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    • 1. 发明专利
    • Co oxidation method
    • CO氧化方法
    • JP2008006353A
    • 2008-01-17
    • JP2006177484
    • 2006-06-28
    • Hitachi Ltd株式会社日立製作所
    • SUGANO SHUICHIHIGASHIYAMA KAZUHISA
    • B01D53/94B01J23/75B01J29/035B01J29/46B01J35/02
    • PROBLEM TO BE SOLVED: To provide a CO oxidation method which has the performance equivalent to a conventional catalyst without using a noble metal or with a small amount of the noble metal. SOLUTION: The CO oxidation method, which oxidizes CO in an exhaust gas to produce CO2, is characterized in that CO and a CO oxidant are made to contact at 150-200°C on a carrier and a catalyst where a catalyst active component is dispersed as a cluster of size of an average of 2 nm or below on the carrier. Co, Fe, Sr and Ni can be used as the active component, and a zeolite, TiO 2 and SiO 2 are given as the carrier wherein any of a mesoporous body and a micro pore can be used. COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:提供一种CO氧化方法,其具有与常规催化剂性能相当的性能,而不使用贵金属或少量贵金属。 解决方案:CO氧化废气中的CO以产生CO 2的CO氧化方法的特征在于使CO和CO氧化剂在150-200℃下在载体和催化剂活性的催化剂上接触 组分作为平均2nm或更小的尺寸的簇分散在载体上。 可以使用Co,Fe,Sr和Ni作为活性组分,并且提供沸石TiO 2 SB 2和SiO 2 SB 2作为载体,其中介孔体和 可以使用微孔。 版权所有(C)2008,JPO&INPIT
    • 3. 发明专利
    • Exhaust emission control device for internal combustion engine, its method, and hydrogen sulfide trapping catalyst
    • 用于内燃机的排气控制装置及其方法和氢硫化物捕集催化剂
    • JP2005120958A
    • 2005-05-12
    • JP2003358644
    • 2003-10-20
    • Hitachi Ltd株式会社日立製作所
    • KANAE MASAHITOIIZUKA HIDEHIROHIGASHIYAMA KAZUHISAKITAHARA YUICHI
    • F02D45/00B01D53/86B01D53/94F01N3/08F01N3/10F01N3/20F01N3/24
    • Y02T10/24
    • PROBLEM TO BE SOLVED: To suppress the exhaustion of hydrogen sulfide from an internal combustion engine to be operated in a lean-burn condition. SOLUTION: This exhaust emission control device for the internal combustion engine comprises a NOx purifying catalyst provided in an exhaust gas duct of the internal combustion engine into which exhaust gas of lean air-fuel ratio and exhaust gas of rich air-fuel ratio or stoichimetric form flows for trapping NOx and SOx in exhaust gas in a lean condition, a hydrogen sulfide trapping catalyst provided at the rear stage thereof for trapping hydrogen sulfide, and a heating means for heating the hydrogen sulfide trapping catalyst. The air-fuel ratio is set lean when the amount of S trapped by the hydrogen sulfide trapping catalyst reaches a preset amount. The heating means is used for increasing the temperature of the hydrogen sulfide trapping catalyst to a preset temperature or higher to permit the release of all or part of S-component trapped by the hydrogen sulfide trapping catalyst as SOx. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了抑制在稀燃状态下运行的内燃机的硫化氢的耗尽。 解决方案:该内燃机废气排放控制装置包括:NOx净化催化剂,其设置在内燃机的排气管道中,稀燃空燃比废气和浓空燃比排气 或用于在稀薄条件下捕集废气中的NOx和SO x的硫酸氢盐捕集催化剂,用于捕获硫化氢的后段的硫化氢捕集催化剂和用于加热硫化氢捕集催化剂的加热装置。 当由硫化氢捕集催化剂捕获的S的量达到预设量时,空燃比设定为稀。 加热装置用于将硫化氢捕集催化剂的温度提高到预设温度或更高,以允许由硫化氢捕集催化剂捕集的S组分的全部或部分的SO x释放。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Method and apparatus for catalytic pfc decomposition processing
