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    • 6. 发明专利
    • PRODUCTION OF PROTECTING TUBE FOR THERMOELECTRIC COUPLE
    • JPH1067582A
    • 1998-03-10
    • JP24412996
    • 1996-08-27
    • ASAHI GLASS CO LTD
    • NAKAYAMA TAKAHIROKAGEYAMA NOBUO
    • G01K1/08C04B41/52C04B41/53C04B41/85C04B41/88C04B41/91
    • PROBLEM TO BE SOLVED: To obtain a protecting tube for a thermoelectric couple without having an oozing out of silicon projections at the inner peripheral surface of a sintered material tube by forming a silicon nitride membrane at the inner peripheral surface of the sintered material tube formed by using a silicone carbide powder, and burned, and then impregnating a molten silicon therein. SOLUTION: This protecting tube for a thermoelectric couple 21 is obtained by (1) forming a tube closed at one end 21a thereof and opened at another end 21b by using a raw material containing a silicon carbide powder and an organic cinder, (2) burning the formed material at 1500-2000 deg.C for 30-400min to obtain a sintered material, (3) applying a silicon powder to the inner peripheral surface of the sintered tube by preferably using a method for application of pouring a slurry containing the silicon powder into the tube and then draining out, and forming a silicone nitride membrane 22 by effecting a gas containing nitrogen at 1000-1500 deg.C, (4) impregnating a molten silica to the sintered material formed with the silicon nitride membrane at the inner peripheral surface thereof at 1500-1650 deg.C, and (5) mechanically removing silicon oozing out to the outer peripheral surface of the tube and solidifying in a state of projections.