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1. 发明专利

JP2008194615A Method of manufacturing catalyst for removal of carbon monoxide 有权
标题翻译：制造催化剂去除一氧化碳的方法
公开(公告)号：JP2008194615A
公开(公告)日：2008-08-28
申请号：JP2007032445
申请日：2007-02-13
申请人： Catalysts & Chem Ind Co Ltd , Idemitsu Kosan Co Ltd , 出光興産株式会社 , 触媒化成工業株式会社
发明人： KAWASHIMA YOSHIMI , UMEKI TAKASHI , MIZUNO TAKAYOSHI , KINO KATSUHIRO , KOYANAGI TSUGUO
IPC分类号： B01J23/46 , B01J37/02 , B01J37/18 , C01B3/38 , H01M8/06
CPC分类号： Y02P20/52 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a catalyst for removal of carbon monoxide which has high activity and selectivity because ruthenium metal supported acts effectively. SOLUTION: The method comprises causing ruthenium nitrate/nitric acid mixed aqueous solution to be absorbed by a metal oxide support and drying and reducing the resultant product. For the mixed aqueous solution, the solution with the concentration of ruthenium adjusted to 0.5 g/L has an absorbance of 2.0-4.0 at the wavelength of 600 nm is used. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决的问题：提供一种制造用于除去一氧化碳的催化剂的方法，其具有高的活性和选择性，因为负载的金属钌有效地起作用。解决方案：该方法包括使硝酸钌/硝酸混合水溶液被金属氧化物载体吸收并干燥并还原所得产物。对于混合水溶液，使用调节至0.5g / L的钌浓度的溶液在600nm的波长处具有2.0-4.0的吸光度。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2006044965A Method for manufacturing zeolite and adsorbent containing the zeolite for removing sulfur compound 有权
标题翻译：用于制造含有沸石的沸石和吸附剂的方法，用于除去硫化合物
公开(公告)号：JP2006044965A
公开(公告)日：2006-02-16
申请号：JP2004225410
申请日：2004-08-02
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , TAKEKOSHI TAKEJI , KAWASHIMA YOSHIMI
IPC分类号： C01B39/24 , B01J20/18 , B01J29/12 , B01J29/74 , C01B3/40 , C01B39/46 , C10G25/05 , C10L3/10 , H01M8/06
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a silver ion-exchange zeolite suitable to be used for an adsorbent capable of efficiently removing sulfur compounds from a hydrocarbon fuel or a dimethyl ether fuel to a low content even at room temperature, and an absorbent containing the silver ion-exchange zeolite for removing sulfur compounds, and further a method for effectively manufacturing hydrogen capable of being used for a fuel cell from a hydrocarbon fuel or a dimethyl ether fuel desulfurized by using the adsorbent, and a fuel cell system using the hydrogen. SOLUTION: The method for manufacturing a silver ion-exchange zeolite comprises subjecting a solution containing silver amine complex ions to silver ion-exchange at pH 4-9 to cause zeolite to carry the silver. The adsorbent for removing sulfur compounds contains the silver ion-exchange zeolite. The method for manufacturing hydrogen capable of being used for a fuel cell from a hydrocarbon fuel or a dimethyl ether fuel uses the adsorbent for desulfurizing. The fuel cell system uses the hydrogen. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种适用于能够有效地从烃燃料或二甲醚燃料中除去硫化合物的吸附剂的银离子交换沸石的制造方法，即使在室温下也是低含量以及含有用于除去硫化合物的银离子交换沸石的吸收剂，还有一种从烃燃料或使用该吸附剂脱硫的二甲醚燃料中有效地制造能够用于燃料电池的氢的方法，以及燃料使用氢气的电池系统。解决方案：制备银离子交换沸石的方法包括使含有银胺络合物离子的溶液在pH 4-9下进行银离子交换以使沸石携带银。用于除去硫化合物的吸附剂含有银离子交换沸石。用于从烃燃料或二甲醚燃料中用于燃料电池的氢的制造方法使用用于脱硫的吸附剂。燃料电池系统使用氢气。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2012066961A Method of generating hydrogen from hydrocarbon compound 审中-公开
标题翻译：从烃类化合物产生氢的方法
公开(公告)号：JP2012066961A
公开(公告)日：2012-04-05
申请号：JP2010212461
申请日：2010-09-22
申请人： Idemitsu Kosan Co Ltd , Tohoku Univ , 出光興産株式会社 , 国立大学法人東北大学
发明人： KAWASHIMA YOSHIMI , UMEKI TAKASHI , FUKUNAGA TETSUYA , WATANABE NORIAKI , KINOSHITA MUTSUMI , TSUCHIYA NORIYOSHI
IPC分类号： C01B3/02 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a method of generating hydrogen, wherein the method eliminates the needs for high temperature, complicate steps and a large apparatus, produces no carbon monoxide as a by-product, and is highly improved in energy efficiency from a hydrocarbon compound, especially a biomass.SOLUTION: The method of generating the hydrogen from the hydrocarbon compound includes: a step (a) of generating the hydrogen by the reaction of a sulfur compound present in an alkaline solution with water; and a step (b) of reducing the sulfur compound oxidized through the step (a) with a hydrocarbon compound that may have oxygen.
摘要翻译：要解决的问题：提供一种产生氢气的方法，其中该方法消除了对高温，复杂步骤和大型装置的需要，不产生一氧化碳作为副产物，并且能量效率大大提高来自烃化合物，特别是生物质。解决方案：从烃化合物产生氢的方法包括：通过碱溶液中存在的硫化合物与水的反应产生氢的步骤（a）; 和（b）通过步骤（a）将可氧化的烃化合物氧化的硫化合物还原。版权所有（C）2012，JPO＆INPIT

