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    • 3. 发明专利
    • Catalyst for olefin polymerization and method of producing olefin polymer
    • 烯烃聚合催化剂和生产烯烃聚合物的方法
    • JP2010043152A
    • 2010-02-25
    • JP2008206681
    • 2008-08-11
    • Tosoh Corp東ソー株式会社
    • TANABIKI MASAOTOGO HIDEKAZUHAMURA SATOSHIMIYOSHI HIROYUKI
    • C08F4/6592C08F10/00
    • PROBLEM TO BE SOLVED: To provide a catalyst for olefin polymerization, capable of efficiently producing a high-molecular-weight component. SOLUTION: The catalyst for olefin polymerization comprises: component (A): a specific transition metal compound which has the structure in which a cyclopentadienyl group having a substituent at the 3-position and a fluorenyl group which may have a substituent are cross-linked and contains a titanium atom, a zirconium atom or a hafnium atom; component (B): a transition metal compound which has the structure in which two cyclopentadienyl groups of formula (2) which may have a substituent are cross-linked and contains a titanium atom, a zirconium atom or a hafnium atom; and component (C): an activation co-catalyst, as components. (In the formula, M 2 represents a titanium atom, a zirconium atom or a hafnium atom). COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供能够有效地制备高分子量组分的烯烃聚合催化剂。 解决方案:用于烯烃聚合的催化剂包括:组分(A):具有这样的结构的特定过渡金属化合物,其中在3位具有取代基的环戊二烯基和可具有取代基的芴基交叉 连接并含有钛原子,锆原子或铪原子; 组分(B):具有其中可以具有取代基的式(2)的两个环戊二烯基交联并含有钛原子,锆原子或铪原子的结构的过渡金属化合物; 和组分(C):作为组分的活化助催化剂。 (式中,M 2 表示钛原子,锆原子或铪原子)。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Method for synthesizing organic compound useful as ligand of transition metal compound
    • 合成有机化合物作为过渡金属化合物配体的方法
    • JP2005239689A
    • 2005-09-08
    • JP2004055361
    • 2004-02-27
    • Tosoh Corp東ソー株式会社
    • HAMURA SATOSHIHASEGAWA AYAKITANABIKI MASAOYANO AKIHIRO
    • C07C2/34C07C13/15C07C13/465C07C13/567C07C13/66C07C17/266C07C23/34C07F1/02
    • PROBLEM TO BE SOLVED: To synthesize easily an organic compound becoming a ligand of a cross-linked type transition metal compound useful as an olefin polymerization catalyst.
      SOLUTION: This method for synthesizing the organic compound expressed as (C), as shown by reaction formula (1) [wherein, Cp
      1 is cyclopentadienyl, indenyl, fluorenyl or such groups having a substituting group; R
      1 s are independently the same or different and are each H, or a 1-30C hydrocarbon or a hydrocarbon including a hetero atom; Z is H or a leaving group; M is a metal component derived from the organometallic compound; Cp
      1' is the same as the Cp
      1 or a group in which the part of Cp
      1 is metallized by the organometallic compound; and X is a halogen atom or a leaving group] is provided by performing the reaction of (A) a compound with an organometallic compound to convert them into (B) a reaction intermediate, then reacting it with a compound expressed by Cp
      2 -X [Cp
      2 is cyclopentadienyl, indenyl, fluorenyl or such groups having a substituent].
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:容易地合成成为可用作烯烃聚合催化剂的交联型过渡金属化合物的配体的有机化合物。 解决方案:如反应式(1)所示,合成表示为(C)的有机化合物的方法[其中,Cp 1 是环戊二烯基,茚基,芴基或具有取代基 组; R 1彼此独立地相同或不同,各自为H或1-30C烃或包含杂原子的烃; Z是H或离去基团; M是衍生自有机金属化合物的金属成分; Cp 1'与Cp 1 相同或其中部分Cp 1 由有机金属化合物金属化的基团; 并且X是卤素原子或离去基团]是通过(A)化合物与有机金属化合物的反应将其转化成(B)反应中间体,然后使其与由Cp 2 [SP SP 2]是环戊二烯基,茚基,芴基或具有取代基的这些基团。 版权所有(C)2005,JPO&NCIPI
    • 5. 发明专利
    • 透明導電膜用塗工液及びこれを用いた透明導電膜
    • 透明导电薄膜和透明导电薄膜
    • JP2015003942A
    • 2015-01-08
    • JP2013128194
    • 2013-06-19
    • 東ソー株式会社Tosoh Corp
    • YAMAMOTO ARINORIHAMURA SATOSHI
    • C09D201/00B05D5/12B32B9/00B32B27/00C08J7/04C09D5/24C09D7/12C09D165/00C09D179/04G06F3/041H01B1/00H01B1/20H01B5/14
