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1. 发明专利

JPS6172737A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172737A
公开(公告)日：1986-04-14
申请号：JP19548984
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C67/00 , C07C231/00 , C07C231/02 , C07C235/20 , C07C235/24 , C25B11/08
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 is H, alkyl, aromatic hydrocarbon group or alkylaromatic group; R
2 and R
3 same as R
1 and at least one of each is alkyl, aryl or alkylaryl group; n is 1W3).
EXAMPLE: 1,2-Bis(N-n-octylaminocarbonylmethoxy)benzene.
USE: It is useful as a cation carrier in a polymeric membrane for ion selective electrode. When plasticizers and hydrophobic anions coexist in the polymer membrane, the compds. show selective electromotive response especially for calcium ion, so the activity of calcium ion can be measured in the presence of alkaline metal ions, except calcium ion, and ammonium ion.
PREPARATION: A biscarboxylic acid chloride expressed by formula III and two equiv. of a primary or secondary amine are acylated in an inert solvent, in the presence of a tertiary amine at -20°CW room temp., to obtain the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I表示（R 1是H，烷基，芳族烃基或烷基芳基; R 2和R 3与R 1相同，并且其中至少一个是烷基，芳基或烷基芳基; n为1-3）。实施例：1,2-双（N-正辛基氨基羰基甲氧基）苯。用途：作为离子选择电极聚合物膜中的阳离子载体是有用的。当增塑剂和疏水性阴离子共存在聚合物膜中时，显示出对钙离子的选择性电动反应，因此钙离子的活性可以在碱金属离子（钙离子和铵离子除外）的存在下测定。制备：由式III表示的双羧酸氯化物和2当量的伯胺或仲胺在惰性溶剂中，在叔胺存在下，在-20℃ - 室温下酰化，得到化合物。由公式I表示。

2. 发明专利

JPH11280639A High polymer electrolyte ammonium derivative 失效
标题翻译：高分子电解质氨基衍生物
公开(公告)号：JPH11280639A
公开(公告)日：1999-10-15
申请号：JP8449598
申请日：1998-03-30
申请人： Agency Of Ind Science & Technol , Kagaku Gijutsu Senryaku Suishin Kiko , 工業技術院長 , 財団法人化学技術戦略推進機構
发明人： OGURO KEISUKE , AZUMI KINSHI , OKADA TATSUHIRO , ONISHI KAZUO , SEWA SHINGO
IPC分类号： F03G7/00 , C08F8/30 , C08L101/00 , C08L101/16 , H02N11/00
CPC分类号： Y02E70/10
摘要： PROBLEM TO BE SOLVED: To create high polymer actuator which does not have air pockets and has good response, by immersing ion-exchange resin formed parts with metal electrodes provided on the surface into alkyl ammonium ionic solution, and by creating potential difference between metal electrodes, to bend and deform plastic parts. SOLUTION: A high polymer electrolyte ammonium derivative 1 presented as a compact, lightweight, and flexible actuator for use in fields such as medical devices and industrial robots, is provided with a long and thin short flat ion- exchange resin formed part 2, and electrodes 3a and 3b mutually insulated from each other on the surface of the resin formed part 2. Then the resin formed part 2 is immersed in alkyl ammonium ionic solution, and by using potential difference between electrodes 3a, 3b, the resin formed part 2 becomes bent or deformed. One end of a pair of lead wires 4a, 4b is connected to electrodes 3a, 3b, respectively, and each lead wire 4a, 4b is connected to a power source 5.
摘要翻译：要解决的问题：为了制造不具有气穴并具有良好响应性的高聚合物致动器，通过将设置在表面上的金属电极的离子交换树脂形成部件浸渍在烷基铵离子溶液中，并通过在金属电极之间产生电位差塑胶件弯曲变形。解决方案：将高分子电解质铵衍生物1呈现为用于医疗器械和工业机器人领域的紧凑，重量轻且柔性的致动器，其具有形成第2部分的长而薄的短扁平离子交换树脂，电极 3a和3b在树脂形成部件2的表面上彼此相互绝缘。然后，将形成树脂的部件2浸渍在烷基铵离子溶液中，并且通过使用电极3a，3b之间的电位差，形成树脂的部件2变得弯曲或变形。一对引线4a，4b的一端分别连接到电极3a，3b，并且每个引线4a，4b连接到电源5。

3. 发明专利

JPS6172738A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172738A
公开(公告)日：1986-04-14
申请号：JP19548884
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C231/02 , C07C233/18 , C07C233/68 , G01N27/30
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 and R
2 are H, alkyl, aromatic hydrocarbon group or alkyl aromatic group, R
3 is alkyl, aromatic hydrocarbon group or alkyl aromatic group, n is 1W3).
EXAMPLE: 1,2-Bis[3-(n-octanoylamino)propoxy]-4-t-butylbenzene.
USE: A carrier for ion selective electrode. Especially when the campd. coexist with plasticizers and hydrophobic anions in a polymer membrane, they show selective electromotive response to specific cations depending on the composition of the membrane.
PREPARATION: A catechol derivative expressed by formula II and an acyl chloride are reacted in the presence of a tertiary amine, in an inert solvent at -20°CW room temp., to give the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I（R 1和R 2）表示为H，烷基，芳族烃基或烷基芳基，R 3为烷基，芳族烃基或烷基芳基，n为1-3）。实施例：1,2-双[3-（正辛酰基氨基）丙氧基] -4-叔丁基苯。用途：离子选择电极载体。特别是营地时。与聚合物膜中的增塑剂和疏水阴离子共存，它们根据膜的组成显示对特定阳离子的选择性电动反应。制备：将式II表示的儿茶酚衍生物和酰氯在叔胺的存在下，在惰性溶剂中，在-20℃ - 室温下反应，得到化合物。由公式I表示。

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