4. 发明专利

JP2006055771A Production method for metal-supported zeolite molded material and adsorbent containing the same for removing sulfur compound 有权
标题翻译：用于金属支撑的ZEOLITE模制材料的生产方法和包含其的用于除去硫化合物的吸附剂
公开(公告)号：JP2006055771A
公开(公告)日：2006-03-02
申请号：JP2004241133
申请日：2004-08-20
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , TAKEKOSHI TAKEJI , KAWASHIMA YOSHIMI
IPC分类号： B01J20/18 , B01D53/04 , B01J20/30 , C01B3/40 , C01B39/02 , C10G25/05 , C10G29/04 , C10L1/00 , C10L3/10 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a metal-supported zeolite molded material wherein sulfur compounds containing not only thiols and sulfides but also carbonyl sulfide in hydrocarbon fuel or a dimethyl ether fuel can be effectively removed to low concentrations and a production method therefor, and an adsorbent for removing sulfur compounds containing the metal-supported zeolite molded material, and to provide a method for effectively producing hydrogen using this adsorbent from the hydrocarbon fuel or the dimethyl ether fuel after desulfurization and a fuel cell system using its hydrogen. SOLUTION: The metal-supported zeolite molded material has a metal component both inside and outside a zeolite crystal. The production method for the metal-supported zeolite molded material is so constituted that a zeolite molded material is used, a metal ion is supported in inside of the zeolite crystal by metal-exchanging and then a metal or a metal compound is supported outside the zeolite crystal. The adsorbent for removing the sulfur compound has this metal-supported zeolite molded material. Hydrogen is produced from the hydrocarbon fuel or the dimethyl ether fuel after desulfurization by using this adsorbent. The fuel cell system using its hydrogen is provided. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种金属负载的沸石模制材料，其中可以有效地除去在烃燃料或二甲醚燃料中不仅含有硫醇和硫化物而且含硫化物的硫化合物，而且其生产方法以及用于除去含有金属负载的沸石模塑材料的硫化合物的吸附剂，以及提供使用该脱硫后的烃燃料或二甲醚燃料的该吸附剂和使用其氢气的燃料电池系统有效地生产氢的方法。解决方案：金属负载的沸石模制材料在沸石晶体的内部和外部具有金属组分。金属负载型沸石成型体的制造方法为使用沸石成型体，通过金属交换将金属离子负载在沸石晶体的内部，金属或金属化合物负载在沸石外水晶。用于除去硫化合物的吸附剂具有该金属负载的沸石模制材料。通过使用该吸附剂在脱硫后由烃燃料或二甲醚燃料生成氢。提供了使用其氢气的燃料电池系统。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2012139637A Copper-zinc-aluminum catalyst, method of producing the same, carbon monoxide conversion method, and method of producing hydrogen 有权
标题翻译：铜 - 铝 - 铝催化剂，其生产方法，一氧化碳转化方法和生产氢的方法
公开(公告)号：JP2012139637A
公开(公告)日：2012-07-26
申请号：JP2010293904
申请日：2010-12-28
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , NAKAI SATOSHI , YOSHINAKA MASAHIRO , KAWASHIMA YOSHIMI
