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    • 1. 发明专利
    • Resin composition, prepreg using the same, metal-clad laminate, metallic foil with resin, adhesive film and printed wiring board
    • 树脂组合物,使用其的PREPREG,金属层压板,带树脂的金属箔,粘合膜和印刷线路板
    • JP2008013618A
    • 2008-01-24
    • JP2006184329
    • 2006-07-04
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • SUZUKI HIRONORIKUMAKURA YOSHITOSHIFUKAI HIROYUKI
    • C08L101/00B32B15/08C08J5/24C08K5/5435C09J7/00C09J11/06C09J201/00H05K1/03
    • PROBLEM TO BE SOLVED: To provide a material for a substrate with a built-in capacitor, such as a prepreg, a metal-clad laminate, a metallic foil with a resin and an adhesive film, wherein variation in dielectric characteristic due to environmental variation is suppressed by reducing water absorption of a thermosetting resin, and a printed wiring board. SOLUTION: A resin composition comprises the thermosetting resin, a filler or a plurality of fillers and an epoxy-silane coupling agent, provided that at least one of the fillers has a dielectric constant of ≥10, and the epoxy-silane coupling agent is 2-(3,4-epoxycyclohexyl)ethyltrimethylsilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane or 3-glycidoxypropyltriethoxysilane. The prepreg, the metal-clad laminate, the metallic foil with the resin, the adhesive film and the printed wiring board using the same are also provided. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供具有内置电容器的基板材料,例如预浸料,覆金属层压板,具有树脂的金属箔和粘合剂膜,其中介电特性的变化由于 通过减少热固性树脂的吸水性和印刷线路板来抑制环境变化。 解决方案:树脂组合物包含热固性树脂,填料或多种填料和环氧硅烷偶联剂,条件是至少一种填料的介电常数≥10,环氧硅烷偶联剂 3-环氧丙氧基丙基三甲氧基硅烷,3-缩水甘油氧基丙基甲基二乙氧基硅烷,3-缩水甘油氧基丙基三乙氧基硅烷等。 还提供了预浸料,覆金属层压板,具有树脂的金属箔,粘合膜和使用其的印刷布线板。 版权所有(C)2008,JPO&INPIT
    • 2. 发明专利
    • Wiring board and method for manufacturing same
    • 接线板及其制造方法
    • JP2006270020A
    • 2006-10-05
    • JP2005181847
    • 2005-06-22
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • TAKANEZAWA SHINMORITA KOJIWATANABE TAKAKOKUMAKURA YOSHITOSHIASAKAWA YUSUKE
    • H05K3/26
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a wiring board which exhibits a high adhesive strength with a wiring conductor, even if a surface of an insulating layer is almost smooth, and provide the wiring board.
      SOLUTION: The method for manufacturing the wiring board includes a step of forming an insulating layer composed of an insulating resin; a step of treating the insulating layer surface with an aqueous solution of pH 11 or more, a step of treating the insulating layer surface with an aqueous solution in which a compound is solved containing at least one carboxylic acid in structure; a step of desmear treatment; and a wiring forming step of forming a wiring layer on the insulating layer surface by plating.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:即使绝缘层的表面几乎平滑,提供一种与布线导体具有高粘合强度的布线板的制造方法,并且提供布线板。 解决方案:制造布线板的方法包括形成由绝缘树脂构成的绝缘层的步骤; 用pH11以上的水溶液处理绝缘层表面的步骤,用结构上含有至少一种羧酸的化合物溶解的水溶液处理绝缘层表面的步骤; 亵渎治疗的一步; 以及通过电镀在绝缘层表面上形成布线层的布线形成步骤。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Production of flame-retardant
    • 阻燃剂的生产
    • JPS6185453A
    • 1986-05-01
    • JP20653884
    • 1984-10-02
    • Hitachi Chem Co Ltd
    • NANAUMI KENYOSHIMURA YUKIOKUMAKURA YOSHITOSHI
    • C09K21/12C07F9/14C08K5/00C08K5/52C08L7/00C08L21/00C08L23/00C08L51/00C08L51/02C08L67/00C08L101/00
    • PURPOSE: To prepare a novel flame-retardant having improved heat resistance, containing phosphorus and bromine in a molecule, by reacting a phosphoric ester with a halogen-containing aromatic alcohol.
