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1. 发明专利

JP2015056490A キャパシタ用セパレータの製造方法及びキャパシタ用セパレータ审中-公开
标题翻译：电容器分离器和电容器分离器的制造方法
公开(公告)号：JP2015056490A
公开(公告)日：2015-03-23
申请号：JP2013188440
申请日：2013-09-11
申请人：三菱製紙株式会社 , Mitsubishi Paper Mills Ltd
发明人： SHIGEMATSU TOSHIHIRO , HIROTA NOBUAKI
IPC分类号： H01G9/00 , H01G9/02 , H01G11/52 , H01G11/84
CPC分类号： Y02E60/13
摘要：【課題】表面強度が強いキャパシタ用セパレータの製造方法と、その製造方法によって製造されるキャパシタ用セパレータを提供することにある。【解決手段】叩解されてなるセルロース繊維と合成繊維とを含有してなり、湿式抄造法により湿式繊維ウェブを形成するキャパシタ用セパレータの製造方法において、湿式繊維ウェブを乾燥して得られた乾燥繊維ウェブを水で再湿潤させ、金属ヒートロールに支持体で押し付けながら再乾燥することを特徴とするキャパシタ用セパレータの製造方法と該製造方法によって製造されるキャパシタ用セパレータ。【選択図】なし
摘要翻译：要解决的问题：提供一种具有强表面强度的电容器用隔膜的制造方法，以及提供通过制造方法制造的电容器用隔膜。本发明公开了一种电容器用隔膜的制造方法，含有捣碎的纤维素纤维和合成纤维，并通过湿造纸法形成湿纤维网。电容器用隔膜的制造方法的特征在于，将通过干燥湿纤维网而获得的干燥纤维网用水再次润湿，并在使用支撑体压制成金属热辊的同时再次干燥。通过该制造方法制造电容器用隔膜。

2. 发明专利

JP2014179249A Separator for alkali batteries 审中-公开
标题翻译： ALKALI电池分离器
公开(公告)号：JP2014179249A
公开(公告)日：2014-09-25
申请号：JP2013052726
申请日：2013-03-15
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： OYAMA KEISUKE , SHIGEMATSU TOSHIHIRO , HIROTA NOBUAKI
IPC分类号： H01M2/16 , D04H1/4291 , D06M10/02 , D06M14/10
摘要： PROBLEM TO BE SOLVED: To provide a separator for alkali batteries which is made of wet type nonwoven fabric, and which is superior in the uniformity of air permeability, large in tensile strength, and high in liquid retentivity, hard to cause a short circuit, and high in heat seal bonding strength.SOLUTION: A separator for alkali batteries comprises a wet type nonwoven fabric which includes polyolefin fiber having an average fiber diameter of 5.0-8.0 μm, exclusive of 5.0 μm, and polyolefin fiber having an average fiber diameter of 8.0-13.0 μm, exclusive of 8.0 μm.
摘要翻译：要解决的问题：为了提供一种由湿式无纺布制成的碱性电池用隔膜，其透气性均匀性，拉伸强度大，液体保持性高，难以引起短路，热封接合强度高。解决方案：碱性电池用隔膜包括湿式无纺布，其包含平均纤维直径为5.0-8.0μm，不含5.0μm的聚烯烃纤维，平均纤维直径为 8.0-13.0μm，不含8.0μm。

