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    • 5. 发明专利
    • Anode-side and cathode-side electrode catalysts, film electrode assembly, and fuel battery cell
    • 阳极侧和阴极侧电极催化剂,电极电极组件和燃料电池
    • JP2012059402A
    • 2012-03-22
    • JP2010198916
    • 2010-09-06
    • Cataler CorpToyota Motor Corpトヨタ自動車株式会社株式会社キャタラー
    • OHASHI SOZABURONAGAMI TETSUOKATAOKA MIKIHIROTERADA TOMOAKINAGATA TAKAHIROHORIUCHI YOSUKEHORI AKIHIRO
    • H01M8/02H01M4/86H01M4/88H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide anode-side and cathode-side electrode catalysts with excellent water retention balance for actualizing a self-humidifying fuel battery based upon relation between acid group densities of the cathode-side and anode-side electrode catalysts, a film electrode assembly with the electrode catalysts, and a fuel battery cell with the film electrode assembly.SOLUTION: With respect to the anode-side and cathode-side catalysts 300, 200 forming a film electrode assembly 400, acid group densities of a catalyst support carrier 10 forming the anode-side electrode catalyst 300 and a catalyst support carrier 10 forming the cathode-side electrode catalyst are both within a range defined by two expressions of (1) Y=-0.5X+0.83 and (2) Y=-0.5X+1.03, where Y is the acid group density (mmol/g) of catalyst support carrier 10 forming the anode-side electrode catalyst 300, and X is the acid group density (mmol/g) of the catalyst support carrier 10 forming the anode-side electrode catalyst.
    • 要解决的问题:为了提供具有优异的保水平衡的阳极侧和阴极侧电极催化剂,用于根据阴极侧和阳极侧电极催化剂的酸基密度之间的关系实现自加湿燃料电池 ,具有电极催化剂的膜电极组件和具有膜电极组件的燃料电池单元。 解决方案:对于形成膜电极组件400的阳极侧和阴极侧催化剂300,200,形成阳极侧电极催化剂300的催化剂载体10的酸基密度和催化剂载体载体10 形成阴极侧电极催化剂都在由(1)Y = -0.5X + 0.83和(2)Y = -0.5X + 1.03的两个表达式限定的范围内,其中Y是酸基密度(mmol / g )形成阳极侧电极催化剂300的催化剂载体载体10,X是形成阳极侧电极催化剂的催化剂载体10的酸基密度(mmol / g)。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • Method for evaluating catalyst layer of solid polymer fuel cell
    • 用于评估固体聚合物燃料电池催化层的方法
    • JP2011028973A
    • 2011-02-10
    • JP2009172827
    • 2009-07-24
    • Cataler CorpToyota Motor Corpトヨタ自動車株式会社株式会社キャタラー
    • TAKEDA NAMINAGAMI TETSUOKATAOKA MIKIHIROHORIUCHI YOSUKEHORI AKIHIRO
    • H01M8/04H01M4/88H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method for evaluating the proton conductivity of the catalyst layer of a solid polymer fuel cell.
      SOLUTION: The proton conductivity of the catalyst layer of the solid polymer fuel cell including carbon powder where a catalyst is supported and hydrophilic treatment is applied, and proton conductive polymer electrolyte is evaluated in accordance with a proton moving distance coefficient defined by an expression :(proton moving distance coefficient)=d×A×S×r
      × , where d is the thickness (μm) of the catalyst layer, A is the acid amount (mmol/g) per unit weight of the carbon powder where the catalyst is supported and the hydrophilic treatment is applied, S is a carrier shape factor determined by the shape of the carbon powder, r is a weight ratio P/C of the proton conductive polymer electrolyte (P) to the carbon powder (C) where thr catalyst is supported and the hydrophilic treatment is applied, in the catalyst layer, and x is -1. It is Preferable to control the proton moving distance coefficient to be 0.05-0.8.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:提供一种用于评价固体高分子型燃料电池的催化剂层的质子传导率的方法。 解决方案:包括催化剂负载的碳粉末和进行亲水处理的固体聚合物燃料电池的催化剂层的质子传导率和质子传导性高分子电解质根据由 表达式:(质子移动距离系数)= d×A×S×r ×,其中d是催化剂层的厚度(μm),A是每单位的酸量(mmol / g) 负载催化剂的碳粉的重量和进行亲水处理的S是由碳粉的形状决定的载流子形状因子,r是质子传导性聚合物电解质(P)〜(P)的重量比P / C 在催化剂层中负载催化剂和进行亲水处理的碳粉末(C),x为-1。 优选控制质子移动距离系数为0.05-0.8。 版权所有(C)2011,JPO&INPIT
    • 10. 发明专利
    • Cathode catalyst for fuel cell
    • 用于燃料电池的CATHODE催化剂
    • JP2005129358A
    • 2005-05-19
    • JP2003363734
    • 2003-10-23
    • Cataler CorpToyota Motor Corpトヨタ自動車株式会社株式会社キャタラー
    • ITO TETSUOTERADA TOMOAKIKATO HISAONAGAMI TETSUO
    • B01J21/18B01J23/89H01M4/90H01M4/92H01M8/10
    • H01M4/921B01J21/18B01J23/8906B01J23/8993C22C5/04H01M4/926
    • PROBLEM TO BE SOLVED: To provide a cathode catalyst for a fuel cell which contains platinum and iron that are capable of maintaining durability of a cell and are capable of making the cell have a high output. SOLUTION: This is a cathode catalyst for the fuel cell which comprises a carrying layer composed of an alloy containing platinum, iron, and furthermore one kind or more of elements out of tungsten, titanium, molybdenum, rhenium, zinc, manganese, tin, tantalum, and rhodium that are third components having affinity with iron, and a carrier carrying the carrying layer. The catalyst using the alloy containing platinum and iron can make the cell have a high output. By making the alloy containing platinum and iron an alloy that contains one kind or more of elements out of third components having affinity with iron, elution of iron into the electrolyte can be prevented. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种能够维持电池的耐久性并且能够使电池具有高输出量的含有铂和铁的燃料电池用阴极催化剂。 解决方案:这是一种用于燃料电池的阴极催化剂,其包括由含有铂,铁以及另外一种或多种钨,钛,钼,铼,锌,锰等元素的合金构成的载体层, 作为与铁具有亲和性的第三成分的锡,钽和铑以及承载层的载体。 使用含有铂和铁的合金的催化剂可以使电池具有高产量。 通过使含有铂和铁的合金是含有与铁具有亲和性的第三成分中的一种以上的元素的合金,可以防止铁向电解液中的溶出。 版权所有(C)2005,JPO&NCIPI