      CONSTITUTION: (A) A phosphoric ester shown by the formula I (R
      1 WR
      3 are alkyl, or aryl such as triphenyl phosphate containing preferably an aromatic group and (B) a halogen-containing aromatic alcohol, preferably 2,4,6- tribromophenyl-β-hydroxyethyl ether shown by the formula II or formula III (R and R' are H, or alkyl; X and X' are bromine or chlorine; m+n=5; Y is group shown by the formula IV or formula V; q and n are 1W10) in a ratio of the component A/B of 1/0.1W1/2 are subjected to ester exchange reaction in the presence of 0.1W5wt% basic catalyst (base on total amounts of the components A and B) in the absence of a solvent under heating at 130W170°C, to give the aimed flame-retardant.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过使磷酸酯与含卤素的芳族醇反应,制备分子中含有磷和溴的耐热性提高的新型阻燃剂。 (A)由式I表示的磷酸酯(R1-R3是烷基或芳基,例如优选芳基的三苯基磷酸酯和(B)含卤素的芳族醇,优选2,4,6-三溴苯基 (R和R'为H或烷基; X和X'为溴或氯; m + n = 5; Y为式IV或式V所示的基团) ; q和n为1-10),组分A / B为1 / 0.1-1 / 2的比例在0.1-5wt%碱性催化剂存在下进行酯交换反应(基于组分总量 A和B)在130-170℃加热下不溶于溶剂,得到目标阻燃剂。
    • 4. 发明专利
    • Printed circuit board and method of manufacturing the same
    • 印刷电路板及其制造方法
    • JP2011142364A
    • 2011-07-21
    • JP2011095980
    • 2011-04-22
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • SUZUKI HIRONORIKUMAKURA YOSHITOSHI
    • H05K3/46
    • PROBLEM TO BE SOLVED: To provide a printed circuit board with built-in components that facilitates manufacture, is less likely to leave solvent and air bubbles in an insulating layer, and has superior strength, and to provide a method of efficiently manufacturing the printed circuit board with built-in components.
      SOLUTION: In the printed circuit board in which components are incorporated, the insulating layer constituting the printed circuit board is partly or entirely formed of an insulating material including fiber which is not spun or woven and a resin composition. The printed circuit board and a method of manufacturing it are provided.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供具有便于制造的内置部件的印刷电路板,不太可能在绝缘层中留下溶剂和气泡,并且具有优异的强度,并且提供有效制造的方法 印刷电路板内置组件。 解决方案:在其中组装部件的印刷电路板中,构成印刷电路板的绝缘层部分或全部由绝缘材料形成,该绝缘材料包括不纺丝或机织的纤维和树脂组合物。 提供印刷电路板及其制造方法。 版权所有(C)2011,JPO&INPIT
    • 8. 发明专利
    • Fabrication method for build-up multilayer circuit board
    • 制造多层电路板的制造方法
    • JP2003332750A
    • 2003-11-21
    • JP2002131835
    • 2002-05-07
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • FUJITA HIROAKIFUKAI HIROYUKIKUMAKURA YOSHITOSHI
    • H05K3/46
    • PROBLEM TO BE SOLVED: To provide a fabrication method for a build-up multilayer circuit board excellent in its adhesion to inner circuitry by using a resin composition as an adhesion imparting layer, the resin composition that contains polyvinyl acetal which has low elasticity and high adhesion to metallic copper, without giving an oxidative blackening treatment and subsequent reduced copper treatment.
      SOLUTION: The fabrication method for the multilayer circuit board is one for the circuit board that does not give an oxidative blackening treatment or reduced copper treatment to the first inner circuitry, but has an adhesion imparting layer that uses as an essential ingredient carboxylic acid denatured polyvinyl acetal resin, thermosetting resin, and a crosslinking agent of polyvinyl acetal in order to obtain high adhesion.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供一种通过使用树脂组合物作为粘合赋予层而具有优异的与内部电路的粘附性的积层多层电路板的制造方法,该树脂组合物含有具有低弹性的聚乙烯醇缩醛 和对金属铜的高附着力,而不会发生氧化黑化处理和随后的铜处理。 解决方案:多层电路板的制造方法是对于不对第一内部电路进行氧化黑化处理或减少铜处理的电路板的制造方法,但具有作为必需成分的羧酸的粘合赋予层 酸改性聚乙烯醇缩醛树脂,热固性树脂和聚乙烯醇缩醛交联剂,以获得高粘合性。 版权所有(C)2004,JPO
    • 9. 发明专利
    • Production of flame retardant
    • 生产阻燃剂
    • JPS6191231A
    • 1986-05-09
    • JP21317284
    • 1984-10-11
    • Hitachi Chem Co Ltd
    • NANAUMI KENYOSHIMURA YUKIOKUMAKURA YOSHITOSHI
    • C09K21/12C07F9/14C08K5/00C08K5/52C08L7/00C08L21/00C08L51/00C08L51/02
    • PURPOSE: To obtain a heat-resistant flame retardant excellent in an effect of imparting flame retardancy to, e.g., an oxygen-containing resin, by reacting a phosphate with a halogenated aromatic glycol and a halogenated aromatic alcohol.