3. 发明专利

JP2014173200A Method for manufacturing nonwoven fabric, nonwoven fabric and separator for battery 审中-公开
标题翻译：制造非织造布，非织造布和电池分离器的方法
公开(公告)号：JP2014173200A
公开(公告)日：2014-09-22
申请号：JP2013045112
申请日：2013-03-07
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： SHIGEMATSU TOSHIHIRO , KAMATA YOSUKE , SAEGUSA HIDEAKI
IPC分类号： D21F5/02 , D21H13/14 , H01M2/16
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a nonwoven fabric containing polyolefin based fibers, which is capable of securing papermaking stability when a fiber web is formed by a wet papermaking method, preventing winding slippage and winding wrinkles, holding a good thickness profile in a width direction, and having strength and a low density, and to provide a separator for a battery including the nonwoven fabric manufactured by the method for manufacturing a nonwoven fabric, which is excellent in liquid-retention properties with a long life.SOLUTION: There is provided a method for manufacturing a nonwoven fabric containing at least polyolefin based fibers, in which a fiber web formed by a wet papermaking method is press bonded on a Yankee dryer with a touch roll having a clearance adjusting jack attached thereto for adjusting a gap with the Yankee dryer, and a thickness profile in a width direction is controlled by cooling the position of a part of the touch roll necessary for a thickness adjustment with air using air nozzles arranged in a width direction on an upper part of the touch roll while adjusting air quantity according to the thickness profile in the width direction continuously measured. The air nozzles are of a flat type. There is provided a nonwoven fabric obtained by manufacturing a nonwoven fabric by the method for manufacturing a nonwoven fabric. There is provided a separator for a battery obtained by subjecting the nonwoven fabric to a sulfonation treatment for hydrophilization.
摘要翻译：要解决的问题：提供一种含有聚烯烃类纤维的无纺布的制造方法，其能够通过湿法造纸法形成纤维网时能够确保造纸的稳定性，防止卷绕滑动和卷绕褶皱，保持良好的厚度分布在宽度方向上具有强度和低密度，并且提供一种电池用隔膜，该电池用隔膜包括由无纺布制造方法制造的无纺布，其具有优异的保液性，寿命长。提供一种制造至少含有聚烯烃类纤维的无纺布的方法，其中将通过湿法造纸方法形成的纤维网被压接在扬克式干燥器上，其中具有附接有间隙调节千斤顶的接触辊用于调整间隙通过扬基烘缸，通过冷却接触辊的一部分的位置来控制宽度方向的厚度分布根据连续测量的宽度方向的厚度分布，调节空气量，根据接触辊的上部沿宽度方向布置的空气喷嘴进行厚度调节。空气喷嘴为平面型。提供了一种通过该无纺织物的制造方法制造无纺布而获得的无纺布。提供了一种通过使无纺布进行磺化处理以进行亲水化而获得的电池用隔膜。

4. 发明专利

JP2013175392A Manufacturing method of lithium ion secondary battery separators, lithium ion secondary battery separator and lithium ion secondary battery 审中-公开
标题翻译：锂离子二次电池分离器，锂离子二次电池分离器和锂离子二次电池的制造方法
公开(公告)号：JP2013175392A
公开(公告)日：2013-09-05
申请号：JP2012039879
申请日：2012-02-27
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： SHIGEMATSU TOSHIHIRO , KAWASAKI KATSUHIKO
IPC分类号： H01M2/16
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of lithium ion secondary battery separators for efficiently manufacturing short fiber-blended separators and obtaining lithium ion secondary battery separators with high mechanical strength as well as low incidence of internal short circuit failure, and also to provide a lithium ion secondary battery separator manufactured by the manufacturing method and a lithium ion secondary battery comprising the lithium ion secondary battery separator.SOLUTION: Provided is a manufacturing method of lithium ion secondary battery separators for producing a lithium ion secondary battery separator by wet papermaking in which the separator is formed by multiply papermaking with the use of a combination of at least two or more paper machines and by using a suction pickup roll, as a pickup roll, for second and subsequent plies. The invention also provides a lithium ion secondary battery separator manufactured by the manufacturing method and a lithium ion secondary battery comprising the lithium ion secondary battery separator.
摘要翻译：要解决的问题：提供一种锂离子二次电池隔板的制造方法，用于有效地制造短纤维混合隔板并获得具有高机械强度和低内部短路故障发生率的锂离子二次电池隔板，并且还提供由该制造方法制造的锂离子二次电池隔板和包含锂离子二次电池隔板的锂离子二次电池。本发明提供一种锂离子二次电池隔板的制造方法，所述锂离子二次电池隔板通过湿式造纸制造锂离子二次电池隔板其中分离器通过使用至少两台或多台造纸机的组合的多次造纸和通过使用抽吸拾取辊作为拾取辊而形成用于第二层和随后的层。本发明还提供一种由该制造方法制造的锂离子二次电池隔板和包含锂离子二次电池隔板的锂离子二次电池。

