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    • 1. 发明专利
    • Chemical thermal storage system
    • 化学储热系统
    • JP2014181879A
    • 2014-09-29
    • JP2013057966
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • KOMAKI KATSUYAAKITA KENJIGOTO YOSUKEWAKASUGI TOMOHISASHIMAZU TAKASHIMITSUI HIROYUKIMOCHIZUKI MIYO
    • F28D20/00F02G5/02
    • F28D20/003Y02E20/14Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical heat storage system capable of improving heat utilization rate more than heretofore.SOLUTION: A chemical heat storage system 1 comprises: a reactor 11 filled with a chemical heat storage substance capable of reversibly performing hydration reaction and dehydration reaction; an evaporation condenser 12 configured such that steam to be used for hydration reaction of the chemical heat storage substance can be generated and steam generated by dehydration reaction of the hydrated chemical heat storage substance can be condensed; a communication path 13 for communicating the reactor 11 and the evaporation condenser 12 and circulating steam; and a flow rate adjusting means 14 which is disposed on the communication path 13 and adjusts flow rate of steam circulated within the communication path 13. The chemical heat storage system 1 is configured such that reaction heat accompanied by hydration reaction of the chemical heat storage substance in the reactor 11 and evaporation latent heat accompanied by generation of steam in the evaporation condenser 12 can be recovered and is configured such that a part or all of recovered reaction heat can be heat-exchanged with a portion 2 of a system outer part.
    • 要解决的问题:提供一种能够比迄今为止提高热利用率的化学蓄热系统。解决方案:化学蓄热系统1包括:填充有能够可逆地进行水合反应和脱水的化学蓄热物质的反应器11 反应; 蒸发冷凝器12构成为能够产生用于化学蓄热物质的水合反应的蒸汽,并且可以冷凝由水合化学蓄热物质脱水反应而产生的蒸汽; 用于连通反应器11和蒸发冷凝器12以及循环蒸汽的连通路径13; 以及流量调节装置14,其设置在连通路径13上并调节在连通路径13内循环的蒸汽的流量。化学蓄热系统1构造成使得伴随着化学储热物质的水合反应的反应热 在反应器11中,蒸发冷凝器12中伴随蒸汽产生的蒸发潜热可以被回收,并且被构造成使得回收的反应热的一部分或全部可以与系统外部的部分2进行热交换。
    • 2. 发明专利
    • Chemical heat storage device
    • 化学储热装置
    • JP2013113552A
    • 2013-06-10
    • JP2011262350
    • 2011-11-30
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所Denso Corp株式会社デンソー
    • WAKASUGI TOMOHISASHIMAZU TAKASHIKOMAKI KATSUYAKUWAYAMA KAZUTOSHIFUSE TAKUYANAKAGAWA TADAHIROSAEGUSA HIROSHI
    • F25B17/08
    • PROBLEM TO BE SOLVED: To improve an energy utilization rate by recovering sensible heat remaining in a reaction vessel in which the regeneration of a chemical heat storage material is completed.SOLUTION: The chemical heat storage device includes: a first heat exchange part 11 and first reaction vessels 12 (a plurality of reaction vessels) heated by a chemical reaction with a reaction material 16 and having a chemical heat storage material 18 from which the reaction material 16 is desorbed by heating; an evaporative condenser 14 storing the reaction material 16, and supplying the reaction material 16 to the reaction vessels while recovering the reaction material 16 desorbed from the chemical heat storage material 18; and the first heat exchange part 11 allowing heat exchange between the first heat exchange part 11 and the first reaction vessels 12 ( the plurality of reaction vessels).
