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    • 1. 发明专利
    • Method and device for producing hydrogen
    • 用于生产氢的方法和装置
    • JP2005232521A
    • 2005-09-02
    • JP2004042019
    • 2004-02-18
    • Ebara Corp株式会社荏原製作所
    • MATSUMURA SATORUOSHITA TAKAHIRO
    • B09B3/00C01B3/02C10K1/08C25B1/10C25B15/08
    • Y02E60/366
    • PROBLEM TO BE SOLVED: To provide a method where, in a high temperature water vapor electrolyzer in which, using a solid oxide electrolytic membrane, a reducing gas is fed to the anode side, water vapor is fed to the cathode side, and, on the anode side, oxygen ions are brought into reaction with the reducing gas to produce a gradient of the concentration in the oxygen ions, thus electrolytic voltage is reduced, the balance of heat at the inside of an electrolytic cell is examined, and the optimum temperatures of the reducing gas and water vapor to be fed are found. SOLUTION: A method of producing hydrogen characterized in that, regarding a method where, in a high temperature water vapor electrolyzer in which an electrolytic cell is partitioned into the anode side and the cathode side using a solid oxide electrolytic membrane as a diaphragm, water vapor is fed to the cathode side and a reducing gas is fed to the anode side, water vapor electrolysis is performed at a high temperature to produce hydrogen, and each temperature of the reducing gas and water vapor to be fed to the electrolytic cell is controlled to 200 to 500°C. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种方法,其中在使用固体氧化物电解质膜的还原气体被供给到阳极侧的高温水蒸汽电解槽中,将水蒸汽供给到阴极侧, 并且在阳极侧使氧离子与还原气体反应而产生氧离子浓度的梯度,因此电解电压降低,检查电解槽内部的热量平衡, 找到要供给的还原气体和水蒸汽的最佳温度。 解决方案:一种生产氢的方法,其特征在于,关于在使用固体氧化物电解膜作为隔膜的电解槽分隔成阳极侧和阴极侧的高温水蒸汽电解槽中的方法 将水蒸气供给到阴极侧,将还原气体供给到阳极侧,在高温下进行水蒸汽电解,生成氢气,还原气体和水蒸气的每一温度供给至电解槽 控制在200〜500℃。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Device for detecting gas component
    • 用于检测气体成分的装置
    • JP2008256485A
    • 2008-10-23
    • JP2007097956
    • 2007-04-04
    • Ebara CorpNational Institute Of Advanced Industrial & Technology株式会社荏原製作所独立行政法人産業技術総合研究所
    • MATSUMURA SATORUKOBAYAKAWA TATSUTODA HIDEKI
    • G01N29/02
    • G01N2291/02809G01N2291/02818
    • PROBLEM TO BE SOLVED: To surely detect generation of gases, even when gas components are difficult to predict.
      SOLUTION: When frequency signals from an oscillation circuit 1 are respectively applied to a measurement cell 10det, to which a sample gas is introduced and a reference cell 10ref, to which a reference gas is introduced, sound waves corresponding to the signals are generated and receiving signals are converted into electrical signals Fdet and Fref to output them. The sound wave propagation lengths of two cells are identical, and the sound velocities of the sample gas and the reference gas are set equal in the initial state. Changes in the gas component of the sample gas result in a phase difference between the signals Fdet and Fref because of a change in the sound velocity. A sampling-hold circuit 4 detects the phase difference, and by using pulses synchronized with the signal Fref from a pulse oscillation circuit 3 as sampling pulses and then sampling saw-tooth waves that are synchronized with the signal Fdet from a saw-tooth oscillation circuit 5, generation of gas is detected. By making the two cells identical in the temperature environment, influence due to changes in the temperature can be prevented.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:即使气体组分难以预测,也可以确定地检测气体的产生。 解决方案:当来自振荡电路1的频率信号分别施加到被引入样本气体的测量单元10det和引入参考气体的参考单元10ref时,与信号对应的声波是 生成和接收信号被转换成电信号Fdet和Fref以输出它们。 两个电池的声波传播长度相同,样品气体和参考气体的声速在初始状态下相等。 由于声速的变化,样气的气体成分的变化导致信号Fdet和Fref之间的相位差。 采样保持电路4检测相位差,并且使用与来自脉冲振荡电路3的信号Fref同步的脉冲作为采样脉冲,然后从锯齿振荡电路采样与信号Fdet同步的锯齿波 5,检测到气体的产生。 通过使两个电池在温度环境下相同,可以防止由温度变化引起的影响。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Method for producing hydrogen