IPC分类号： B01J23/80 , C01B3/38
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a copper-zinc-aluminum catalyst having high activity and durability even under the condition that the temperature rise and drop are repeated such as in a fuel cell.SOLUTION: The copper-zinc-aluminum catalyst containing copper, zinc, aluminum and oxygen contains 60-90 mass% copper expressed in terms of CuO, 2-15 mass% zinc expressed in terms of ZnO, 5-30 mass% aluminum expressed in terms of AlOand has 50-200 m/g specific surface area, ≤200 Å CuO crystallite diameter, 0.6-2.0 g/cmbulk density, 0.30-0.60 cm/g pore volume and 45-120 Å average pore diameter, wherein X-ray diffraction pattern has broad peaks of ≥1.0 ° half-value width in a lattice spacing d(Å) of 2.44±0.05 and 2.86±0.05 and no peak in any lattice spacing d(Å) of 2.48±0.05, 2.81±0.05 and 2.60±0.05.
摘要翻译：要解决的问题：即使在诸如燃料电池中重复升温和降温的条件下，也提供具有高活性和耐久性的铜 - 锌 - 铝催化剂。解决方案：含有铜，锌，铝和氧的铜 - 锌 - 铝催化剂含有以CuO表示的60-90质量％的铜，以ZnO表示的2-15质量％的锌，5-30质量％铝表示为Al 2 O 3 ，并且具有50-200 m 2 < SP> / g比表面积，≤200ÅCuO微晶直径，0.6-2.0g / cm 3 SPF =“POST”> 3 体积密度，0.30-0.60cm 3 孔体积和平均孔径为45-120埃，其中X射线衍射图在晶格间距d（Å）为2.44±0.05和2.86±0.05时具有≥1.0度半值宽度的宽峰并且在任何晶格间距d（Å）中没有峰值为2.48±0.05,2.81±0.05和2.60±0.05。版权所有（C）2012，JPO＆INPIT

6. 发明专利

JP2008081326A Co converting apparatus and method, and fuel cell system and method for controlling the same 审中-公开
标题翻译： CO转换装置和方法，以及燃料电池系统及其控制方法
公开(公告)号：JP2008081326A
公开(公告)日：2008-04-10
申请号：JP2006259662
申请日：2006-09-25
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： KAWASHIMA YOSHIMI , UMEKI TAKASHI
IPC分类号： C01B3/48 , H01M8/04 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a fuel cell system which can well convert CO by controlling deactivation of a copper-based catalyst. SOLUTION: When a copper-based CO conversion catalyst in a CO converter 142 is heated to 150°C during start-up, an inert gas is supplied to provide a reduction atmosphere to the CO conversion catalyst. Before the temperature falls to a temperature where steam condensates at the time the operation is stopped, an inert gas is supplied and sealed within the CO converter 142. Thus, the activity of the CO conversion catalyst is stabilized for a long period of time with almost no aggregation of copper. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够通过控制铜基催化剂的失活来很好地转化CO的燃料电池系统。解决方案：当CO转化器142中的铜基CO转化催化剂在启动期间被加热至150℃时，供应惰性气体以向CO转化催化剂提供还原气氛。在温度下降到停止运行时蒸汽冷凝的温度之前，将惰性气体供给并密封在CO转化器142内。因此，CO转化催化剂的活性在很长一段时间内稳定，几乎没有铜的聚集。版权所有（C）2008，JPO＆INPIT

