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    • 1. 发明专利
    • Laminated polyester film for coating metal sheet and method for manufacturing the same, laminated polyester film-coated metal sheet and method for manufacturing the same and laminated polyester film-coated metal can
    • 用于涂覆金属片的层压聚酯薄膜及其制造方法,层压聚酯薄膜包覆金属片及其制造方法和层压聚酯薄膜包覆金属罐
    • JP2005297380A
    • 2005-10-27
    • JP2004117555
    • 2004-04-13
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • MORI KUNIHARUISAKA TSUTOMUFUJITA HIROHISAOHASHI HIDETOHAYASHI TOMOHIKOTAKAO YUKIHIRO
    • B65D25/14B32B15/08B32B15/09B32B27/36B65D65/40
    • PROBLEM TO BE SOLVED: To provide a laminated polyester film for coating a metal sheet with a wide part for laminating the metal sheet, with little material loss, and being hardly broken, and in addition, to provide a laminated polyester film-coated metal sheet capable of drawing and wiping at a high speed and a high degree of processing, and having excellent can manufacturing properties. SOLUTION: The laminated polyester film for coating the metal sheet has a laminated constitution of a layer A/a layer B/a layer A, wherein the layer A comprises a crystalline polyester with a melting point of ≥180°C, the layer B comprises a polyester resin composition in which a polyester and an olefin polymer with a functional group of 200-2,000 equivalent/ton and an equivalent value sphere converted diameter of 0.25-2.0 μm are mixed by a ratio of 70/30-99/1 wt.%, and a molten resin film of a laminated resin composition of the layer A/the layer B/the layer A is solidified on a cooling roll with a surface roughness (Ra) of ≥0.2 μm and 3 . In addition, the laminated polyester film-coated metal sheet is obtained by covering the metal sheet with the laminated film. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种用于层压金属片的宽幅金属片的层压聚酯膜,材料损失少,几乎不破裂,另外,为了提供层压聚酯膜 - 能够以高速和高加工度进行拉伸和擦拭的涂布金属板,并具有优异的罐制造性能。 解决方案:用于涂覆金属片的叠层聚酯膜具有层A /层B /层A的层压结构,其中层A包括熔点≥180℃的结晶聚酯, 层B包含聚酯树脂组合物,其中聚酯和官能团为200-2000当量/吨,当量球转化直径为0.25-2.0μm的烯烃聚合物以70 / 30-99 / 1重量%,层A /层B /层A的层叠树脂组合物的熔融树脂膜在表面粗糙度(Ra)≥0.2μm且<4.0μm的冷却辊上固化,以及 在纵向方向上单轴拉伸以具有≤0.1μm的表面粗糙度(Ra)和≤1.360g/ cm 3的密度。 此外,通过用层压膜覆盖金属片,获得层压聚酯膜涂覆金属片。 版权所有(C)2006,JPO&NCIPI
    • 2. 发明专利
    • Polyester film-coated metal sheet, its manufacturing method and polyester film-coated metal can
    • 聚酯薄膜包覆金属片,其制造方法和聚酯薄膜包覆金属
    • JP2005178047A
    • 2005-07-07
    • JP2003418750
    • 2003-12-16
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • KONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKOMORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMU
    • B65D8/16B29C65/02B29K67/00B29L9/00B29L22/00B32B15/08B32B15/09B65D65/40
    • B29C66/71
    • PROBLEM TO BE SOLVED: To provide a polyester film-coated metal sheet excellent in can making properties, its manufacturing method and a polyester film-coated metal can having excellent characteristics. SOLUTION: The polyester film coated metal sheet is constituted by coating a metal sheet with a polyester film (AF) of layer (I)/layer (II) on the inner surface of a can and coating the metal sheet with a polyester film (BF) on the outer surface of the can. Herein, the layer (I) comprises a mixed polyester wherein wax is compounded with ethylene terephthalate and butylene terephthalate and the layer (II) comprises a polyester wherein 95 mol% or below of the total acid component residue is terephthalic acid residue and 5 mol% or above thereof comprises an ≥10C aliphatic dicarboxylic acid. The polyester film (BF) comprises the same mixed polyester as the layer (I). The polyester films are respectively bonded and applied to both sides of the metal sheet under pressure so that the layer (II) comes into contact with the metal sheet on the inner surface of the can and the polyester film (BF) comes into contact with the metal sheet on the outer surface of the can to obtain the polyester film-coated metal sheet. