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    • 1. 发明专利
    • FEEDER FOR FINELY POWDERED SOLID CARBONACEOUS RAW MATERIAL
    • JP2001226682A
    • 2001-08-21
    • JP2000034774
    • 2000-02-14
    • BABCOCK HITACHI KK
    • UEDA AKIOYOSHIDA KUNIKATSUYOSHIDA NAOMITAKEDA MAKOTOUEDA TOSHIYUKI
    • B65G53/08C10J3/50
    • PROBLEM TO BE SOLVED: To prevent the amount supplied from varying when a finely powdered solid carbonaceous raw material accommodated in a pressurized feed hopper is taken out and supplied to a gasifying furnace. SOLUTION: This feeder for finely powdered solid carbonaceous raw material is constructed by containing the pressurized feed hopper 30 accommodating a finely powdered coal, a feeder 34 connected to the bottom of the feed hopper 30 through a valve 33, a passage-reduced part 35 connected to the outlet side of the feeder 34, a supplying pipe arrangement 36 of nitrogen gas supplying the passage-reduced part 35 with nitrogen gas for conveying, a differential pressure detecting pipe 38 connecting the upper spatial part in the feed hopper 30 with the passage-reduced part 35, a differential pressure detector 39 installed in the differential pressure detecting pipe 38 and detecting and outputting a differential pressure between the upper spatial part in the feed hopper 30 and the passage-reduced part 35, a pipe arrangement 25 of nitrogen gas for pressurizing connected to the feed hopper 30 and supplying nitrogen gas, a flow control valve 26 installed in the pipe arrangement 25 of nitrogen gas for pressurizing and controlling a flow rate of nitrogen gas and a controller 27 controlling the flow control valve 26 in accordance with an output signal of the differential pressure detector 39.
    • 4. 发明专利
    • METHOD FOR DETECTING ABNORMAL FEEDING OF COAL INTO COAL GASIFICATION DEVICE
    • JPH0532977A
    • 1993-02-09
    • JP19377591
    • 1991-08-02
    • BABCOCK HITACHI KK
    • UEDA TOSHIYUKIKIDA EIJI
    • C10J3/46C10J3/50C10J3/72
    • PURPOSE:To rapidly detect the abnormal feeding of coal by charging the coal into a hopper, increasing the pressure of a gas in the hopper with a pressing gas, introducing a pressure-controlling gas and a coal-fluidizing gas into the hopper, feeding the coal into a gasification oven with a coal-feeding gas and detecting the concentrations of the gases in the gasification product. CONSTITUTION:Coal is charged into a rock hopper 3, and a pressing gas is introduced into the rock hopper 3 through a press valve 23 to increase the pressure. A pressure-controlling gas 7 and a coal-fluidizing gas 8 are introduced into a feeding hopper 4 to control the pressure of the gas in the feeding hopper 4 and simultaneously fluidize the charged coal. The coal carried from the feeding hopper 4 is fed into a coal-gasification oven 12 with a coal-feeding gas 10. The concentrations of components in the pressure-controlling gas 7 and the coal-fluidizing gas 8 in the coal-feeding gas 10 passed through the coal- gasification oven 12 are detected, and the lowering of the feeding amount of the coal is detected on the basis of the increase in the detected concentrations of the components, thus rapidly detecting the abnormal feeding of the coal.
    • 5. 发明专利
    • COAL GASIFICATION COMPOUND POWER GENERATION METHOD
    • JPH04116232A
    • 1992-04-16
    • JP23746090
    • 1990-09-07
    • BABCOCK HITACHI KK
    • KIDA EIJIUEDA TOSHIYUKI
    • F02C3/28C10J3/72
    • PURPOSE:To decrease generation of NOx so as to simplify the separating operation of CO2 after burning of generated gas by using oxygeon as an oxygeon source of a gas turbine as well as using exhaust gas as gas for coal supply, and gas for char circulation. CONSTITUTION:The air compressed by an air compressor 11 is supplied to a cryogenic separator 17, and oxygeon separated by the cryogenic separator 17 is supplied to a gas turbine 8 and a gasification furnace 4 through an oxygeon compressor 10. The exhaust gas mainly composed of CO2 cooled by a heat recovery device 12 is respectively supplied to a feed lines to the gas turbine 8 and the gasification furnace 4 for material coal 1 and to a circulation line for char collected by a dust collector 5 through an exhaust gas compressor 16. As it is, so constituted that no nitrogenous component except the nitrogen within the material coal 1 may be mixed in the system, NOx is hardly generated therein. Exhaust gas 24 in the outlet finally becomes CO2 independent gas, and not only it can be used as inactive gas, but also it can be easily collected in slip stream.
