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    • 1. 发明专利
    • Heat-shrinkable polyester resin laminated film
    • 热收缩聚酯树脂层压薄膜
    • JP2013039787A
    • 2013-02-28
    • JP2011179454
    • 2011-08-19
    • Daiwa Can Co Ltd大和製罐株式会社
    • MATSUMURA JUNJIMATSUNAMI KATSUMASA
    • B32B27/36C08L67/02
    • B32B27/36B32B27/08B32B2250/03B32B2250/24B32B2250/40B32B2307/558B32B2307/5825B32B2307/736B32B2519/00C08L67/02
    • PROBLEM TO BE SOLVED: To provide a heat-shrinkable polyester resin film that excels in heat shrinkability and heat sealability, has improved in the impact resistance, and does not easily teared up to one direction.SOLUTION: A heat-shrinkable polyester resin laminated film comprises three layers of (A) layer, (B) layer, and (C) layer. The (A) layer and the (C) layer corresponding to the surface layers comprise the resin mixture including polyethylene terephthalate resin in 20-60 mass% and the copolymerized polyethylene terephthalate resin in 40-60 mass% containing the neopentyl glycol component in 20-40 mol% against total amount of diol component. The (B) layer corresponding to the intermediate layer comprises the resin mixture of the polybutylene terephthalate resin in 40-60 mass%, copolymerized polyethylene terephthalate resin in 20-40 mass% that contains the neopentyl glycol component of 20-40 mol% to the total amount of the diol component, and the polyethylene terephthalate resin in 0-40 mass%.
    • 要解决的问题:为了提供热收缩性和热封性优异的热收缩性聚酯树脂膜,耐冲击性提高,并且不易向一个方向进行切割。 解决方案:热收缩聚酯树脂层压膜包括三层(A)层,(B)层和(C)层。 对应于表面层的(A)层和(C)层包括20-60质量%的聚对苯二甲酸乙二醇酯树脂的树脂混合物,含有20-60质量%的新戊二醇组分的40-60质量%的共聚聚对苯二甲酸乙二醇酯树脂, 相对于二醇成分的总量为40摩尔%。 对应于中间层的(B)层包括40-60质量%的聚对苯二甲酸丁二醇酯树脂的树脂混合物,20-40质量%的共聚对苯二甲酸乙二醇酯树脂,其含有20-40摩尔%的新戊二醇组分 二醇成分的总量,聚对苯二甲酸乙二醇酯树脂为0〜40质量%。 版权所有(C)2013,JPO&INPIT
    • 2. 发明专利
    • Vertically uniaxially oriented polyester film for metal can, its manufacturing method and resin-laminated metal sheet
    • 用于金属罐的垂直均匀聚酯薄膜,其制造方法和树脂层压金属片
    • JP2009279902A
    • 2009-12-03
    • JP2008136872
    • 2008-05-26
    • Daiwa Can Co Ltd大和製罐株式会社
    • MATSUMURA JUNJINAKANO MICHITERUMATSUNAMI KATSUMASAKONDO YOSHITERUTAKAO YUKIHIRO
    • B29C55/06B29K67/00B29L7/00B32B15/09B65D8/16B65D65/40C08J5/18C08L67/02
    • PROBLEM TO BE SOLVED: To provide a vertically uniaxially oriented film for metal can which is composed of a specific resin composition suitable for a throttle can, a shear spun can or the like, is excellent in adhesion property, a laminate aptitude and film roll appearance and eliminates the need of a heat setting in a film formation process, to provide its manufacturing method, and to provide a resin-laminated metal sheet for metal can which is coated with the resin and is excellent in can-manufacturing performance.
      SOLUTION: The vertically uniaxially oriented film comprises a polyester resin composition comprising: 50 to 70 wt.% of polyester (a) having terephthalic acid as a dicarboxylic acid component and 1, 4-butanediol as a glycol component; and 50 to 30 wt.% of polyester (b) having terephthalic acid as the dicarboxylic acid component and ethylene glycol as the glycol component. In the vertically uniaxially oriented film for the metal can, (1) refractive index difference in a film surface (difference between a refractive index in a longitudinal direction and a refractive index in a lateral direction) ΔN is ≥60×10
      -3 , (2) crystallization fraction is ≤50% and (3) heating shrinkage ratio in a condition of 150°C for 30 minutes is ≤25% in a longitudinal direction (a MD direction) of the film and ≤8% in a lateral direction (a TD direction).
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种用于金属罐的垂直单向取向膜,其由适用于节流罐,剪切纺丝罐等的特定树脂组合物组成,粘合性能优异,层压板性能和 薄膜辊外观,并且在成膜过程中不需要热定形,以提供其制造方法,并且提供涂覆有树脂并且制造性能优异的用于金属罐的树脂层压金属片。 解决方案:垂直单轴取向膜包括聚酯树脂组合物,其包含:50至70重量%的具有对苯二甲酸作为二羧酸组分的聚酯(a)和1,4-丁二醇作为二元醇组分; 和50〜30重量%的具有对苯二甲酸作为二羧酸成分的聚酯(b)和作为二醇成分的乙二醇。 在金属罐的垂直单轴取向膜中,(1)膜表面的折射率差(长度方向的折射率与横向的折射率的差)ΔN为≥60×10 - 3 ,(2)结晶分数≤50%,(3)150℃30分钟的加热收缩率在膜的长度方向(MD方向)≤25%,≤ 横向方向(TD方向)为8%。 版权所有(C)2010,JPO&INPIT