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供可制造性能优异的聚酯薄膜包覆金属片,其制造方法和具有优异特性的聚酯薄膜包衣金属罐。 &lt; P&gt;解决方案:聚酯薄膜包衣金属片是通过在罐的内表面上涂覆具有层(I)/层(II)的聚酯膜(AF)的金属板和用聚酯涂覆金属片 薄膜(BF)在罐的外表面上。 这里,层(I)包含混合聚酯,其中蜡与对苯二甲酸乙二醇酯和对苯二甲酸丁二醇酯复合,层(II)包含聚酯,其中总酸成分残基的95mol%或更低是对苯二甲酸残基和5mol% 或其上包含≥10C脂族二羧酸。 聚酯膜(BF)包含与层(I)相同的混合聚酯。 分别在压力下将聚酯薄膜粘合并施加到金属板的两侧,使得层(II)与罐的内表面上的金属片接触,并且聚酯膜(BF)与 将金属片放在罐的外表面上,得到聚酯薄膜包覆的金属片。 版权所有(C)2005,JPO&NCIPI
    • 3. 发明专利
    • Polyester film coated metal sheet, its manufacturing method and polyester film coated metal can
    • 聚酯薄膜涂层金属板,其制造方法和聚酯薄膜涂层金属罐
    • JP2005178045A
    • 2005-07-07
    • JP2003418732
    • 2003-12-16
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • KONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKOMORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMU
    • B65D25/14B29C65/02B29K67/00B29L9/00B29L22/00B32B15/08B32B15/09B65D25/34C08G63/183C08K5/524C08L67/02
    • B29C66/71
    • PROBLEM TO BE SOLVED: To provide a polyester film coated metal sheet excellent in can making properties, its manufacturing method and a polyester film coated metal can having excellent characteristics. SOLUTION: The polyester film coated metal sheet is constituted by coating a metal sheet with a polyester film (AF) of layer (I)/layer (II) on the inner surface side of a can and coating the metal sheet with a polyester film (BF) on the outer surface side of the can. Herein, the layer (I) comprises a mixed polyester containing ethylene terephthalate, butylene terephthalate and a stabilizer and the layer (II) comprises a polyester wherein 95 mol% or below of the total acid component residue is terephthalic acid residue and 5 mol% or above thereof comprises an ≥10C aliphatic dicarboxylic acid. The polyester film (BF) comprises the same mixed polyester as the layer (I). (AF) and (BF) are bonded to both sides of the metal sheet under pressure so that the layer (II) of (AF) becomes the innermost surface side and (AF), the metal sheet and (BF) come into contact with each other to obtain the polyester film coated metal sheet. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供可制造性能优异的聚酯薄膜包覆金属片,其制造方法和具有优异特性的聚酯薄膜包衣金属罐。 解决方案:聚酯薄膜包覆的金属片是通过在罐的内表面侧上涂覆层(I)/层(II)的聚酯膜(AF)的金属板和涂覆金属片 聚酯膜(BF)在罐体的外表面侧。 这里,层(I)包含含有对苯二甲酸乙二醇酯,对苯二甲酸丁二醇酯和稳定剂的混合聚酯,层(II)包含聚酯,其中95重量%以下的总酸成分残基为对苯二甲酸残基和5摩尔% 其上包含≥10C脂族二羧酸。 聚酯膜(BF)包含与层(I)相同的混合聚酯。 (AF)和(BF)在压力下结合到金属板的两侧,使得(AF)的层(II)成为最内表面侧和(AF),金属板和(BF)与 彼此获得聚酯薄膜涂层金属板。 版权所有(C)2005,JPO&NCIPI
    • 5. 发明专利
    • Polyester film for metal plate coating, method for producing the same and method for producing polyester film-coated metal plate
    • 用于金属板涂料的聚酯膜,其制造方法和用于生产聚酯薄膜包覆金属板的方法
    • JP2005139365A
    • 2005-06-02
    • JP2003379180
    • 2003-11-07
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • MORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMUKONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKO
    • C08J5/18B32B15/08B32B15/09C08L67/02
    • PROBLEM TO BE SOLVED: To provide a polyester film for metal plate coating, having a wide center part having uniform thickness, scarcely causing breakage of the film when cutting and removing the both ends, having little material loss, because the both ends can be recycled, excellent in a can-making property and scarcely causing whitening of the film and to provide a method for producing the film and a method for producing a polyester film-coated metal plate.
