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    • 2. 发明专利
    • Curable resin composition for optical component, optical component and image display apparatus
    • 光学元件,光学元件和图像显示设备的可固化树脂组合物
    • JP2005258119A
    • 2005-09-22
    • JP2004070202
    • 2004-03-12
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • OBAYASHI TATSUHIKO
    • G02B1/11C08F30/08C08F290/14C08G77/18G02B1/04
    • PROBLEM TO BE SOLVED: To provide a curable resin composition for an optical component capable of forming a fine rugged structure with high scratch resistance and excellent shape holding property, to provide an optical component having excellent optical characteristic, high scratch resistance and excellent shape holding property by using the above curable resin composition for an optical component, and to provide an image display apparatus using the component. SOLUTION: The curable resin composition for an optical component comprises a silicon compound having a polymerizable group on a leaving group subjected to hydrolysis. Preferably the silicon compound contains a structural unit expressed by at least either general formula (1) or general formula (2). The above resin composition for an optical component is to be used to mold a fine rugged structure of an optical component. In formula (1), R represents a radical polymerizable group or a cationic polymerizable group. In formula (2), R represents a radical polymerizable group or a cationic polymerizable group. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题的方案为了提供能够形成具有高耐擦伤性和优异的形状保持性的微细凹凸结构的光学部件用固化性树脂组合物,提供具有优异的光学特性,高耐擦伤性和优异的光学部件 通过使用上述光学部件用固化性树脂组合物的形状保持性,并提供使用该部件的图像显示装置。 解决方案:用于光学部件的可固化树脂组合物包括在离去基团上具有可聚合基团的硅化合物进行水解。 硅化合物优选含有由至少通式(1)或通式(2)表示的结构单元。 上述用于光学部件的树脂组合物用于模制光学部件的精细坚固结构。 式(1)中,R表示自由基聚合性基团或阳离子聚合性基团。 在式(2)中,R表示可自由基聚合的基团或阳离子可聚合基团。 版权所有(C)2005,JPO&NCIPI
    • 3. 发明专利
    • Fluorine-containing polymer, process for producing the same and curable resin composition comprising the same
    • 含氟聚合物,其制造方法和包含该聚合物的可固化树脂组合物
    • JP2005139363A
    • 2005-06-02
    • JP2003379053
    • 2003-11-07
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • OBAYASHI TATSUHIKOHOSOKAWA TAKASHIKITAMURA MASAHARUGOTOU HARUYOSHI
    • G03F7/004C08F8/14C08L27/12G02B1/10
    • PROBLEM TO BE SOLVED: To provide a process for producing a fluorine-containing polymer having an ethylenically unsaturated group that uses an inexpensive raw material having good availability, reduces the burden on equipment and enables stably introducing an ethylenically unsaturated group into a fluorine-containing polymer containing a hydroxy group at a sufficiently high degree of conversion, to provide the fluorine-containing polymer and to provide a curable resin composition comprising the fluorine-containing polymer. SOLUTION: The process for producing a reactive fluorine-containing polymer comprises permitting a compound having an ethylenically unsaturated group and a carboxylic group to act on a fluorine-containing polymer containing a hydroxy group to conduct an esterification reaction in the presence of an acid catalyst. In addition, the process for producing a fluorine-containing polymer includes a step of separating a solution of the fluorine-containing polymer into at least one organic layer having the fluorine-containing polymer dissolved therein and at least one organic layer other than the aforementioned organic layer to separately take out the fluorine-containing polymer. The fluorine-containing polymer produced by either of these production processes is provided. The curable resin composition comprising the fluorine-containing polymer is provided. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题的方案为了提供使用廉价的具有良好可利用性的原料的具有烯键式不饱和基团的含氟聚合物的制造方法,减少了对设备的负担,能够稳定地将烯属不饱和基团引入氟 含有羟基的聚合物以足够高的转化率提供,以提供含氟聚合物,并提供包含含氟聚合物的固化性树脂组合物。 解决方案:制备反应性含氟聚合物的方法包括使具有烯键式不饱和基团和羧基的化合物作用于含有羟基的含氟聚合物上进行酯化反应,在 酸催化剂。 此外,含氟聚合物的制造方法包括将含氟聚合物的溶液分离成溶解有含氟聚合物的至少一种有机层和除上述有机物以外的至少一种有机层的工序 层以分别取出含氟聚合物。 提供通过这些制造方法中的任一种制造的含氟聚合物。 提供包含含氟聚合物的可固化树脂组合物。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Fluorine-containing resin composition and optical article and image display device using the same
    • 含氟树脂组合物和使用其的光学制品和图像显示装置
    • JP2005097371A
    • 2005-04-14
    • JP2003330636
    • 2003-09-22
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • OBAYASHI TATSUHIKO
    • G02B5/18C08K5/00C08L101/00G02B1/04G02B1/11G02B5/30G02F1/1335H01L51/50H05B33/02H05B33/14