    • 解决的问题:通过回收在化学蓄热材料的再生完成的反应容器中残存的显热来提高能量利用率。 解决方案:化学蓄热装置包括:通过与反应材料16的化学反应加热并具有化学蓄热材料18的第一热交换部分11和第一反应容器12(多个反应容器) 反应物料16通过加热解吸; 储存反应材料16的蒸发冷凝器14,并且在回收从化学蓄热材料18脱附的反应材料16的同时将反应材料16供给到反应容器中; 以及允许第一热交换部11和第一反应容器12(多个反应容器)之间进行热交换的第一热交换部11。 版权所有(C)2013,JPO&INPIT
    • 4. 发明专利
    • Heat storage device
    • 热存储设备
    • JP2010249412A
    • 2010-11-04
    • JP2009099302
    • 2009-04-15
    • Denso CorpToyota Central R&D Labs Inc株式会社デンソー株式会社豊田中央研究所
    • FUSE TAKUYAINOUE SATORUSAEGUSA HIROSHIKOMAKI KATSUYASHIMAZU TAKASHIFUKUSHIMA YOSHIAKIWAKAYAMA HIROAKI
    • F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a heat storage device capable of reducing an unreacted part of a filling layer, and reducing a thermal distribution inside of the filling layer.
      SOLUTION: This heat storage device has the filling layer 40 filled with heat storage agent particles 43 applying a gas as a reaction medium, internal flow passages 41, 42 formed form the surface of the filling layer 40 to the inside of the filling layer 40 for introducing the reaction medium supplied from the external into the filling layer 40 and releasing the reaction medium led out from the inside of the filling layer 40 to the external, a fluid flow channel 31 spatially separating from the filling layer 40 and the internal flow passages 41, 42 for circulating a heat exchange fluid, and a flat tube 30 having an outer wall face 30c exchanging heat with the filling layer 40, and an inner wall face 30d exchanging heat with the heat exchange fluid, and transferring heat between the filling layer 40 and the heat exchange fluid through the outer wall face 30c and the inner wall face 30d. The internal flow passages 41, 42 are formed in a state of being gradually narrowed from a surface of the filling layer 40 toward the depth.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种能够减少填充层的未反应部分并减少填充层内部的热分布的蓄热装置。 解热方案:该蓄热装置具有填充层40,填充有作为反应介质的气体的蓄热剂颗粒43,从填充层40的表面形成到填充层内部的内部流路41,42 用于将从外部供给的反应介质引入填充层40并将从填充层40的内部引出的反应介质释放到外部的层40,与填充层40和内部的空间分离的流体流动通道31 用于循环热交换流体的流动通道41,42和具有与填充层40进行热交换的外壁面30c的扁平管30和与热交换流体进行热交换的内壁面30d, 填充层40和热交换流体通过外壁面30c和内壁面30d。 内部流路41,42形成为从填充层40的表面向深度逐渐变窄的状态。 版权所有(C)2011,JPO&INPIT
    • 5. 发明专利
    • Adsorption type heat pump device
    • 吸附式热泵装置
    • JP2009121710A
    • 2009-06-04
    • JP2007293592
    • 2007-11-12
    • Denso Corp株式会社デンソー
    • KOMAKI KATSUYAINOUE SATORUSAEGUSA HIROSHIINOUE SEIJITANAKA YOSHIAKI
    • F25B17/08
    • Y02A30/278Y02B30/64
    • PROBLEM TO BE SOLVED: To prevent condensation of water vapor in a connection pipe portion connecting an evaporator 1 and an adsorption heat exchanger 3, or the adsorption heat exchanger 3 and a condenser 2.
