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1. 发明专利

JPH11109650A PRODUCTION OF MULTILAYER PRINTED CIRCUIT BOARD 失效
公开(公告)号：JPH11109650A
公开(公告)日：1999-04-23
申请号：JP26597597
申请日：1997-09-30
申请人： HITACHI CHEMICAL CO LTD
发明人： HATAKEYAMA SHUICHI , TAKANEZAWA SHIN , TAKEUCHI KAZUMASA , MORITA MASAKI , YAMADERA TAKASHI , IRINO TETSURO
IPC分类号： G03F7/32 , H05K3/46
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a multilayer printed circuit board of a build-up system which forms via holes of high quality having no gouge or separation and is excellent in interlayer connection reliability. SOLUTION: In this manufacturing method of the multilayer printed circuit board, a photosensitive insulating resin layer is provided on an inner conductor formed in an insulating substrate and is exposed and developed via a phototool to form the via holes. Thereafter, the photosensitive insulating resin layer surface is subjected to circuit machining including plating to form a conductor wiring. At the time of developing, an aq. alkaline developer containing an organic solvent is used as a developer and an aq. soln. containing the organic solvent is used as a rinsing soln. after developing to manufacture the multilayer printed circuit board. As the developer, an aq. soln. containing diethylene glycol monobutyl ether and sodium borate is preferably used. Further as the rinsing soln., an aq. soln. containing diethylene glycol monobutyl ether is preferably used.

2. 发明专利

JPH1098266A PHOTOSENSITIVE INSULATION MATERIAL AND MANUFACTURE OF WIRING BOARD USING THE SAME 失效
公开(公告)号：JPH1098266A
公开(公告)日：1998-04-14
申请号：JP24983396
申请日：1996-09-20
申请人： HITACHI CHEMICAL CO LTD
发明人： TAKEUCHI KAZUMASA , TOMIOKA KENICHI , MORITA MASAKI , YAMADERA TAKASHI
IPC分类号： G03F7/004 , G03F7/022 , G03F7/027 , H05K3/46
摘要： PROBLEM TO BE SOLVED: To reduce poor insulation due to deposition of foreign substances on a mask and repairs therefor by laminating a positive-type photosensitive resin layer, ultraviolet absorbent-contg. resin layer and negative-type hardening resin layer. SOLUTION: A negative-type hardening resin layer, an ultraviolet absorbent- contg. resin layer and positive-type photosensitive resin layer on a circuit board having a first wiring layer are laminated. After exposure to an active ray through a mask, shielding parts other than the inter-layer connection holes, inter-layer connection holes for a first circuit are opened by a developer. After developing the positive-type photosensitive resin layer of the holes, this resin layer is used as an etching mask, the ultraviolet absorbent-contg. resin layer and negative-type hardening resin layer are developed. The entire positive-type photosensitive resin layer is again exposed to an active ray and developed to remove this layer and the ultraviolet absorbent-contg. resin layer. The negative-type hardening resin layer remaining on the first circuit board is hardened by light or heat and is plated with Cu.

3. 发明专利

JPH04198183A TETRAPHENYLPORPHYRIN DERIVATIVE, ITS PRODUCTION AND PRODUCTION OF LB FILM 失效
公开(公告)号：JPH04198183A
公开(公告)日：1992-07-17
申请号：JP32590890
申请日：1990-11-29
申请人： HITACHI CHEMICAL CO LTD
发明人： YAMADERA TAKASHI , TAGUSARI TOSHINORI , HONDA YUTAKA , TAKEUCHI KAZUMASA , OBATA RITSUKO
IPC分类号： C07D487/22 , B01J31/22 , B05D1/20 , C07F3/06 , C09B47/00 , C09K3/00
摘要： NEW MATERIAL:A compound expressed by formula I (M is metal, metallic halide, metallic oxide, metallic hydroxide or two Hs; R to R are alkoxy). EXAMPLE:Tetrakis(3-carboxy-4-octadecyloxyphenyl)porphyrin. USE:An LB film-forming agent. PREPARATION:A benzaldehyde derivative expressed by formula II (R is alkoxy) is reacted with pyrrole to afford the objective compound expressed by formula I (group M is two Hs).