7. 发明专利

JP2006299955A Power generation system of diesel engine 审中-公开
标题翻译：柴油发动机发电系统
公开(公告)号：JP2006299955A
公开(公告)日：2006-11-02
申请号：JP2005123550
申请日：2005-04-21
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： SUZUKI KAZUHIKO , KAWASHIMA YOSHIMI
IPC分类号： F01N3/28 , B01D53/94 , B01J29/46 , F01N3/08 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To provide a power generation system of a diesel engine including an NOx selective reducing section which comprises a catalyst having high durability against sulfur poisoning without using a reducing agent. SOLUTION: In the diesel engine power generation system 1 which drives an electric generator 11 by the diesel engine 10, the diesel engine is a homogeneous charge compression ignition combustion engine. The diesel engine power generation system 1 includes the NOx selective reducing section 13 for cleaning up exhaust gas from the diesel engine 10, and the NOx selective reducing catalyst is used for the NOx selective reducing section 13. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种柴油发动机的发电系统，该柴油发动机包括NOx选择还原部，该NOx选择还原部包括不使用还原剂的，对硫中毒具有高耐久性的催化剂。解决方案：在由柴油发动机10驱动发电机11的柴油发动机发电系统1中，柴油发动机是均质充气压缩点火内燃机。柴油发动机发电系统1包括用于净化来自柴油发动机10的废气的NOx选择减少部分13，并且NOx选择还原催化剂用于NOx选择还原部分13。版权所有（C）2007 ，JPO＆INPIT

8. 发明专利

JP2006036616A Method for manufacturing zeolite and adsorbent containing the zeolite for removing sulfur compound 审中-公开
标题翻译：用于制造含有沸石的沸石和吸附剂的方法，用于除去硫化合物
公开(公告)号：JP2006036616A
公开(公告)日：2006-02-09
申请号：JP2004223389
申请日：2004-07-30
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , TAKEKOSHI TAKEJI , KAWASHIMA YOSHIMI
IPC分类号： C01B39/24 , B01J20/18 , C01B3/40 , C10L1/00 , C10L3/10 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a metal ion-exchange zeolite suitable to be used for an adsorbent for removing a sulfur compound capable of efficiently removing the sulfur compound from a hydrocarbon fuel or a dimethyl ether fuel to a low content even at room temperature, the adsorbent containing the metal ion-exchange zeolite for removing the sulfur compound, a method for efficiently manufacturing hydrogen usable for a fuel cell from the hydrocarbon fuel or the dimethyl ether fuel desulfurized by the adsorbent and a fuel cell system using the hydrogen. SOLUTION: The method for manufacturing the metal ion-exchange zeolite comprises carrying out metal ion-exchange of a type Y zeolite containing sodium of 0.5-5 mass% by using a solution which desirably contains metal ammine complex ions in order to cause the zeolite to carry the resulting metal. The adsorbent for removing the sulfur compound contains the metal ion-exchange zeolite. Furthermore, the hydrogen usable for the fuel cell is manufactured using the hydrocarbon fuel or the dimethyl ether fuel desulfurized by using the adsorbent, and the resulting hydrogen is used for the fuel cell system. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决问题的方法：提供一种适合用于除去能够从烃燃料或二甲醚燃料中除去硫化合物的硫化合物的吸附剂的金属离子交换沸石的制造方法，低含量，甚至在室温下，含有用于除去硫化合物的金属离子交换沸石的吸附剂，用于从烃燃料或由吸附剂脱硫的二甲醚燃料中有效地制造用于燃料电池的氢的方法和燃料电池系统使用氢气。解决方案：金属离子交换沸石的制造方法包括使用含有金属氨络合离子的溶液进行含有0.5〜5质量％的钠的Y型沸石的金属离子交换，以使沸石携带所得金属。用于除去硫化合物的吸附剂含有金属离子交换沸石。此外，可以使用通过使用吸附剂脱硫的烃燃料或二甲醚燃料来制造可用于燃料电池的氢，并且将所得氢用于燃料电池系统。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2012183459A Carbon monoxide shift catalyst, method for producing the same, method for converting carbon monoxide, and method for producing hydrogen 审中-公开
标题翻译：碳氧化物转化催化剂，其生产方法，一氧化碳转化方法和生产氢气的方法
公开(公告)号：JP2012183459A
公开(公告)日：2012-09-27
申请号：JP2011047006
申请日：2011-03-03
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , NAKAI SATOSHI , YOSHINAKA MASAHIRO , KAWASHIMA YOSHIMI
IPC分类号： B01J23/80 , B01J35/10 , B01J37/03 , C01B3/36 , C01B3/48 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a carbon monoxide shift catalyst high in activity and durability.SOLUTION: The carbon monoxide shift catalyst comprises a copper-zinc-aluminum catalyst containing copper, zinc, aluminum and oxygen. The content of copper is 30-90 mass% in terms of CuO, that of zinc is 3-30 mass% in terms of ZnO and that of aluminum is 7-60 mass% in terms of AlO. The carbon monoxide shift catalyst has a 80-200 m/g specific surface area, a ≤120 Å CuO crystallite diameter, 0.6-1.5 g/cmbulk density, a 0.3-0.6 cm/g pore volume and a 45-120 Å average pore radius.
摘要翻译：要解决的问题：提供高活性和耐久性的一氧化碳转移催化剂。一氧化碳转移催化剂包括含有铜，锌，铝和氧的铜 - 锌 - 铝催化剂。铜的含量以CuO计为30〜90质量％，锌的含量换算为ZnO为3-30质量％，铝的含量以Al 2 O 3 。一氧化碳转移催化剂具有80-200m比表面积，≤120ACuO微晶直径，0.6-1.5g / cm 2 SP SP =“POST” “> 3 堆积密度，0.3-0.6厘米 3 /克孔体积和45-120埃的平均孔半径。版权所有（C）2012，JPO＆INPIT

