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1. 发明专利

JP2011140606A Phosphoric acid residue-containing (meth)acrylic amide-containing composition, phosphoric acid residue-containing vinyl polymer-containing composition, method for producing the same, and application of the same 有权
标题翻译：含有甲酸的含丙烯酸酰胺的组合物，含磷酸酯残留的含乙烯基聚合物的组合物，其制备方法及其应用
公开(公告)号：JP2011140606A
公开(公告)日：2011-07-21
申请号：JP2010003417
申请日：2010-01-08
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO
IPC分类号： C08L43/02 , C07F9/24 , C08F230/02 , C08K5/17 , C08K5/19 , C08K5/3445 , H01B3/44
摘要： PROBLEM TO BE SOLVED: To provide a phosphoric acid residue-containing vinyl polymer-containing composition excellent in flame retardancy, insulation property, and transparency; a phosphoric acid residue-containing (meth)acrylic amide-containing composition as a raw material for the phosphoric acid residue-containing vinyl polymer containing composition; and a method for producing the polymer containing composition and its application. SOLUTION: The phosphoric acid residue-containing (meth)acrylic amide-containing composition comprising a (meth)acrylic amide having a (poly)sulfonic acid group and/or a phosphonic acid group consisting of a (poly)phosphoric acid group and a nitrogen-containing surfactant is excellently compatible with another ethylenically unsaturated coupling-containing compound, to provide a transparent mixture. The phosphoric acid residue-containing vinyl polymer-containing composition, which is prepared by reacting the phosphoric acid residue-containing (meth)acrylic amide the mixture with the other ethylenically unsaturated coupling-containing compound, has excellent flame retardancy and transparency. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的阻燃性，绝缘性和透明性的含磷酸残基的含乙烯基聚合物的组合物。含磷酸残基（甲基）丙烯酰胺的组合物作为含磷酸残基的含乙烯基聚合物的组合物的原料; 以及含有聚合物的组合物的制造方法及其应用。解决方案：含磷酸残基（甲基）丙烯酰胺的组合物包含具有（聚）磺酸基的（甲基）丙烯酰胺和/或由（聚）磷酸基组成的膦酸基并且含氮表面活性剂与另一种含烯属不饱和键合的化合物非常相容，以提供透明的混合物。含有磷酸残基的含乙烯基聚合物的组合物通过使含磷酸残基的（甲基）丙烯酰胺与其它含有烯属不饱和键合的化合物反应而制备，具有优异的阻燃性和透明性。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2008202058A Solid polymer electrolyte membrane, raw material monomer composition for the same, and fuel cell 有权
标题翻译：固体聚合物电解质膜，其原料单体组合物和燃料电池
公开(公告)号：JP2008202058A
公开(公告)日：2008-09-04
申请号：JP2008121635
申请日：2008-05-07
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： C08F230/02 , C08F220/24 , C08F220/34 , C08J5/22 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide an inexpensive solid polymer electrolyte membrane which has high proton conductivity in a wide temperature range and has excellent solvent resistance, and a raw material monomer composition for the solid polymer electrolyte membrane, and to provide a manufacturing method and used of the solid polymer electrolyte membrane. SOLUTION: The solid polymer electrolyte membrane is prepared by copolymerization of (A) a monomer composition and (B) a fluorine group-containing unsaturated monomer (c), wherein (A) the monomer composition is prepared by reaction of a phosphate group-containing unsaturated monomer (a) having a phosphate group and an ethylenically unsaturated bond in a molecule and an amino group-containing unsaturated monomer (b) having a substituted or unsubstituted amino group and an ethylenically unsaturated bond in a molecule so that the rate of the amino group of (b) to the phosphate group of (a) ranges from 50 to 180 mol%, and includes a quaternary ammonium salt in which (a) is denatured with (b). COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方案：提供一种在宽温度范围内具有高质子传导性和耐溶剂性优异的廉价的固体高分子电解质膜和用于固体高分子电解质膜的原料单体组合物，并提供制造方法并使用固体高分子电解质膜。解决方案：固体聚合物电解质膜通过（A）单体组合物和（B）含氟基的不饱和单体（c）的共聚制备，其中（A）单体组合物通过磷酸酯在分子中具有磷酸基和烯键式不饱和键的含有不饱和基团的不饱和单体（a）和分子中具有取代或未取代的氨基和烯属不饱和键的含氨基的不饱和单体（b）（b）的氨基与（a）的磷酸酯基的比例为50〜180摩尔％，并且包括（a）变性为（b）的季铵盐。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2007016205A Electroconductive polymer obtained by copolymerizing phosphate group-containing unsaturated monomer and unsaturated liquid oligomer, solid polyelectrolyte membrane and use thereof, method for producing phosphate group-containing unsaturated monomer and flame retarfant using phosphate group-containing unsaturated monomer and method for producing the same 有权