      CONSTITUTION: A phosphate such as tricresyl phosphate or triphenyl phosphate is reacted with a halogenated aromatic glycol having two alcoholic hydroxyl groups in the molecule [e.g., 2,2-bis(3,5-dibromo-4-β-hydroxyethoxyphenyl) propane] and a halogenated aromatic alcohol having one alcoholic hydroxyl group in the molecule (e.g., 2,4,6-tribromophenyl-β-hydroxyethyl ether or monochlorobenzyl alcohol). In this way, the purpose flame retardant containing phosphorus and halogen in the molecule is obtained.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过使磷酸酯与卤代芳香族二醇和卤代芳香醇反应,得到对例如含氧树脂赋予阻燃性的效果优异的耐热阻燃剂。 构成:磷酸酯如磷酸三甲苯酯或磷酸三苯酯与分子中具有两个醇羟基的卤代芳族二醇反应(例如,2,2-双(3,5-二溴-4-β-羟基乙氧基苯基)丙烷]和 在分子中具有一个醇羟基的卤代芳族醇(例如2,4,6-三溴苯基-β-羟乙基醚或一氯苄醇)。 以这种方式获得分子中含有磷和卤素的目的阻燃剂。
    • 10. 发明专利
    • Method for producing insulating resin adhesive sheet and method for producing printed wiring board using insulating resin adhesive sheet
    • 生产绝缘树脂粘合片的方法和使用绝缘树脂粘合片生产印刷线路板的方法
    • JP2007126498A
    • 2007-05-24
    • JP2005318253
    • 2005-11-01
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • FUJITA HIROAKIKUMAKURA YOSHITOSHIFUKAI HIROYUKITAKANEZAWA SHINMORITA KOJI
    • C09J7/02C09J11/04C09J11/06C09J121/00C09J163/00H01L23/32H05K1/03
    • PROBLEM TO BE SOLVED: To obtain a substrate for an organic interposer, which is produced by mixing a resin composition containing an inorganic filler with a very small amount of a silica fiber having a low coefficient of thermal expansion and excellent dimensional stability, chemical resistance, wettability, etc., is expected to have improved connection reliability while satisfying various properties as an insulating substrate compatible with a semi-additive method.
      SOLUTION: The method for producing an insulating resin adhesive sheet comprises coating a carrier film with an insulating resin composition composed of an epoxy resin, a rubber component, a phosphorus-based flame retardant, a thermosetting agent, an inorganic filler and a silica fiber as essential components and drying the film to a semicured state. The method for producing a printed wiring board comprises treating an insulating layer with an oxidizing roughening liquid and forming a circuit by an electroless plating or electrolytic plating as a method for piling a fixed number of the insulating resin adhesive sheets produced by the production method and curing the resin under heating and pressure to form a circuit on the insulating resin layer.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题为了获得通过将含有无机填料的树脂组合物与极少的热膨胀系数和极小尺寸稳定性的二氧化硅纤维混合而制备的有机中介层的基板, 耐化学性,润湿性等有望提高连接可靠性,同时满足作为与半添加法相容的绝缘基板的各种性能。 解决方案:绝缘树脂粘合片的制造方法包括用由环氧树脂,橡胶成分,磷系阻燃剂,热固性剂,无机填料和无机填料构成的绝缘树脂组合物涂布载体膜 二氧化硅纤维作为必需组分,并将薄膜干燥至半熟化状态。 制造印刷电路板的方法包括用氧化性粗糙液处理绝缘层,通过无电解电镀或电解电镀形成电路,作为用于堆叠固定数量的通过制造方法制造的绝缘树脂粘合片和固化的方法 树脂在加热和加压下在绝缘树脂层上形成电路。 版权所有(C)2007,JPO&INPIT