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1. 发明专利

JPH11273754A Organic pigment sensitization-type oxide semiconductor and solar battery including it 有权
标题翻译：有机颜料致敏型氧化物半导体和太阳能电池包括其中
公开(公告)号：JPH11273754A
公开(公告)日：1999-10-08
申请号：JP868499
申请日：1999-01-18
申请人： Agency Of Ind Science & Technol , 工業技術院長
发明人： SAYAMA KAZUHIRO , ARAKAWA HIRONORI , SUGIHARA HIDEKI
IPC分类号： H01L21/28 , H01B1/16 , H01L31/04 , H01M14/00
CPC分类号： Y02E10/542
摘要： PROBLEM TO BE SOLVED: To provide a device for generating a large short circuit current and a high open circuit voltage, by forming, on a conductive surface of a substrate, an oxide semiconductor film having a film thickness, at least, of a specific size and a ratio more than a specific value, of its actual surface area to its apparent surface area, and causing a surface of the oxide semiconductor film to adsorb a specific organic pigment.
SOLUTION: An oxide semiconductor is of zinc oxide, an oxide semiconductor film is a porous-structured film of the burned matter of an oxide semiconductor particulate aggregate, the film thickness is at least 10 nm, preferably 100 to 10,000 nm. and a ratio of its actual surface area to its apparent surface area is 10 or more, preferably 100 or more, and normally 1,000 to 2,000 without any upper limit. As an organic pigment, at least one kind is used selected from among dibromofluoresceine, dichlorofluoresceine, ergthrosine B, and fluoresceine. By combining such an oxide semiconductor with such an organic pigment, a solar battery is obtained having oxide semiconductor electrodes giving a practical current/voltage curve and a redox electrolyte contacting therewith.
COPYRIGHT: (C)1999,JPO
摘要翻译：要解决的问题：为了提供一种用于产生大的短路电流和高开路电压的装置，通过在衬底的导电表面上形成具有至少具有特定尺寸的膜厚的氧化物半导体膜并且其比实际表面积与其表观表面积的比值大于特定值，并使氧化物半导体膜的表面吸附特定的有机颜料。解决方案：氧化物半导体是氧化锌，氧化物半导体膜是氧化物半导体颗粒聚集体的烧成物质的多孔结构膜，膜厚度至少为10nm，优选为100至10,000nm。其实际表面积与其表观面积的比例为10以上，优选为100以上，通常为1,000〜2000，无任何上限。作为有机颜料，使用选自二溴荧光素，二氯荧光素，ergthrosine B和荧光素中的至少一种。通过将这样的氧化物半导体与这种有机颜料组合，得到具有赋予实用电流/电压曲线的氧化物半导体电极和与其接触的氧化还原电解质的太阳能电池。

2. 发明专利

JPH11273755A Organic coloring matter sensitizing niobium oxide semiconductor electrode and solar cell containing it 有权
标题翻译：有机颜料敏感度氧化镍半导体电极及其包含的太阳能电池
公开(公告)号：JPH11273755A
公开(公告)日：1999-10-08
申请号：JP869299
申请日：1999-01-18
申请人： Agency Of Ind Science & Technol , 工業技術院長
发明人： SAYAMA KAZUHIRO , ARAKAWA HIRONORI , SUGIHARA HIDEKI
IPC分类号： H01L21/28 , H01B1/16 , H01L31/04 , H01M14/00
CPC分类号： Y02E10/542 , Y02P70/521
摘要： PROBLEM TO BE SOLVED: To provide a niobium oxide electrode providing a practical current/ voltage curve, and a solar cell containing this electrode in an organic coloring matter sensitizing oxide semiconductor electrode. SOLUTION: An organic coloring matter having 9-phenylxanthene skeleton and an amino group is adsorbed in a burned product of niobium oxide semiconductor fine particle aggregate having a thickness of at least 10 nm, and a ratio of an actual surface area to an apparent surface area of 10 or more. The organic coloring matter is preferable to be at least one selected from the group comprising rhodamine B, amino pyrogallol, fluorothene amine I, fluorothene amine II, rhodamine 123, and rhodamine 6G.
摘要翻译：要解决的问题：提供一种提供实用电流/电压曲线的铌氧化物电极和在有机色素敏化氧化物半导体电极中含有该电极的太阳能电池。解决方案：具有9-苯基呫吨骨架和氨基的有机色素被吸附在具有至少10nm的厚度的铌氧化物半导体细颗粒聚集体的烧制产物中，并且实际表面积与表观表面积之比为10以上。有机色素优选为选自罗丹明B，氨基连苯三酚，氟代苯胺I，氟代乙胺II，罗丹明123和罗丹明6G中的至少一种。