    • 生产氢的方法
    • JP2005232526A
    • 2005-09-02
    • JP2004042041
    • 2004-02-18
    • Ebara CorpNational Institute Of Advanced Industrial & Technology株式会社荏原製作所独立行政法人産業技術総合研究所
    • KATO TORUNOZAKI TAKESHIMATSUMURA SATORUYAMADA HIROYUKI
    • C25B1/04C25B9/00
    • Y02E60/366
    • PROBLEM TO BE SOLVED: To provide a method for efficiently producing hydrogen while reducing electric energy necessary for electrolysis of water by lowering electrolytic voltage through supplying a hydrocarbon-containing gas to an anode side of an apparatus for electrolyzing high-temperature steam, which has an electrolytic tank partitioned into the anode side and a cathode side with the use of a solid oxide electrolyte of a diaphragm, and through the consequent depolarization action of hydrocarbon, by preventing clogging in an electrode caused by solid-state carbon precipitated by the decomposition of hydrocarbon, and effectively using heat and an unburned gas component contained in an exhaust gas from the anode side after having finished the reaction.
      SOLUTION: The method for producing hydrogen by electrolyzing the high-temperature steam while decreasing electrolytic voltage through supplying steam to a cathode side of an apparatus for electrolyzing the high-temperature steam, which has an electrolytic tank partitioned into the anode side and the cathode side with the use of the solid oxide electrolyte of the diaphragm, and through supplying a hydrocarbon-containing gas to an anode side to react it with oxygen ions, includes mixing an exhaust gas discharged from the anode side of the electrolytic apparatus into the hydrocarbon-containing gas to be supplied to the anode side of the electrolytic apparatus.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题:提供一种通过向用于电解高温蒸汽的装置的阳极侧供给含烃气体来降低电解电压,同时降低电解水中所需的电能而有效地生产氢的方法, 其具有使用隔膜的固体氧化物电解质分隔成阳极侧和阴极侧的电解槽,并且通过随后的烃的去极化作用,通过防止由固体碳沉淀的固体碳引起的电极堵塞 分解烃,并且在完成反应之后有效地使用包含在来自阳极侧的废气中的热量和未燃烧气体成分。 解决方案:通过向用于电解具有分隔成阳极侧的电解槽的高温蒸汽的电解设备的阴极侧的蒸汽供给蒸汽而降低电解电压来生产氢气的方法,以及 使用隔膜的固体氧化物电解质的阴极侧,并且通过向阳极侧供给含烃气体以与氧离子反应,包括将从电解设备的阳极侧排出的废气混入到 供给到电解装置的阳极侧的含烃气体。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • DC POWER SUPPLY CIRCUIT
    • JPH11168884A
    • 1999-06-22
    • JP34583497
    • 1997-12-01
    • EBARA CORP
    • MATSUMURA SATORUHOTTA OSAMU
    • H02M7/155
    • PROBLEM TO BE SOLVED: To provide a DC power supply circuit which can sharply reduce losses in a no-load condition during the waiting operation. SOLUTION: In a DC power supply circuit for obtaining a DC current from the secondary side via a rectifying circuit by providing a transformer 1 and then connecting a commercial power supply 2 to a primary side, switching circuits 5, 6 for turning on and off the commercial power supply are provided between the primary side of the transformer 1 and the commercial power supply 2, the rectifying circuit is provided with a circuit 22 for detecting that a DC output voltage is larger or smaller compared to a constant value and a drive circuit 7 for turning on and off the switching circuit 5, 6 based on the detection result, in order to turn on and off the switching circuits 5, 6 depending on the load of the DC power supply circuit.