      SOLUTION: The adsorption heat exchanger 3 includes a water vapor flowing-in portion 36 projecting from the adsorption heat exchanger 3 to be connected with an evaporator-side valve 5, and includes a heating means 40 for heating the water vapor flowing-in portion 36. Thus the water vapor flowing-in portion 36 connecting the evaporator-side valve 5 and the adsorption heat exchanger 3 and having the most effect on performance, that is, a pipe part at a side near the adsorption heat exchanger 3 from a part partitioned by the evaporator-side valve 5 is heated, the water vapor is prevented from condensing to be water droplets in the pipe part, and degradation of performance can be prevented.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了防止连接蒸发器1和吸附热交换器3的连接管部分或吸附热交换器3和冷凝器2中的水蒸气冷凝。解决方案:吸附热交换器 3包括从吸附热交换器3突出以与蒸发器侧阀5连接的水蒸气流入部分36,并且包括用于加热水蒸汽流入部分36的加热装置40.因此,水蒸汽流动 在从蒸发器侧阀5和吸附热交换器3连接并且对蒸发器侧阀分隔的部分的效果最大的部分36,即吸附热交换器3附近的管部分 5被加热,防止水蒸汽冷凝成管部分中的水滴,并且可以防止性能的劣化。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Steam engine
    • 蒸汽机
    • JP2007247609A
    • 2007-09-27
    • JP2006074984
    • 2006-03-17
    • Denso Corp株式会社デンソー
    • ODA SHUZOYATSUKA SHINICHIKOMAKI KATSUYA
    • F01B29/12F01K21/02
    • F01K21/00F01K13/006
    • PROBLEM TO BE SOLVED: To improve heat efficiency, in a steam engine constituted so as to generate fluid displacement in the liquid in a pipe, by repeatedly performing vaporization by heating of the liquid sealed in the pipe and liquefaction by cooling. SOLUTION: In this steam engine 1, the whole inner wall surface 22a of a connecting pipe part 22 is constituted as a water repellent treating surface 22b. Thus, a quantity of droplet becoming a state of sticking to the inner wall surface 22a of the connecting pipe part 22, can be reduced more than when the whole inner wall surface 22a of the connecting pipe part 22 is not formed as the water repellent treatment surface 22b, when pushing down a liquid level of the liquid in a vertically extending pipe 12 up to a bottom dead center Lb from the top dead center Lu, in response to boiling and vaporization by heating the liquid positioned in a vicinal part of a heater 30 in the vertically extending pipe 12. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了提高热效率,在蒸汽机中构成,以便在管道中的液体中产生流体的位移,通过加热密封在管道中的液体并通过冷却液化反复进行蒸发。 解决方案:在该蒸汽机1中,连接管部22的整个内壁面22a构成为防水处理表面22b。 因此,与连接管部22的整个内壁面22a不形成为防水处理相比,成为粘附于连接管部22的内壁面22a的状态的液滴的量可以减少 表面22b,当从位于上止点Lu的垂直延伸的管12中的液体液面向下死点Lb下降时,响应于通过加热定位在加热器的相邻部分中的液体的沸腾和汽化 30在垂直延伸管12中。版权所有(C)2007,JPO&INPIT
    • 7. 发明专利
    • Steam engine
    • 蒸汽机
    • JP2005330910A
    • 2005-12-02
    • JP2004150722
    • 2004-05-20
    • Denso Corp株式会社デンソー
    • KOMAKI KATSUYAODA SHUZOOCHI TAKESHIYATSUKA SHINICHI
    • F01B29/12A22C5/00F01K1/00F01K13/02F01K27/00
    • F01K27/005
    • PROBLEM TO BE SOLVED: To prevent the internal pressure of a container from exceeding the saturated steam pressure of a fluid during operation and the fluid vaporized by heating from being liquefied in a steam engine. SOLUTION: In this steam engine, a heater 12 and a cooler 13 are installed in a fluid container 11 sealed with a working fluid 20, the working fluid is vaporized by heating by the heater 12, and the vaporized working fluid is cooled by the cooler 13 for liquefication to generate a cyclic pressure fluctuation