5. 发明专利

JP2005322615A Separator for battery 审中-公开
标题翻译：电池分离器
公开(公告)号：JP2005322615A
公开(公告)日：2005-11-17
申请号：JP2005028836
申请日：2005-02-04
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： SHIGEMATSU TOSHIHIRO , TANABE KUNIHIRO , MAEDA SHIGEHIRO , ESUMI SHINICHI
IPC分类号： H01M2/16
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a separator for a battery, having superior hydrophilic properties, alkali resistance properties, anti-oxidation properties, superior thermal resistance properties, having high capacity, superior output characteristics and life time characteristics, with which the yield of battery manufacturing becomes high. SOLUTION: The separator for the battery consists of non-woven fabric, containing half-aromatic polyamide fiber with superior oxidation resistance properties, which is synthesized from dicarboxylic acid component, consisting of 60 mol% or higher aromatic carboxylic acid component and diamine component consisting of 6-12C 60 mol% or higher aliphatic alkylene diamine, and containing polyparaphenylene benzobis oxazole fiber having high mechanical strength. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种电池用隔膜，具有优异的亲水性，耐碱性，抗氧化性，优异的耐热性，具有高容量，优异的输出特性和寿命特性，电池制造成品率高。解决方案：电池用隔膜由含有60摩尔％以上的芳香族羧酸成分和二胺的二羧酸成分合成的具有优异抗氧化性的半芳香族聚酰胺纤维的无纺布构成由6-12℃60摩尔％以上脂肪族亚烷基二胺构成的成分，含有机械强度高的聚对亚苯基苯并双恶唑纤维。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2004319261A Separator for battery 审中-公开
公开(公告)号：JP2004319261A
公开(公告)日：2004-11-11
申请号：JP2003111574
申请日：2003-04-16
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： SHIGEMATSU TOSHIHIRO , AIZAWA WAKANA
IPC分类号： H01M2/16
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a separator for a battery with a superior hydrophilicity, alkali resistance, oxidation deterioration resistance, and heat resistance and high in yield during manufacturing the battery.
SOLUTION: In the separator for the battery made of a multilayered nonwoven fabric composed of more than two layers of nonwoven fabric layers, at least one layer among the nonwoven fabric layers is a wet-type nonwoven fabric layer containing a semi-aromatic polyamide fiber synthesized from a dicarboxylic acid component in which not less than 60 mol% of the dicarboxylic acid component is an aromatic carboxylic acid component, and a diamine component in which not less than 60 mol% of the diamine component is a 6-12C aliphatic alkylene diamine. The other layer is a spun bonded dry-type nonwoven fabric layer of fiber diameters of 3-30 μm containing a semi-aromatic polyamide fiber synthesized from a dicarboxylic acid component in which not less than 60 mol% of the dicarboxylic acid component is an aromatic carboxylic acid component, and a diamine component in which not less than 60 mol% of the diamine component is a 6-12C aliphatic alkylene diamine.
COPYRIGHT: (C)2005,JPO&NCIPI