    • 9. 发明专利
    • PRODUCTION OF METHYL ETHYL KETONE
    • JPS61186341A
    • 1986-08-20
    • JP2443285
    • 1985-02-13
    • BABCOCK HITACHI KK
    • UEDA TOSHIYUKIFURUE TOSHIKI
    • C07C49/10C07C45/00C07C45/28C07C67/00
    • PURPOSE:To obtain the titled substance economically with reduced steam consumption and investment cost, by synthesizing the titled substance by the oxidation of 1-butene and 2-butene in the presence of an oxygen catalyst, and separating the catalyst with a flash distillation column at a specific temperature and pressure. CONSTITUTION:Methyl ethyl ketone is synthesized by oxidizing 1-butene and 2-butene (line 1) in the oxidation reactor 6 in the presence of a catalyst activating oxygen by forming an oxygen complex. The reaction liquid of the oxidation reactor 6 is heated with the heat-exchanger 11 and the steam heater 12, and introduced to the catalyst-separation column 7 (a flash distillation column). The reaction liquid is separated into gas and liquid by the vacuum effect in the distillation column controlled to 60-100 deg.C and 0--0.7kg/cm G pressure. The aqueous solution of catalyst returned from the catalyst-separation column 7 is aerated in the oxygen-absorption column 5 with air 2 to form an oxygen complex. The objective substance is delivered from the line 13.
    • 10. 发明专利
    • Production of methyl ethyl ketone
    • 甲基乙基酮的生产
    • JPS6143131A
    • 1986-03-01
    • JP16478784
    • 1984-08-08
    • Babcock Hitachi Kk
    • FURUE TOSHIKIUEDA TOSHIYUKIKAKO HIROYUKI
    • C07C49/10B01J31/22B01J31/24C07C45/34
    • PURPOSE: The titled compound is produced by carring out the isobutene-removal pretreatment, and oxidizing the resultant raw material composed of 1-butene and 2-butene in the presence of a metal complex compound catalyst, converting unreacted 2-butene to 1-butene, and recyling to the raw material gas.
      CONSTITUTION: A 4C fraction containing 1-butene and 2-butene is supplied through the line 5 to the reactor 6 containing the solution of O
      2 -absorbed metallic catalyst (e.g. a catalyst solution prepared by adding a proper amount of water to PdCl
      2 , CuCl, hexamethyl-phosphoramide and benzonitrile, and absorbing O
      2 in the catalyst liquid in the O
      2 -absorption column 8 to obtain an oxygen complex). Methyl ethyl ketone can be produced from 1-butene by this process. The residual 4C fraction containing 2-butene is introduced into the isomerization reactor 22, and the converted 1-butene is recycled to the reactor 6 as the recycling 4C fraction.
      EFFECT: The objective product can be produced at a relatively low temperature and pressure in high yield.
      USE: Solvent, detergent, polymerization initiator for the resin curing agent, etc.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过除去异丁烯预处理,在金属配位化合物催化剂的存在下氧化由1-丁烯和2-丁烯组成的原料,将未反应的2-丁烯转化成1-丁烯,得到标题化合物 ,并重新生产原料气。 构成:将含有1-丁烯和2-丁烯的4C馏分通过管线5供给到含有吸收了O2的金属催化剂溶液的反应器6(例如通过将适量的水加入到PdCl 2,CuCl, 六甲基磷酰胺和苄腈,并且在O 2吸收塔8中的催化剂液体中吸收O 2以获得氧络合物)。 可以通过该方法由1-丁烯生产甲基乙基酮。 将含有2-丁烯的残余4C馏分引入异构化反应器22中,将转化的1-丁烯作为回收4C馏分再循环至反应器6。 效果:目标产品可以在相对较低的温度和压力下以高产率生产。 用途:溶剂,洗涤剂,树脂固化剂聚合引发剂等