    • 【課題】高い微粒子分散性と、塗工に適した粘性を有する透明導電膜用塗工液、及びこれを製膜、乾燥して製造される、膜中の空隙率が低く、高透明、高導電性を発現する透明導電膜を提供する。【解決手段】溶媒中に、0.1〜50重量%の(a)成分及び0.001〜5重量%の(b)成分を含有することを特徴とする透明導電膜用塗工液。(a)透過型電子顕微鏡により測定される平均粒子径が3〜60nmであり、かつ粒子表面に、微粒子全体の重量の0.5〜10重量%の有機配位子が配位している、ITO微粒子。(b)構造単位中に、酸素、窒素、硫黄のいずれか1つ以上を含有する、重量平均分子量が10,000〜200,000の高分子化合物であり、かつ該高分子化合物を膜とした際に、シート抵抗が1?107&OHgr;/□以下である導電性高分子。【選択図】なし
    • 要解决的问题:提供具有高细颗粒分散性和适于涂布的粘度的透明导电膜涂布液,并且提供具有低膜空隙率并表现出高透明度和高导电性的透明导电膜 通过制膜和干燥来制造。本发明提供一种透明导电膜涂布液,其特征在于,在溶剂中含有(a)成分为0.1〜50重量%,(b)成分为0.001〜5重量% 。%。 (a)是通过透射电子显微镜测定的平均粒径为3〜60nm的ITO细颗粒,并且在颗粒表面上的有机配体的量为微粒总重量的0.5〜10重量% 协调一致 (b)是在结构单元中含有氧,氮或硫中的任意一种以上的重均分子量为10,000〜200,000的高分子化合物,并且是将高分子化合物成膜时的导电性高分子, 表面电阻为1×10&OHgr / sq。 或更少。
    • 6. 发明专利
    • Coating liquid for solvent resistance transparent conductive film, and solvent resistance transparent conductive film comprising the same
    • 用于耐溶剂透明导电膜的溶剂液体和包含其的耐溶剂透明导电膜
    • JP2014032799A
    • 2014-02-20
    • JP2012171790
    • 2012-08-02
    • Tosoh Corp東ソー株式会社
    • YAMAMOTO ARINORIHAMURA SATOSHIDOI TORUOBARA NAOTO
    • H01B1/20C01G19/00C09D1/00C09D5/24H01B1/00H01B5/14
    • PROBLEM TO BE SOLVED: To provide a coating liquid for a solvent resistance transparent conductive film that comprises a fluid dispersion that includes a crystallinity tin inclusion indium oxide fine particle and that is excellent in dispersion stability, and to provide the transparent conductive film that is excellent in an electric characteristic, an optic characteristic, and solvent resistance by coating the coating liquid for a solvent resistance transparent conductive film.SOLUTION: A coating liquid for a solvent resistance transparent conductive film is a fluid dispersion that includes 0.1-100 pts.wt. of a crystallinity tin inclusion indium oxide fine particle having characteristics shown by at least the following (a)-(d) based on 100 pts.wt. of a dispersion solvent. (a) A cubic system bixbyite structure is possessed, (b) tin/indium (molar ratio) measured by an inductive coupling plasma emission spectral analysis apparatus (ICP)=5/95-40/60 of a range, (c) an average particle diameter measured by a transmission electron microscope is in a range of 5-20 nm, and (d) 1-10 wt.% of an amine ligand having a carbon number of 6-24 is coordinated.
    • 要解决的问题:提供一种耐溶剂性透明导电膜的涂布液,其包含含有结晶性锡夹杂物氧化铟微粒并且分散稳定性优异的流体分散体,并且提供优异的透明导电膜 具有电特性,光学特性和耐溶剂性,通过涂布耐溶剂性透明导电膜的涂布液。溶剂:用于耐溶剂性透明导电膜的涂布液是包含0.1-100重量份的流体分散体。 具有至少以下(a) - (d)所示的特性的结晶性锡夹杂物氧化铟微粒,基于100重量份。 的分散溶剂。 (a)具有立方体系双峰结构,(b)通过感应耦合等离子体发射光谱分析装置(ICP)= 5 / 95-40 / 60测量的锡/铟(摩尔比),(c) 通过透射电子显微镜测定的平均粒径在5-20nm的范围内,(d)1-10重量%的碳数为6〜24的胺配位体配位。
    • 8. 发明专利
    • Vinyl chloride polymer and method for producing the same
    • 乙烯基氯化聚合物及其制备方法
    • JP2013057024A
    • 2013-03-28
    • JP2011196905
    • 2011-09-09
    • Tosoh Corp東ソー株式会社
    • SAKAGUCHI KOTAHAMURA SATOSHIYAMADA SATORU
    • C08F293/00C08F8/34
    • PROBLEM TO BE SOLVED: To provide a vinyl chloride polymer which has high thermal stability without diminishing heat resistance, and a method for producing the same.SOLUTION: In the vinyl chloride polymer, a vinyl acetate polymer segment B and a terminal C represented by general formula (1) are bonded to a vinyl chloride polymer segment A in the sequence of A-B-C. The content of the vinyl acetate polymer segment B is more than 0 wt.% and not more than 5 wt.% based on the vinyl chloride polymer segment A. In formula, Z is a substitute selected from the group consisting of an organic group selected from a 1-20C alkoxy group, alkylsulfanyl group, arylsulfanyl group, alkyl group, and aryl group.
    • 待解决的问题:提供一种具有高热稳定性而不降低耐热性的氯乙烯聚合物及其制备方法。 解决方案:在氯乙烯聚合物中,将乙酸乙烯酯聚合物链段B和由通式(1)表示的末端C以A-B-C的顺序结合到氯乙烯聚合物链段A上。 乙酸乙烯酯聚合物链段B的含量相对于氯乙烯聚合物链段A大于0重量%且不大于5重量%。在式中,Z是选自以下的取代基:选自 由1-20C烷氧基,烷基硫烷基,芳基硫烷基,烷基和芳基组成。 版权所有(C)2013,JPO&INPIT