      SOLUTION: The polyester film having ≤0.1 μm surface roughness (Ra) is obtained by solidifying a melted resin film of polyester containing a polyester mainly composed of ethylene terephthalate and a polyester mainly composed of butylene terephthalate in (60:40) to (30:70) mixing ratio (weight ratio) and further compounding wax in an amount of 0.01-0.15 pts. wt. based on 100 pts. wt. polyester therewith by using a cooling roll having ≥0.2 μm and
    • 要解决的问题:为了提供一种用于金属板涂覆的聚酯膜,具有宽的中心部分具有均匀的厚度,在切割和去除两端时几乎不会导致膜的断裂,材料损失很小,因为两端 可再循环,制罐性优异,几乎不引起薄膜的白化,提供薄膜的制造方法以及聚酯薄膜包覆金属板的制造方法。 解决方案:通过将主要由对苯二甲酸乙二醇酯和主要由对苯二甲酸丁二醇酯组成的聚酯(60:40)的聚酯的聚酯的熔融树脂膜固化成(60:40)的聚酯树脂膜,得到具有≤0.1μm表面粗糙度(Ra)的聚酯膜, (30:70)混合比(重量比)和进一步混合蜡的量为0.01-0.15点。 重量。 基于100点。 重量。 通过使用≥0.2μm的冷却辊和<4.0μm的表面粗糙度(Ra)进行聚酯,然后在至少垂直方向上使固化的树脂膜单轴取向。 聚酯薄膜包覆金属板的制造方法包括将聚酯薄膜层叠在加热金属板上的工序。 版权所有(C)2005,JPO&NCIPI
    • 7. 发明专利
    • Polyester film coated metal sheet, its manufacturing method and polyester film coated metal can
    • 聚酯薄膜涂层金属板,其制造方法和聚酯薄膜涂层金属罐
    • JP2005178048A
    • 2005-07-07
    • JP2003418755
    • 2003-12-16
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • KONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKOMORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMU
    • B65D8/16B29C65/02B29K67/00B29L9/00B29L22/00B32B15/08B32B15/09C08G63/183C08K5/103C08K5/20C08L67/02
    • B29C66/45B29C66/1122B29C66/4322B29C66/71B29C66/723B29K2067/006B29K2067/003B29K2067/00
    • PROBLEM TO BE SOLVED: To provide a polyester film coated metal sheet excellent in can making properties, its manufacturing method and a polyester film coated metal can having excellent characteristics. SOLUTION: The polyester film coated metal sheet is constituted by coating a metal sheet with a polyester film (AF) of layer (I)/layer (II)/layer (III) on the inner surface of a can and coating the metal sheet with a polyester film (BF) on the outer surface of the can. Herein, the layer (I) and the layer (III) comprise a mixed polyester wherein wax is compounded with a mixture of ethylene terephthalate and butylene terephthalate and the layer (II) comprises a polyester wherein 95 mol% or below of the total acid component residue is terephthalic acid residue and 5 mol% or above thereof comprises an ≥10C aliphatic dicarboxylic acid. The polyester film (BF) comprises the same mixed polyester as the layer (I). The polyester films are respectively bonded and applied to both sides of the metal sheet under pressure so that the layer (I) or the layer (III) comes into contact with the metal sheet on the inner surface side of the can and the polyester film (BF) comes into contact with the metal sheet on the outer surface side of the can to obtain the polyester film coated metal sheet. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供可制造性能优异的聚酯薄膜包覆金属片,其制造方法和具有优异特性的聚酯薄膜包衣金属罐。 解决方案:聚酯薄膜包覆的金属片是通过在罐的内表面上涂覆具有层(I)/层(II)/层(III)的聚酯膜(AF)的金属板而构成的, 在罐的外表面上具有聚酯膜(BF)的金属板。 这里,层(I)和层(III)包含混合聚酯,其中蜡与对苯二甲酸乙二醇酯和对苯二甲酸丁二醇酯的混合物复合,层(II)包含聚酯,其中95重量%或更低的总酸成分 残基为对苯二甲酸残基,5摩尔%以上含有≥10C脂肪族二羧酸。 聚酯膜(BF)包含与层(I)相同的混合聚酯。 聚酯膜分别在压力下粘合并施加到金属板的两侧,使得层(I)或层(III)与罐的内表面侧上的金属片和聚酯膜( BF)与罐的外表面侧的金属片接触,得到聚酯膜被覆金属片。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Polyester film coated metal sheet, its manufacturing method and polyester film coated metal can
    • 聚酯薄膜涂层金属板,其制造方法和聚酯薄膜涂层金属罐
    • JP2005144734A
    • 2005-06-09
    • JP2003382271
    • 2003-11-12