4. 发明专利

JPH03171778A OPTOELECTRONIC ELEMENT 失效
公开(公告)号：JPH03171778A
公开(公告)日：1991-07-25
申请号：JP31131689
申请日：1989-11-30
申请人： HITACHI CHEMICAL CO LTD
发明人： TAKEUCHI KAZUMASA , YAMADERA TAKASHI , HONDA YUTAKA , TAGUSARI TOSHINORI , OBATA RITSUKO
IPC分类号： H01L31/10
摘要： PURPOSE:To acquire an optoelectronic element which generates a pulse current corresponding to change of light strength by a three-component layer containing an electron donating substance, a phthalocyanine coloring matter and an electron accepting substance which are laminated on a first electrode, and a second electrode through electrolyte. CONSTITUTION:A film 2 of a first electrode is formed on a first substrate 1 and a three-component layer 3 is formed thereon. The three-component layer 3 is in contact with a solid state film (electrolytic layer) 4 and a second electrode 5 is formed on a surface thereof. A salt bridge 7 to connect a third electrode (reference electrode) is connected to the solid state film (electrolytic layer) 5. The three-component layer is formed by laminating an electron donating substance, a phthalocyanine coloring matter and an electron accepting substance. When light of a wavelength which allows phthalocyanine coloring matter to show absorption is irradiated to the optoelectronic element, a pulse-like current flows corresponding to change of light strength. At this time, a direction of a pulse current can detect change of light strength of irradiated light by measuring a current value thereof. Use of the element as a light switch can be realized by using the current properties.

5. 发明专利

JPH0113089B2 失效
公开(公告)号：JPH0113089B2
公开(公告)日：1989-03-03
申请号：JP7115181
申请日：1981-05-11
申请人： HITACHI CHEMICAL CO LTD
发明人： YAMADERA TAKASHI , HAYASHI NOBUYUKI
IPC分类号： C08F2/00 , C08F2/44 , C08F2/48 , C08F291/00 , C23F1/00 , G03F7/004 , G03F7/085

6. 发明专利

JPS62165652A OPTICAL RECORDING METHOD 失效
公开(公告)号：JPS62165652A
公开(公告)日：1987-07-22
申请号：JP833586
申请日：1986-01-18
申请人： HITACHI CHEMICAL CO LTD
发明人： YAMADERA TAKASHI , TAGUSARI TOSHINORI , HAYASHI NOBUYUKI
IPC分类号： G11B7/00 , G03C1/73 , G03C5/08 , G03C5/56 , G11B7/004 , G11B7/241 , G11B7/244
摘要： PURPOSE:To enable recording and reproducing of information without inducing the breakdown of reading out by using a material which can attain a mixed valency state for at least either of an electron donative material and electron acceptive material. CONSTITUTION:A photosensitizer S is converted by writing light to a photosensitizer S* of an excitation type. The photosensitizer is made to an oxidation type S . and reduction type A . respectively by transferring electrons to the electron acceptive material A. S . is still active and reacts with the electron donative material D in succession thereof to apply the oxidation type D*. thereof. The photosensitizer itself is returned to S. The photosensitizer is thus regenerated. The physical and optical change generated in at least either of D . and A . is optically read by the wavelength different from the wave length used in th stage of the previous writing, by which the nondestructive reading out is attained. The writing and reading out of the information are thereby executed all non-destructively and since the materials of a wide wave length range are usable, the wide design meeting the light source and detector of the system is made possible.

7. 发明专利

JPS62165648A OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPS62165648A
公开(公告)日：1987-07-22
申请号：JP833786
申请日：1986-01-18
申请人： HITACHI CHEMICAL CO LTD
发明人： TAGUSARI TOSHINORI , YAMADERA TAKASHI
IPC分类号： B41M5/28 , B41M5/26 , B41M5/30 , G03C1/675 , G11B7/244 , G11B7/249
摘要： PURPOSE:To improve the sensitivity by using a specified org. metallic complex as an infrared absorbing dye. CONSTITUTION:One or more kinds of org. metallic complexes represented by the formulae I-VI are used as an infrared absorbing dye. In the formulae, each of X and X' is H, alkyl or the like, each of Y, Y', Y'' and Y''' is H, alkyl, phenylor cyano, each of Z and Z' is H, alkyl or halogen, each of E and E' is H, alkyl phenyl or the like, each of G and G' is H, alkyl or halogen, and M is Ni, Co, Pd or Pt. The org. metallic complexes are kneaded with a dispersion medium such as transparent plastics and used in the form of a film or a sheet. The complexes may be dissolved in a solvent and applied to a substrate.