    • PROBLEM TO BE SOLVED: To provide a fluorine-containing resin composition efficiently forming a periodic uneven microstructure having excellent optical characteristics and stain resistance and an optical article suitably used in various optical applications such as an antireflection coating, an antireflection film, an optical waveguide, a relief hologram, a lens, an optical card, an optical disk and a polarizing separation element and to provide an image display device using the optical article. SOLUTION: The fluorine-containing resin composition comprises at least a fluorine-containing compound and is used for forming the uneven microstructure of the optical article. The fluorine-containing compound is preferably a mode which is at least any selected from a fluorine-containing monomer, a fluorine-containing silane coupling agent, a fluorine-containing surfactant and a fluorine-containing polymer. The optical article has the uneven microstructure formed by using the fluorine-containing resin composition and comprises fluorine atoms on the surface. The image display device comprises the optical article arranged therein. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题:为了提供有效地形成具有优异的光学特性和耐污染性的周期性不均匀微观结构的含氟树脂组合物和适用于各种光学应用的光学制品,例如抗反射涂层,抗反射膜, 光波导,浮雕全息图,透镜,光卡,光盘和偏振分离元件,并提供使用该光学物品的图像显示装置。 解决方案:含氟树脂组合物至少含有含氟化合物,用于形成光学制品的不均匀微观结构。 含氟化合物优选为选自含氟单体,含氟硅烷偶联剂,含氟表面活性剂和含氟聚合物中的至少任一种。 光学制品具有通过使用含氟树脂组合物而形成的不均匀的微观结构,并且在表面上含有氟原子。 图像显示装置包括布置在其中的光学制品。 版权所有(C)2005,JPO&NCIPI
    • 5. 发明专利
    • Curable resin composition and optical article, and image display device using the same
    • 可固化树脂组合物和光学制品,以及使用其的图像显示装置
    • JP2005092099A
    • 2005-04-07
    • JP2003328560
    • 2003-09-19
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • OBAYASHI TATSUHIKO
    • G02B5/18C08G77/04C09D183/04G02B1/04G02B1/11G02B5/30G11B7/24G11B7/257H01L51/50H05B33/02H05B33/14
    • PROBLEM TO BE SOLVED: To provide a curable resin composition which permits formation of periodic fine ruggedness structures and an optical article suitable for various optical applications and an image display device using the same. SOLUTION: The curable resin composition contains polysiloxane which is a hydrolysis condensate prepared by hydrolyzing and condensing a trifunctional silane compound expressed by general formula (1): RSiX 3 and is formed by silane bonding of ≥90% of one silicon atom to other three silicon atoms . The above curable resin composition is used for forming the fine ruggedness structure of the optical article. The optical article has the fine ruggedness structure formed by using the curable resin composition. The image display device is arranged with the optical article. In the general formula (1), R represents a group including a reactive unsaturated group or ring-opening polymerizing group and X represents a hydroxyl group or hydrolyzable group. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种允许形成周期性微细凹凸结构的固化树脂组合物和适用于各种光学应用的光学制品和使用其的图像显示装置。 解决方案:可固化树脂组合物含有聚硅氧烷,其是通过水解和缩合由通式(1)表示的三官能硅烷化合物制备的水解缩合物:RSiX 3 ,并通过硅烷键合≥ 一个硅原子与其他三个硅原子的90%。 上述可固化树脂组合物用于形成光学制品的微细凹凸结构。 该光学制品具有通过使用该固化性树脂组合物形成的细小的凹凸结构。 图像显示装置配置有光学物品。 在通式(1)中,R表示包含反应性不饱和基团或开环聚合基团的基团,X表示羟基或可水解基团。 版权所有(C)2005,JPO&NCIPI
    • 10. 发明专利
    • Antireflection coating, antireflection film, polarizing plate, image display device and hard-coated article
    • 抗反射涂层,抗反射膜,极化板,图像显示装置和硬涂层
    • JP2005043749A
    • 2005-02-17
    • JP2003279009
    • 2003-07-24
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • MATSUFUJI AKIHIROOBAYASHI TATSUHIKO
    • G02B5/30B32B27/30C08F290/12G02B1/10G02B1/11G03F7/027H01L51/50H05B33/02H05B33/14
    • PROBLEM TO BE SOLVED: To provide a coat-type antireflection coating suitable for mass production, an antireflection coating having a low reflectance and excellent in scratch resistances, an antireflection film with the antireflection coating applied on a transparent support, and an image display device and a hard-coated article excellent in scratch resistances of a surface and reducing reflection. SOLUTION: The antireflection coating has a hardened film formed from a curable composition comprising a copolymer (P) comprising a polymerized unit of a fluorine-containing vinyl monomer and a polymerized unit having an ethylenically unsaturated group in a side chain, wherein a backbone consists of only carbon atoms, and a curable resin containing two or more ethylenically unsaturated groups in the same molecule. The antireflection film has the antireflection coating applied on a transparent support. The image display device and the hard-coated article have the antireflection coating arranged. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供适合批量生产的涂层型抗反射涂层,具有低反射率和优异耐擦伤性的抗反射涂层,具有应用于透明载体上的抗反射涂层的抗反射膜和图像 显示装置和表面耐擦伤性优异且减少反射的硬涂层制品。 防反射涂层具有由包含含氟乙烯基单体的聚合单元和侧链中具有烯属不饱和基团的聚合单元的共聚物(P)的固化性组合物形成的硬化膜,其中, 骨架仅由碳原子组成,在同一分子中含有两个以上烯属不饱和基团的固化性树脂。 抗反射膜具有应用在透明支撑体上的抗反射涂层。 图像显示装置和硬涂层制品具有布置的抗反射涂层。 版权所有(C)2005,JPO&NCIPI