方法
    • JP2003002632A
    • 2003-01-08
    • JP2001178013
    • 2001-06-13
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • MATSUTANI HIROSHIHONDA YUTAKASUSA KENZO
    • C01B33/18C08G85/00
    • PROBLEM TO BE SOLVED: To provide ultrafine silica particles having 1-100 nm average particle diameter distribution of which is simple dispersing type.
      SOLUTION: The ultrafine silica particles are manufactured by the following processes (a), (b), and (c); the process (a): a dendorimer having a reactive functional group, which reacts with isocyanates, at a branch terminal and an alkoxysilane as a reaction reagent having isocyanate group are reacted together to obtain a dendorimer having an alkoxysilyl group at the branch terminal (silyl dendorimer), a process (b): an alkoxysilane at the branch terminal (surface layer) of the dendorimer having the alkoxysilyl group at the branch terminal (silyl dendorimer) is hydrolyzed and dehydrated and condensated to obtain a precursor of the ultrafine silica particles, a process (c): the precursor is added with an alkoxysilane and reacted to laminate a silica layer on the surface layer.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供其具有1-100nm平均粒径分布的超细二氧化硅颗粒,其分散是简单的分散型。 解决方案:超细二氧化硅颗粒通过以下方法(a),(b)和(c)制备; 方法(a):在具有异氰酸酯基的反应试剂的分支末端和作为具有异氰酸酯基团的反应试剂的烷氧基硅烷上具有与异氰酸酯反应的反应性官能团的具有反应性官能团的树枝状醇与反应物反应,得到在分支末端具有烷氧基甲硅烷基的树枝状醇(甲硅烷基 树枝状聚合物),方法(b):将在分支末端具有烷氧基甲硅烷基的树枝状体的分支末端(表面层)上的烷氧基硅烷(甲硅烷基树枝状体)进行水解脱水缩合,得到超细二氧化硅粒子的前体, 方法(c):将前体加入烷氧基硅烷并反应以在表面层上层压二氧化硅层。