8. 发明专利

JP2001119140A METHOD OF MANUFACTURING WIRING BOARD 失效
公开(公告)号：JP2001119140A
公开(公告)日：2001-04-27
申请号：JP29899299
申请日：1999-10-21
申请人： HITACHI CHEMICAL CO LTD
发明人： TAKANEZAWA SHIN , HATAKEYAMA SHUICHI , MORITA MASAKI , YAMADERA TAKASHI
IPC分类号： H05K3/00 , H05K3/46
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a wiring board by which a tapered via hole is obtained easily, without changing a composition for improving light transmittance of an insulating resin. SOLUTION: In this method of manufacturing the wiring board, a part except where a hole is provided of an insulating layer using a photocuring resin is exposed, and then a part not exposed is developed and removed to form a hole, and treatment is performed using liquid solution with which the developing solution has been diluted, after development.

9. 发明专利

JPH11100409A HEAT OR LIGHT-CURABLE RESIN COMPOSITION, AND FILM AND LAMINATE USING THE SAME 失效
公开(公告)号：JPH11100409A
公开(公告)日：1999-04-13
申请号：JP21549198
申请日：1998-07-30
申请人： HITACHI CHEMICAL CO LTD
发明人： MORITA MASAKI , TAKANEZAWA SHIN , TAKEUCHI KAZUMASA , YAMADERA TAKASHI , HATAKEYAMA SHUICHI
IPC分类号： H05K3/28 , B32B27/00 , C08F2/50 , C08F22/40 , C08F290/00 , C08L101/00 , G03F7/027 , G03F7/031 , G03F7/032 , H05K1/03 , H05K3/46
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition maintaining the high heat resistance of a bismaleimide compound, improving the curability of the bismaleimide compound and imparted with photocurability without deteriorating the thermal curability by including the bismaleimide compound and a specific acridine compound. SOLUTION: This composition comprises 100 pts.wt. of a mixture of (A) a bismeleimide compound e.g. 2,2-bis[4-(4-N-maleimidylphenyl)phenyl] propane}, if necessary, with (B) one or more other resin components (e.g. the unsaturated acid-modified product of an epoxy resin), and (C) 0.1-30 pts.wt. of an acridine compound comprising a compound of formula I (R2 -R9 are each H, a halogen, a 1-8C alkyl, an alkoxy; R1 is a 1-8C alkyl) (e.g. 9-methylacridine) or formula II (R10 is a 1-12C alkylene) (e.g. 1,7-di-9-acridinylheptane) as a thermal curing accelerator or a photoinitiator.

10. 发明专利

JPH0915861A PHOTOSENSITIVE RESIN COMPOSITE 失效
公开(公告)号：JPH0915861A
公开(公告)日：1997-01-17
申请号：JP16546895
申请日：1995-06-30
申请人： HITACHI CHEMICAL CO LTD
发明人： OBATA RITSUKO , TAKEUCHI KAZUO , SUZUKI KAZUKO , YAMADERA TAKASHI
IPC分类号： G03F7/004 , C08G59/40 , G03F7/027 , G03F7/038 , H05K1/00
摘要： PURPOSE: To provide a photosensitive composite with high heat resistance, high temperature elasticity and excellent flexibility which has photosensitivity and can be used for manufacture of a multilayer printed wiring board or MCM-L. CONSTITUTION: In a resin composite consisting of two kinds or more of resins (for example, epoxy resin and bismaleimide resin, epoxy resin and cyanate ester resin) in which a layer separated state is formed, a resin A and a resin B are not mutually reacted, and form a separate cross-linked net such as optical crosslinking or thermal crosslinking.

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