3. 发明专利

JPS6172737A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172737A
公开(公告)日：1986-04-14
申请号：JP19548984
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C67/00 , C07C231/00 , C07C231/02 , C07C235/20 , C07C235/24 , C25B11/08
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 is H, alkyl, aromatic hydrocarbon group or alkylaromatic group; R
2 and R
3 same as R
1 and at least one of each is alkyl, aryl or alkylaryl group; n is 1W3).
EXAMPLE: 1,2-Bis(N-n-octylaminocarbonylmethoxy)benzene.
USE: It is useful as a cation carrier in a polymeric membrane for ion selective electrode. When plasticizers and hydrophobic anions coexist in the polymer membrane, the compds. show selective electromotive response especially for calcium ion, so the activity of calcium ion can be measured in the presence of alkaline metal ions, except calcium ion, and ammonium ion.
PREPARATION: A biscarboxylic acid chloride expressed by formula III and two equiv. of a primary or secondary amine are acylated in an inert solvent, in the presence of a tertiary amine at -20°CW room temp., to obtain the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I表示（R 1是H，烷基，芳族烃基或烷基芳基; R 2和R 3与R 1相同，并且其中至少一个是烷基，芳基或烷基芳基; n为1-3）。实施例：1,2-双（N-正辛基氨基羰基甲氧基）苯。用途：作为离子选择电极聚合物膜中的阳离子载体是有用的。当增塑剂和疏水性阴离子共存在聚合物膜中时，显示出对钙离子的选择性电动反应，因此钙离子的活性可以在碱金属离子（钙离子和铵离子除外）的存在下测定。制备：由式III表示的双羧酸氯化物和2当量的伯胺或仲胺在惰性溶剂中，在叔胺存在下，在-20℃ - 室温下酰化，得到化合物。由公式I表示。

4. 发明专利

JPS6172738A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172738A
公开(公告)日：1986-04-14
申请号：JP19548884
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C231/02 , C07C233/18 , C07C233/68 , G01N27/30
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 and R
2 are H, alkyl, aromatic hydrocarbon group or alkyl aromatic group, R
3 is alkyl, aromatic hydrocarbon group or alkyl aromatic group, n is 1W3).
EXAMPLE: 1,2-Bis[3-(n-octanoylamino)propoxy]-4-t-butylbenzene.
USE: A carrier for ion selective electrode. Especially when the campd. coexist with plasticizers and hydrophobic anions in a polymer membrane, they show selective electromotive response to specific cations depending on the composition of the membrane.
PREPARATION: A catechol derivative expressed by formula II and an acyl chloride are reacted in the presence of a tertiary amine, in an inert solvent at -20°CW room temp., to give the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I（R 1和R 2）表示为H，烷基，芳族烃基或烷基芳基，R 3为烷基，芳族烃基或烷基芳基，n为1-3）。实施例：1,2-双[3-（正辛酰基氨基）丙氧基] -4-叔丁基苯。用途：离子选择电极载体。特别是营地时。与聚合物膜中的增塑剂和疏水阴离子共存，它们根据膜的组成显示对特定阳离子的选择性电动反应。制备：将式II表示的儿茶酚衍生物和酰氯在叔胺的存在下，在惰性溶剂中，在-20℃ - 室温下反应，得到化合物。由公式I表示。

5. 发明专利

JPS59216847A Polyether derivative useful as ionophore 失效
标题翻译：聚醚衍生物作为离子源有用
公开(公告)号：JPS59216847A
公开(公告)日：1984-12-06
申请号：JP1198683
申请日：1983-01-27
申请人： Agency Of Ind Science & Technol
发明人： TAGUCHI KAZUHIRO , HIRATANI KAZUHISA , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , C07C51/00 , C07C51/347 , C07C65/21 , C07C67/00
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:A polyether derivative shown by the formula I [R
1 , R
2 , and R
3 are H, or alkyl; R
4 is substituent group containing two or more of H, alkyl, benzyl, 2-phenylethyl, 3-(naphthyl-1-oxy)propyl, 2-propyleneoxyphenoxy unit as repeating units].
EXAMPLE: 1-[ 3'-(O-Carboxylphenoxy)propyloxy ]-2-( 3'-O-ethoxyphenyloxy )propyloxy-4-t-butylbenzene.
USE: Useful as a cationic carrier (ionophore). Acting selectively especially on lithium ion, capable of transporting it against concentration gradient.
PREPARATION: A polyether derivative shown by the formula II (R
5 is reaction protecting group) is hydrolyzed under alkali conditions, to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：由式I [R 1，R 2和R 3]表示的聚醚衍生物是H或烷基; R 4是含有H，烷基，苄基，2-苯基乙基，3-（萘基-1-氧基）丙基，2-丙烯氧基苯氧基单元作为重复单元的两个或更多个的取代基。实施例：1- [3' - （O-羧基苯氧基）丙氧基] -2-（3'-O-乙氧基苯氧基）丙氧基-4-叔丁基苯。用途：用作阳离子载体（ionophore）。特别是对锂离子进行选择，能够将其与浓度梯度进行运输。制备：在碱性条件下水解式II所示的聚醚衍生物（R 5为反应保护基），得到式I所示的化合物。