in the fluid container 11 so as to reciprocatingly move a piston by the pressure fluctuation. A cylindrical pressure regulating part 30 capable of regulating the volume of the fluid container by a regulator screw 32 is formed in the fluid container 11. In manufacturing the engine, after the working fluid 20 is sealed in the fluid container 11, the volume of the fluid container 11 is increased by utilizing the pressure regulating part 30. As a result, since the pressure of the fluid container 11 is lowered, it can be suppressed that the internal pressure exceeds a saturated steam pressure during the operation of the engine. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了防止在操作期间容器的内部压力超过流体的饱和蒸汽压力,并且通过加热而蒸发的流体在蒸汽发动机中液化。 解决方案:在该蒸汽机中,加热器12和冷却器13安装在用工作流体20密封的流体容器11中,工作流体通过加热器12的加热而蒸发,汽化的工作流体被冷却 通过冷却器13进行液化以在流体容器11中产生循环压力波动,以便通过压力波动使活塞往复移动。 在流体容器11中形成能够通过调节螺钉32调节流体容器的体积的圆筒形压力调节部30.在制造发动机时,在将工作流体20密封在流体容器11中之后, 流体容器11通过利用压力调节部30而增加。结果,由于流体容器11的压力降低,因此可以抑制在发动机运转期间内部压力超过饱和蒸汽压力。 版权所有(C)2006,JPO&NCIPI
    • 8. 发明专利
    • Chemical thermal storage air-conditioning system
    • 化学热储存空调系统
    • JP2014180979A
    • 2014-09-29
    • JP2013057968
    • 2013-03-21
    • Denso Corp株式会社デンソーToyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASE TOMOHIROFUSE TAKUYAKOMAKI KATSUYAMITSUI HIROYUKISHIMAZU TAKASHIWAKASUGI TOMOHISAMOCHIZUKI MIYO
    • B60H1/20B60H1/03B60H1/14F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system capable of flexibly responding to both of the case where heat is stored in a chemical thermal storage medium of a reactor by dehydration reaction and the case where heat is released from the chemical thermal storage medium of the reactor by hydration reaction.SOLUTION: A chemical thermal storage air-conditioning system 4 is used in an energy operation device 1 including energy conversion means 2 and energy storage means 3. The chemical thermal storage air-conditioning system 4 includes: a reactor 6 in which a chemical thermal storage medium 61 is incorporated: and air-conditioning piping 5 that accommodates the reactor 6 therein for passing air A. The reactor 6 includes: a first reaction unit 6A enabling dehydration reaction of the chemical thermal storage medium 61 by using exhaust energy X by the energy conversion means 2; and a second reaction unit 6B enabling dehydration reaction of the chemical thermal storage medium 61 by using either of the exhaust energy X or stored energy by the energy storage means 3.
    • 要解决的问题:提供一种能够灵敏地响应于通过脱水反应将热量存储在反应器的化学热存储介质中的情况和从化学品释放热量的情况的化学热存储空调系统 反应器的热存储介质通过水合反应。解决方案:化学热存储空调系统4用于包括能量转换装置2和储能装置3的能量操作装置1中。化学热存储空调系统4包括 :组装有化学蓄热介质61的反应器6和容纳反应器6的空气调节配管5,使空气A通过。反应器6包括:第一反应单元6A,其能够进行化学热存储器的脱水反应 介质61通过能量转换装置2使用废气能量X; 以及第二反应单元6B,其能够通过利用能量存储装置3中的任一种排放能量X或存储的能量来实现化学热存储介质61的脱水反应。
    • 9. 发明专利
    • Method for producing heat-storage substance powder, as well as chemical heat-storage apparatus and method for manufacturing the apparatus
    • 生产储热物质粉末的方法,作为化学加热储存装置和制造装置的方法
    • JP2010185035A
    • 2010-08-26
    • JP2009031299
    • 2009-02-13
    • Denso CorpToyota Central R&D Labs Inc株式会社デンソー株式会社豊田中央研究所
    • WAKAYAMA HIROAKIFUKUSHIMA YOSHIAKISHIMAZU TAKASHIMITSUI HIROYUKISOFUGAWA HIDEOKOMAKI KATSUYASAEGUSA HIROSHI
    • C09K5/08F28D20/00
    • Y02E60/142