7. 发明专利

JP2015041551A 電池セパレータ用不織布审中-公开
标题翻译：非电动电瓶分离器
公开(公告)号：JP2015041551A
公开(公告)日：2015-03-02
申请号：JP2013172784
申请日：2013-08-23
申请人：三菱製紙株式会社 , Mitsubishi Paper Mills Ltd
发明人： SHIGEMATSU TOSHIHIRO , OYAMA KEISUKE
IPC分类号： H01M2/16 , D21H13/14
摘要：【課題】低坪量にも拘わらず、電池構成機での群巻回作業時における耐リーク性に優れた電池セパレータ用不織布を提供することにある。【解決手段】ポリオレフィン系芯鞘型複合繊維のみを含有し、湿式抄造法によりウェブ形成され、水流交絡処理を施さずに、スルホン化処理された電池セパレータ用不織布において、該ポリオレフィン系芯鞘型複合繊維のアスペクト比(繊維長/繊維径)が450〜1300であり、繊維径が7.5〜13.0μmであり、乾強度が3.0〜4.4cN/dtexであることを特徴とする電池セパレータ用不織布。【選択図】なし
摘要翻译：要解决的问题：提供一种用于电池隔膜的非织造布，其在使用电池配置机的组缠绕工作期间的耐漏出性优异，尽管重量不足。解决方案：在仅含有聚烯烃的芯的电池隔板用无纺布中 - 通过湿法造纸方法形成的网，经过磺化而不进行水流交联，聚烯烃类芯鞘复合纤维（纤维长度/纤维直径）的纵横比为450-1300，纤维直径为7.5-13.0μm，干强度为3.0-4.4cN / dtex。

8. 发明专利

JP2014186857A Separator base material for lithium ion secondary batteries, and separator for lithium ion secondary batteries 审中-公开
标题翻译：用于锂离子二次电池的分离器基材和锂离子二次电池的分离器
公开(公告)号：JP2014186857A
公开(公告)日：2014-10-02
申请号：JP2013060642
申请日：2013-03-22
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： MATSUDA NORIYUKI , SATO TOMOHIRO , SHIGEMATSU TOSHIHIRO
IPC分类号： H01M2/16 , D04H1/55 , D21H13/24 , D21H19/10 , D21H19/36
摘要： PROBLEM TO BE SOLVED: To provide a separator base material for lithium secondary batteries for making a separator for lithium ion secondary batteries by applying a coating-use slurry including filler particles and a resin, which achieves excellent coating suitability because it is hard to cause a coating defect such as a coating streak in coating, but it achieves good coverage with a coating-use slurry, and to provide a separator for lithium ion secondary batteries which is arranged by use of such a separator base material for lithium secondary batteries, and is low in percentage of defective owing to internal short circuit.SOLUTION: A separator base material for lithium ion secondary batteries is composed of a nonwoven fabric base material. The nonwoven fabric base material comprises polyester-based short fiber. The main fiber forming the nonwoven fabric base material has an average fiber diameter of 5.7-7.1 μm. A separator for lithium secondary batteries is arranged by performing at least one combined step selected from the steps of: coating the separator base material for lithium ion secondary batteries with a coating-use slurry including filler particles; coating the separator base material with a coating-use slurry including a resin; and coating the separator base material with a coating-use slurry including solid electrolyte or gel electrolyte.
摘要翻译：要解决的问题：提供一种用于制备锂离子二次电池用隔膜的锂二次电池用隔膜基材，其通过涂布包含填料粒子和树脂的涂布用浆料，由于难以引起涂布适应性，涂布等涂布缺陷，但是涂覆用浆料达到良好的覆盖率，并且提供了使用这种锂二次电池用隔板基材配置的锂离子二次电池用隔膜，并且是由于内部短路导致的缺陷百分比低。解决方案：锂离子二次电池用隔板基材由无纺布基材构成。无纺布基材包含聚酯类短纤维。形成无纺布基材的主纤维的平均纤维直径为5.7-7.1μm。通过进行至少一个组合步骤来设置用于锂二次电池的隔板，所述组合步骤选自以下步骤：用包含填料颗粒的涂布用浆料涂覆锂离子二次电池用隔膜基材; 用包括树脂的涂布用浆料涂覆隔板基材; 并用包含固体电解质或凝胶电解质的涂布用浆料涂布隔板基材。