    • 用于催化PFC分解处理的方法和装置
    • JP2005111423A
    • 2005-04-28
    • JP2003351470
    • 2003-10-10
    • Hitachi Ltd株式会社日立製作所
    • SUGANO SHUICHITAMADA SHINRI KOKUNHIGASHIYAMA KAZUHISA
    • B01D53/70B01D53/34B01D53/86
    • Y02C20/30
    • PROBLEM TO BE SOLVED: To provide a method and an apparatus for inexpensively and efficiently removing, from a gas containing PFC (perfluorocompounds), a (gas) component which reacts with water and produces a solid substance and maintaining a high PFC decomposition rate. SOLUTION: The method for catalytically decomposing the PFC in a gas flow containing the gas component which reacts with water and produces the solid substance and further containing the PFC is provided at least with: a solid substance producing process that allows the gas flow to come into contact with water and produces the solid substance; a solid substance capturing process that eliminates the produced solid substance; and a PFC catalytic decomposition process. Thereby, clogging in the catalytic PFC decomposition apparatus hardly occurs and high PFC decomposition performance can be maintained. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种从含有PFC(全氟化合物)的气体中廉价有效地除去与水反应并产生固体物质并保持高PFC分解的(气体)成分的方法和装置 率。 解决方案:在含有与水反应并产生固体物质并进一步含有PFC的气体组分的气流中催化分解PFC的方法至少提供:允许气体流动的固体物质生产方法 与水接触并产生固体物质; 消除生成的固体物质的固体物质捕获过程; 和PFC催化分解过程。 因此,催化PFC分解装置中的堵塞几乎不发生,并且可以保持高PFC分解性能。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • Halogen corrosion resistant member, and perfluoro compound decomposition treatment apparatus
    • 耐腐蚀成员和全氟化合物分解处理装置
    • JP2004269946A
    • 2004-09-30
    • JP2003060777
    • 2003-03-07
    • Hitachi Ltd株式会社日立製作所
    • SUGANO SHUICHITAMADA SHINHIGASHIYAMA KAZUHISA
    • B01D53/86B01J19/02C22C19/05C22C38/00C22C38/40
    • Y02C20/30
    • PROBLEM TO BE SOLVED: To improve the corrosion resistance to Cl 2 -containing corrosive gas or Cl 2 and PFC (perfluoro compound)-containing gas in a member heated at 200 to 1,000°C. SOLUTION: In a member to be exposed to high temperature Cl 2 or Cl 2 -containing PFC gas, the member to be exposed to the corrosive gas heated at 500 to 1,000°C is made of an Ni based alloy containing, by weight, 10 to 30% Cr, 1 to 10% Fe and ≤0.1% C or an Fe based alloy containing 10 to 20% Cr, 0.05 to 0.20% Ni, 4 to 5% Al and ≤0.01% C. The member to be exposed to the corrosive gas heated at 200 to 500°C is made of Ni. The surface of the member consisting of the Ni based alloy is preferably provided with a film of chromium oxide. Further, the boundary between the Ni based alloy and the chromium oxide film is desirably provided with a film of aluminum oxide. COPYRIGHT: (C)2004,JPO&NCIPI
    • 要解决的问题:为了提高在加热的构件中含Cl / SB> 2 的含腐蚀性气体或Cl 2 和PFC(全氟化合物)的气体的耐腐蚀性 在200至1000℃。

      解决方案:在暴露于高温Cl 2 或含Cl 2 的PFC气体的构件中,暴露于加热至500℃的腐蚀性气体的构件 至1000℃由Ni基合金制成,其含有10〜30%的Cr,1〜10%的Fe和≤0.1%的C,或含有10〜20%的Cr,0.05〜0.20%的Ni, 4〜5%Al,≤0.01%C。加热至200〜500℃的腐蚀性气体的部件由Ni构成。 由Ni基合金构成的部件的表面优选设置有氧化铬膜。 此外,Ni基合金和氧化铬膜之间的边界优选设置有氧化铝膜。 版权所有(C)2004,JPO&NCIPI