    • PROBLEM TO BE SOLVED: To provide a method for producing a heat-storage substance powder with less reduction in a reaction rate even when injection and extraction of heat are repeated, and to provide a chemical heat-storage apparatus and a method for manufacturing the apparatus. SOLUTION: This method for producing the heat-storage substance powder includes a growing step of applying a temperature gradient or temperature cycle to a raw material liquid where a hydroxide source to be a chemical heat storage material is dissolved or dispersed in water, and growing a hydroxide crystal at an elevated temperature part or elevated temperature period of the raw material liquid. The method for manufacturing the chemical heat-storage apparatus includes a growing step of putting a growing liquid which contains water between the heat storage substance containing the chemical heat storage material which performs endotherm/exotherm by dehydration/hydration, and a heat-transfer wall to perform heat exchange with the heat storage substance, of applying the temperature gradient or temperature cycle to the growing liquid, and of growing the hydroxide crystal at an elevated temperature part or elevated temperature period of the growing liquid. The chemical heat-storage apparatus obtained using the method is also disclosed. COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供即使重复注入和提取热量也能较少降低反应速率的储热物质粉末的制备方法,并且提供化学蓄热装置和方法 制造设备。 解决方案:这种制备储热物质粉末的方法包括对将化学蓄热材料的氢氧化物源溶解或分散在水中的原料液体施加温度梯度或温度循环的生长步骤, 并在原料液体的高温部分或升高的温度下生长氢氧化物晶体。 制造化学蓄热装置的方法包括以下步骤:将含有通过脱水/水合进行吸热/放热的化学蓄热材料的蓄热物质和传热壁之间含有水的生长液体投入到 与储热物质进行热交换,向生长液体施加温度梯度或温度循环,以及在生长液体的高温部分或升高的温度下生长氢氧化物晶体。 还公开了使用该方法获得的化学蓄热装置。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Adsorption heat exchanger
    • 吸附式热交换器
    • JP2009121711A
    • 2009-06-04
    • JP2007293593
    • 2007-11-12
    • Denso Corp株式会社デンソー
    • KOMAKI KATSUYAINOUE SEIJIINOUE SATORUSAEGUSA HIROSHITANAKA YOSHIAKI
    • F25B35/04F28F23/00
    • Y02A30/278Y02B30/64
    • PROBLEM TO BE SOLVED: To improve performance by reducing flow channel resistance near an inlet/outlet of a water vapor passage 25.
      SOLUTION: The inside of a case 3 is composed of a first area A1 having an adsorbent filling layer 22 and a second area A2 free from the adsorbent filling layer 22, the water vapor passage 25A is formed from the second area A2 toward the inside of the adsorbing filling layer 22, and an area of the water vapor passage 25A at an inlet/outlet side opened to the second area A2 is wider than an area of the passage of the inside. Thus the flow channel resistance near the inlet/outlet of the water vapor passage 25A having a high flow rate of the water vapor, can be reduced. As an adsorbed medium can smoothly enter into the inside of the water vapor passage 25A when the passage is formed into the tapered shaped without changing the inside area of each water vapor passage 25A and the total amount of the adsorbent from that of the straight shape, the performance can be improved by just that much.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:通过减少水蒸汽通道25的入口/出口附近的流道阻力来改善性能。解决方案:壳体3的内部由具有吸附剂填充物的第一区域A1 层22和不含吸附剂填充层22的第二区域A2,从第二区域A2朝向吸附填充层22的内部形成水蒸气通路25A,在入口/出口处的水蒸气通路25A的区域, 向第二区域A2开口的出口侧比内部通道的面积宽。 因此,能够降低水蒸气流量高的水蒸气通路25A的入口/出口附近的流路阻力。 当不改变每个水蒸气通道25A的内部面积和吸附剂的总量与直线形状的总和相比,当通道形成锥形时,吸附介质可以平稳地进入水蒸气通道25A的内部, 性能可以通过这么多来改善。 版权所有(C)2009,JPO&INPIT