10. 发明专利

JP2009241036A Carbon monoxide conversion catalyst comprising composition for carbon monoxide conversion catalyst, and method of removing carbon monoxide using the same 审中-公开
标题翻译：用于一氧化碳转化催化剂的包含组合物的一氧化碳转化催化剂及其使用的一氧化碳的除去方法
公开(公告)号：JP2009241036A
公开(公告)日：2009-10-22
申请号：JP2008094080
申请日：2008-03-31
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： TAKATSU KOZO , KAWASHIMA YOSHIMI , UMEKI TAKASHI , NAKAI SATOSHI
IPC分类号： B01J23/80 , B01J23/89 , B01J37/04 , B01J37/08 , C01B3/40 , C01B3/48 , H01M8/06
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a carbon monoxide conversion catalyst having excellent catalytic activity and durability, small in the deterioration of activity even when applied to a fuel cell and used as a water gas shift reaction catalyst which can be used for a long period of time, and a method of removing carbon monoxide using the carbon monoxide conversion catalyst. SOLUTION: The carbon monoxide conversion catalyst contains (A) a copper oxide component, (B) a zinc oxide component and (C) an aluminum oxide component, wherein at least 0.01-0.5 mmol element of one of a group I, a group II, a group VIII, a group X and a group XIII per 1 g in total of (A)-(C) is contained as a (D) component. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：为了提供具有优异的催化活性和耐久性的一氧化碳转化催化剂，即使在施加到燃料电池上时也具有较小的活性劣化，并且用作可用于燃料电池的水煤气变换反应催化剂长时间使用一氧化碳转化催化剂除去一氧化碳的方法。一氧化碳转化催化剂含有（A）氧化铜组分，（B）氧化锌组分和（C）氧化铝组分，其中至少含有0.01-0.5mmol元素的组I，作为（D）成分，含有（A） - （C）的总计1g的第II族，第VIII族，X族和第XIII族。版权所有（C）2010，JPO＆INPIT

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