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • KONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKOMORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMU
    • B32B15/09B32B15/08C08K5/524C08L67/02
    • PROBLEM TO BE SOLVED: To provide a polyester film coated metal sheet excellent in can making properties under a condition of a high speed/high processing degree. SOLUTION: A mixed polyester, which is prepared by compounding 0.01-3 pts.wt. of a phosphorous acid ester stabilizer with 100 pts.wt. of a mixed polyester wherein a weight mixing ratio of a polyester based on ethylene terephthalate and a polyester based on butylene terephthalate is 60:40-30:70 and restricted in its weight average molecular weight and density, is cooled and solidified on a cooling roll with a surface roughness (Ra) of 0.2-below 4.0 μm and the cooled mixed polyester is uniaxially stretched at least longitudinally to manufacture a polyester film. This polyester film is bonded at least to one side of a metal sheet, which is heated to a temperature from the melting point of butylene terephthalate of the polyester film -10°C to the melting point +50°C, under pressure to coat the metal sheet and this coated metal sheet is heated to a temperature higher than the melting point of ethylene terephthalate of the polyester film before quenched. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供在高速/高加工度的条件下具有优异的可制造性能的聚酯膜涂覆的金属片。

      解决方案:混合聚酯,其通过将0.01-3重量份 的具有100重量份的磷酸酯稳定剂 的混合聚酯,其中基于对苯二甲酸乙二醇酯的聚酯和基于对苯二甲酸丁二醇酯的聚酯的重量混合比为60:40-30:70并且其重均分子量和密度的限制在冷却辊上冷却和固化 其表面粗糙度(Ra)低于4.0μm,并且冷却的混合聚酯至少纵向单向拉伸以制造聚酯膜。 该聚酯薄膜至少粘合在金属薄片的一侧,该金属薄片被加热至聚酯薄膜的熔点为-10℃至+ 50℃的温度,在压力下涂布 金属片和该被覆金属片在淬火前被加热至高于聚酯膜的对苯二甲酸乙二醇酯的熔点的温度。 版权所有(C)2005,JPO&NCIPI

    • 9. 发明专利
    • Polyester film for metal plate coating, method for producing the same and method for producing polyester film-coated metal plate
    • 用于金属板涂料的聚酯膜,其制造方法和用于生产聚酯薄膜包覆金属板的方法
    • JP2005139366A
    • 2005-06-02
    • JP2003379185
    • 2003-11-07
    • Daiwa Can Co LtdToyobo Co Ltd大和製罐株式会社東洋紡績株式会社
    • MORI KUNIHARUFUJITA HIROHISAOHASHI HIDETOISAKA TSUTOMUKONDO YOSHITERUTAKAO YUKIHIROMATSUMURA JUNJIHAYASHI TOMOHIKO
    • C08J5/18B32B15/08B32B15/09C08K5/524C08L67/02
    • PROBLEM TO BE SOLVED: To provide a polyester film for metal plate coating, having a wide center part having uniform thickness, scarcely causing breakage of the film when cutting and removing the both ends, having little material loss, because the both ends can be recycled, excellent in a can-making property and scarcely causing whitening of the film and to provide a method for producing the film and a method for producing the polyester film-coated metal plate.
      SOLUTION: The polyester film having ≤0.1 μm surface roughness (Ra) is obtained by solidifying a melted resin film of polyester containing a polyester mainly composed of ethylene terephthalate and a polyester mainly composed of butylene terephthalate in (60:40) to (30:70) mixing ratio (weight ratio) and further compounding a phosphite stabilizer in an amount of 0.01-3 wt. based on 100 pts. wt. polyester therewith by using a cooling roll having ≥0.2 μm and
    • 要解决的问题:为了提供一种用于金属板涂覆的聚酯膜,具有宽的中心部分具有均匀的厚度,在切割和去除两端时几乎不会导致膜的断裂,材料损失很小,因为两端 可回收利用,制罐性优异,几乎不引起薄膜的白化,提供薄膜的制造方法以及聚酯薄膜包覆金属板的制造方法。 解决方案:通过将主要由对苯二甲酸乙二醇酯和主要由对苯二甲酸丁二醇酯组成的聚酯(60:40)的聚酯的聚酯的熔融树脂膜固化成(60:40)的聚酯树脂膜,得到具有≤0.1μm表面粗糙度(Ra)的聚酯膜, (30:70)混合比(重量比),并进一步混合量为0.01-3重量%的亚磷酸酯稳定剂 基于100点。 重量。 通过使用≥0.2μm的冷却辊和<4.0μm的表面粗糙度(Ra)进行聚酯,然后在至少垂直方向上使固化的树脂膜单轴取向。 聚酯薄膜包覆金属板的制造方法包括将聚酯薄膜层叠在加热金属板上的工序。 版权所有(C)2005,JPO&NCIPI