9. 发明专利

JP2014022094A Separator for lithium ion battery 审中-公开
标题翻译：锂离子电池分离器
公开(公告)号：JP2014022094A
公开(公告)日：2014-02-03
申请号：JP2012157296
申请日：2012-07-13
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： KATO MAKOTO , WATANABE HIROAKI , KATO TAKAHISA , KAJI HIROO , SHIGEMATSU TOSHIHIRO , TSUKUDA TAKAHIRO
IPC分类号： H01M2/16
摘要： PROBLEM TO BE SOLVED: To provide a separator for a lithium ion battery using no organic solvent in forming a sheet, extremely high in heat resistance, causing no contamination of a coating device due to strike-through of a coating liquid in production thereof, and extremely low in internal resistance.SOLUTION: In a separator for a lithium ion battery, a coating layer including an inorganic pigment is arranged in a B layer of a nonwoven fabric base material which mainly comprises thermoplastic fibers and is obtained by laminating a layer (A layer) including no fibrillated fiber and the layer (B layer) including fibrillated aromatic fibers.
摘要翻译：要解决的问题：为了提供一种在形成片材时不使用有机溶剂的锂离子电池用隔膜，耐热性极高，在其制造中不会引起涂布液的渗透而污染涂布装置，内阻极低。解决方案：在锂离子电池用隔膜中，将包含无机颜料的被覆层配置在主要包含热塑性纤维的无纺布基材的B层中，通过层叠（A 层），不包括原纤化纤维和包含原纤化芳族纤维的层（B层）。

10. 发明专利

JP2014013692A Base material for lithium ion secondary battery separator, and lithium ion secondary battery separator 有权
标题翻译：锂离子二次电池分离器和锂离子二次电池分离器的基材
公开(公告)号：JP2014013692A
公开(公告)日：2014-01-23
申请号：JP2012150591
申请日：2012-07-04
申请人： Mitsubishi Paper Mills Ltd , 三菱製紙株式会社
发明人： KAJI HIROO , SHIGEMATSU TOSHIHIRO , TSUKUDA TAKAHIRO , WATANABE HIROAKI , SATO TOMOHIRO , KATO MAKOTO , MASUDA TAKAO , TAKAHAMA NOBUKO
IPC分类号： H01M2/16
摘要： PROBLEM TO BE SOLVED: To provide a base material for a lithium ion secondary battery separator high in processability, strength, uniformity, and post-process handleability when a coating layer containing inorganic particles is formed on an unwoven fabric surface.SOLUTION: A base material for a lithium ion secondary battery separator includes a coating layer containing inorganic particles on at least one surface of an unwoven fabric made of synthetic resin short fibers. The average fiber diameter of the entire unwoven fabric made of the synthetic resin short fibers is equal to or less than 5.5 μm, the average fiber diameter of fibers constituting the surface of one surface of the unwoven fabric and the average fiber diameter of fibers constituting the surface of an opposite surface are different from each other, and the ratio R=D(W)/D(T) of the average fiber diameter D(W) of the surface having a large average fiber diameter with the average fiber diameter D(T) of the surface having a small average fiber diameter is equal to or higher than 1.10, more preferably, 1.30 to 2.50. Preferably, the base material for the lithium ion secondary battery separator includes synthetic resin short fibers each having a length of 1 mm or lower.
摘要翻译：要解决的问题：当在无纺布表面上形成含有无机颗粒的涂层时，提供高加工性，强度，均匀性和后处理操作性的锂离子二次电池用隔板的基材。解决方案：基材对于锂离子二次电池隔板，包括在由合成树脂短纤维制成的无纺布的至少一个表面上含有无机颗粒的涂层。由合成树脂短纤维制成的整个无纺布的平均纤维直径等于或小于5.5μm，构成无纺织物一个表面表面的纤维的平均纤维直径和构成织物的纤维的平均纤维直径相对表面的表面彼此不同，平均纤维直径D的平均纤维直径D（W）的平均纤维直径D（W）的平均纤维直径D（W）的比R = D（W）/ D（T）具有小平均纤维直径的表面的T）等于或高于1.10，更优选为1.30至2.50。优选地，用于锂离子二次电池隔板的基材包括长度为1mm以下的合成树脂短纤维。

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