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    • 6. 发明专利
    • Preparation of electrically conductive stannic oxide
    • 电导电氧化锡的制备
    • JPS6110029A
    • 1986-01-17
    • JP12934284
    • 1984-06-25
    • Nippon Kagaku Sangyo Kk
    • NISHIYAMA HIROHOHAMAOKA AKIRATANAKA MINORUSAKATA TAKASHI
    • C01G19/02
    • PURPOSE: To obtain electrically conductive stannic oxide having excellent electrical conductivity and suitable as an antistatic agent for synthetic fiber, by dispersing antimony oxide in an aqueous solution of tartaric acid, mixing the dispersion with hydrated stannic oxide, and drying, pulverizing and calcining the mixture.
      CONSTITUTION: Antimony tartrate is produced by dispersing antimony oxide in an aqueous solution of tartaric acid. The amount of tartaric acid is ≥0.01 equivalent per 1 equivalent of antimony. Hydrated stannic oxide is added to the dispersion, mixed thoroughly with a ball mill, etc., dried in a hot-air circulation drier, etc., pulverized with an impact pulverizer, and calcined with a calcination oven to obtain the objective electrically conductive stannic oxide wherein a part of Sn atoms of stannic oxide are substituted with Sb atoms. A product having excellent electrical conductivity can be produced without using the water-washing step, even at a calcination temperature of as low as ≤1,000°C, and accordingly, the compound can be obtained at a low cost with simple procedure.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过将氧化锑分散在酒石酸水溶液中,将该分散体与水合氧化锡混合,并将该混合物干燥,粉碎和煅烧,得到导电性优良的导电性锡氧化物,适合用作合成纤维的抗静电剂 。 构成:酒石酸锑是通过将氧化锑分散在酒石酸水溶液中制得的。 酒石酸的量相当于每1当量锑> 0.01当量。 将水合氧化锡加入到分散体中,用球磨机等充分混合,在热风循环干燥器等中干燥,用冲击式粉碎机粉碎,并用煅烧炉煅烧,得到目标导电锡 氧化锡,其中一部分锡原子的氧化锡被Sb原子取代。 即使在低于<= 1000℃的煅烧温度下也可以不使用水洗步骤来制造具有优异的导电性的产品,因此可以以简单的方法以低成本获得化合物。