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    • 1. 发明专利
    • Co-removing catalyst and its manufacturing method
    • CO去除催化剂及其制造方法
    • JP2006142239A
    • 2006-06-08
    • JP2004337609
    • 2004-11-22
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • YOSHINAKA MASAHIROFUKUNAGA TETSUYA
    • B01J27/25B01J37/00B01J37/16C01B3/38H01M8/06
    • Y02P20/52Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a CO-removing catalyst from which a nitrogen compound produced from the CO-removing catalyst during the operation of a fuel cell system and poisoning the electrode of a fuel cell is restrained from being caused, and to provide a method for manufacturing the CO-removing catalyst. SOLUTION: This CO-removing catalyst is manufactured by depositing a nitrogen-containing ruthenium compound on a fire-resistant oxide carrier and made to have ≤0.5 wt% nitrogen content. The method for manufacturing the CO-removing catalyst comprises the steps of: depositing the nitrogen-containing ruthenium compound on the fire-resistant oxide carrier; and removing the nitrogen content of the deposited nitrogen-containing ruthenium compound. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种除去催化剂,从而抑制在燃料电池系统的操作期间由CO去除催化剂产生的氮化合物和燃料电池的电极中毒,并且, 以提供制造除氧催化剂的方法。 解决方案:通过在耐火氧化物载体上沉积含氮钌化合物并制成具有≤0.5重量%的氮含量来制造该除氧催化剂。 制造除氧催化剂的方法包括以下步骤:将含氮钌化合物沉积在耐火氧化物载体上; 并除去沉积的含氮钌化合物的氮含量。 版权所有(C)2006,JPO&NCIPI
    • 2. 发明专利
    • Copper-zinc-aluminum catalyst, method of producing the same, carbon monoxide conversion method, and method of producing hydrogen
    • 铜 - 铝 - 铝催化剂,其生产方法,一氧化碳转化方法和生产氢的方法
    • JP2012139637A
    • 2012-07-26
    • JP2010293904
    • 2010-12-28
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • TAKATSU KOZONAKAI SATOSHIYOSHINAKA MASAHIROKAWASHIMA YOSHIMI
    • B01J23/80C01B3/38
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a copper-zinc-aluminum catalyst having high activity and durability even under the condition that the temperature rise and drop are repeated such as in a fuel cell.SOLUTION: The copper-zinc-aluminum catalyst containing copper, zinc, aluminum and oxygen contains 60-90 mass% copper expressed in terms of CuO, 2-15 mass% zinc expressed in terms of ZnO, 5-30 mass% aluminum expressed in terms of AlOand has 50-200 m/g specific surface area, ≤200 Å CuO crystallite diameter, 0.6-2.0 g/cmbulk density, 0.30-0.60 cm/g pore volume and 45-120 Å average pore diameter, wherein X-ray diffraction pattern has broad peaks of ≥1.0 ° half-value width in a lattice spacing d(Å) of 2.44±0.05 and 2.86±0.05 and no peak in any lattice spacing d(Å) of 2.48±0.05, 2.81±0.05 and 2.60±0.05.
    • 要解决的问题:即使在诸如燃料电池中重复升温和降温的条件下,也提供具有高活性和耐久性的铜 - 锌 - 铝催化剂。 解决方案:含有铜,锌,铝和氧的铜 - 锌 - 铝催化剂含有以CuO表示的60-90质量%的铜,以ZnO表示的2-15质量%的锌,5-30质量% 铝表示为Al 2 O 3 ,并且具有50-200 m 2 < SP> / g比表面积,≤200ÅCuO微晶直径,0.6-2.0g / cm 3 SPF =“POST”> 3 体积密度,0.30-0.60cm 3 孔体积和平均孔径为45-120埃,其中X射线衍射图在晶格间距d(Å)为2.44±0.05和2.86±0.05时具有≥1.0度半值宽度的宽峰 并且在任何晶格间距d(Å)中没有峰值为2.48±0.05,2.81±0.05和2.60±0.05。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • Co-removing catalyst and its manufacturing method
    • CO去除催化剂及其制造方法
    • JP2006142240A
    • 2006-06-08
    • JP2004337632
    • 2004-11-22
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • YOSHINAKA MASAHIROFUKUNAGA TETSUYA
    • B01J23/46C01B3/38C10K3/04H01M8/06
    • Y02P20/52Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a CO-removing catalyst the CO-methanation activity of which is low and to provide a method for manufacturing the CO-removing catalyst.
      SOLUTION: This method for manufacturing the CO-removing catalyst comprises the step of impregnating a fire-resistant oxide carrier with a ruthenium compound solution of the volume 1.1-1.3 times as much as the volume of water to be absorbed by the fire-resistant oxide carrier. This CO-removing catalyst can be obtained by using this method. It is preferable that at least one selected from alumina, titania, silica, zirconia and ceria is used as the fire-resistant oxide carrier and ruthenium nitrate is used as the ruthenium compound.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种CO-甲烷化活性低的除氧催化剂,并提供一种制造除氧催化剂的方法。 解决方案:用于制造除氧催化剂的方法包括用耐火氧化物载体浸渍的体积为被火吸收的水的体积的1.1-1.3倍的钌化合物溶液的步骤 耐氧化物载体。 该除氧催化剂可以通过使用该方法得到。 优选使用氧化铝,二氧化钛,二氧化硅,氧化锆和二氧化铈中的至少一种作为耐火氧化物载体,并使用硝酸钌作为钌化合物。 版权所有(C)2006,JPO&NCIPI