6. 发明专利

JPS59163342A Cation transferring method using dicarboxylic acid polyether derivative as carrier to transfer alkaline earth metal ion 失效
标题翻译：使用二羧酸聚醚衍生物作为载体转移碱金属离子的载体转移方法
公开(公告)号：JPS59163342A
公开(公告)日：1984-09-14
申请号：JP3863683
申请日：1983-03-08
申请人： Agency Of Ind Science & Technol
发明人： HIRATANI KAZUHISA , TAGUCHI KAZUHIRO , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , B01D11/04 , B01D15/00 , B01J45/00 , B01J47/00 , C07C65/21
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:The compound of formula I (n is 2 or 3; R and R are H or alkyl). EXAMPLE:1,2-Bis {3'-(o-carboxyphenyloxy)propyloxy}-4-t-butylbenzene. USE:A cation transfer agent (ionophore) acting selectively to an alkaline earth metal ion, having variable selective transfer capability of the above ion according to the structure and the condition of transfer, and capable of transferring the cation against the concentration gradient. PREPARATION:The objective compound of formula I can be prepared by reacting the compound of formula III with the compound of formula IV (R is protecting group) in an alkaline medium at 30-150 deg.C, especially 60-120 deg.C, and hydrolyzing the resultant compound of formula V by conventional method. When the compound is used as an ionophore, and two kinds of solutions A and B are contacted indirectly interposing the solution of the ionophore M between them, the cation contained in the solution A can be transferred to the solution B.
摘要翻译：新材料：式I化合物（n为2或3; R 1和R 2为H或烷基）。实施例：1,2-双（3' - （邻 - 羧基苯氧基）丙氧基} -4-叔丁基苯。用途：选择性地对碱土金属离子起作用的阳离子转移剂（离子载体），其具有根据结构和转移条件的上述离子的选择性转移能力，并能够相对于浓度梯度转移阳离子。制备：式I的目的化合物可以通过使式III化合物与式IV化合物（R 3是保护基）在碱性介质中在30-150℃，特别是60-120度并通过常规方法水解得到的式V化合物。当化合物用作离子载体时，并且两种溶液A和B在它们之间间接插入离子载体M的溶液时，溶液A中所含的阳离子可以转移到溶液B中。

7. 发明专利

JPS59163343A Polyether derivative useful as ionophore 失效
标题翻译：聚醚衍生物作为离子源有用
公开(公告)号：JPS59163343A
公开(公告)日：1984-09-14
申请号：JP3863783
申请日：1983-03-08
申请人： Agency Of Ind Science & Technol
发明人： HIRATANI KAZUHISA , TAGUCHI KAZUHIRO , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , B01D11/04 , B01J45/00 , B01J47/00 , C07C51/00 , C07C51/09 , C07C65/21 , C07C67/00
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:The compound of formula I [R -R are H or alkyl; R may be benzyl, 2-phenylethyl, 3-(naphthyl-1-oxy)propyl or group of formula II (n>=2)]. EXAMPLE:1-[3'-( o-Carboxylphenyloxy )propyloxy]-2-[3'-( o-ethoxyphenyloxy )-propyloxy]-4(or 5)-t-butylbenzene. USE:A cation transfer agent (ionophore) acting selectively especially to lithium ion, capable of transferring the ion against concentration gradient, and having equal rate of transfer independent of the kind of anion. PREPARATION:The compound of formula I can be prepared by hydrolyzing the compound of formula III (R is protecting group) under alkaline condition. When the compound is used as an ionophore, and two kinds of solutions A and B are contacted indirectly interposing the solution of the ionophore M between them, the cation contained in the solution A can be transferred to the solution B.
摘要翻译：新材料：式I化合物[R 1 -R 4]为H或烷基; R 4可以是苄基，2-苯基乙基，3-（萘基-1-氧基）丙基或式II的基团（n> = 2）]。实施例：1- [3' - （邻 - 羧基苯氧基）丙氧基] -2- [3' - （邻 - 乙氧基苯氧基） - 丙氧基] -4（或5） - 叔丁基苯。用途：选择性地特别对锂离子起作用的离子迁移剂（离子载体），其能够离子浓度梯度转移，并且具有与阴离子种类相同的相等转移速率。制备：式Ⅰ化合物可以在碱性条件下水解式Ⅲ化合物（R 5为保护基）来制备。当化合物用作离子载体时，并且两种溶液A和B在它们之间间接插入离子载体M的溶液时，溶液A中所含的阳离子可以转移到溶液B中。

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