标题翻译：通过使含磷酸酯基的不饱和单体和不饱和液体低聚物，固体聚电解质膜共聚获得的电极聚合物及其用途，使用含磷酸酯基的不饱和单体生产含磷酸酯基的不饱和单体和阻燃剂的方法及其制备方法
公开(公告)号：JP2007016205A
公开(公告)日：2007-01-25
申请号：JP2006075345
申请日：2006-03-17
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO
IPC分类号： C08F290/04 , C08F220/00 , C09K21/14 , H01B1/06 , H01B1/12 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a relatively inexpensively producible polymer having excellent solvent and water resistances and high electroconductivity and to provide uses thereof. SOLUTION: The polymer is obtained by copolymerizing at least (a) a phosphate group-containing unsaturated monomer having an oxybutyl or a polyoxybutyl skeleton with (b) a liquid oligomer having at least one ethylenically unsaturated bond in the molecule. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的溶剂和耐水性和高导电性的相对便宜的可生产的聚合物并提供其用途。解决方案：聚合物通过至少（a）具有氧基丁基或聚氧丁基骨架的含磷酸根的不饱和单体与（b）分子中具有至少一个烯键式不饱和键的液体低聚物共聚而获得。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2006160890A Solid polymer electrolyte membrane using unsaturated alcohol-based copolymer phosphate and its use, and method for producing unsaturated alcohol-based copolymer phosphate 有权
标题翻译：使用不饱和醇基的共聚物磷酸酯及其用途的固体聚合物电解质膜及其制备基于不饱和醇的共聚物磷酸酯的方法
公开(公告)号：JP2006160890A
公开(公告)日：2006-06-22
申请号：JP2004354554
申请日：2004-12-07
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO
IPC分类号： C08F8/40 , C08L29/02 , C08L101/00 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide an inexpensive solid polymer electrolyte membrane which has proton conductivity, water resistance and solvent resistance in a good balance. SOLUTION: This solid polymer electrolyte membrane comprises a vinyl polymer prepared by forming the phosphate ester of an unsaturated alcohol-based copolymer containing fatty acid vinyl units, or comprises the vinyl polymer phosphate ester and any other conductive resin and/or a non-conductive resin. The solid polymer electrolyte membrane has conductivity, water resistance and solvent resistance in a good balance. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种廉价的固体高分子电解质膜，其具有质子传导性，耐水性和耐溶剂性。解决方案：该固体聚合物电解质膜包括通过形成含有脂肪酸乙烯基单元的不饱和醇基共聚物的磷酸酯而制备的乙烯基聚合物，或包含乙烯基聚合物磷酸酯和任何其它导电树脂和/ 导电树脂。固体高分子电解质膜具有良好的导电性，耐水性和耐溶剂性。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2006049225A Solid polymer electrolyte film and solid polymer fuel cell 审中-公开
标题翻译：固体聚合物电解质膜和固体聚合物燃料电池
公开(公告)号：JP2006049225A
公开(公告)日：2006-02-16
申请号：JP2004231592
申请日：2004-08-06
申请人： Canon Inc , Uni-Chemical Co Ltd , キヤノン株式会社 , ユニケミカル株式会社
发明人： KOBAYASHI MOTOKAZU , ERITATE SHINJI , KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： H01M8/02 , C08F290/00 , H01B1/06 , H01M8/10
CPC分类号： B01D71/40 , B01D71/44 , B01D71/54 , B01D71/80 , B01D71/82 , C08F230/02 , C08J5/2231 , C08J2343/02 , C08L75/16 , H01B1/122 , H01M8/1011 , H01M8/1023 , H01M8/1072 , Y02E60/523 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte film attaining both proton conductivity and strength of a polymer electrolyte film having phosphate, and a fuel cell using the same.
SOLUTION: The solid polymer electrolyte film contains copolymer formed by polymerizing phosphorus atom-containing unsaturated monomer having one or more of phosphor atom and one or more of ethylenic unsaturated bond; and monomer or pre-polymer of average molecular weight in number of not less than 2,000. The phosphorus atom-containing unsaturated monomer having one or more of phosphorus atoms and one or more of ethylenic unsaturated bonds in a molecule is composed of a compound expressed in general formula (1) (in the formula, R1 denotes hydrogen atom or an alkyl group, R2 denotes hydrogen atom or a substituted or non-substituted alkyl group, and n denotes an integer of 1 to 6.).
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有质子传导性和具有磷酸盐的聚合物电解质膜的强度的固体聚合物电解质膜和使用其的燃料电池。解决方案：固体聚合物电解质膜包含通过聚合具有一个或多个磷原子和一个或多个烯属不饱和键的含磷原子的不饱和单体形成的共聚物; 和平均分子量为不小于2,000的单体或预聚物。在分子中具有一个或多个磷原子和一个或多个烯属不饱和键的含磷原子的不饱和单体由通式（1）表示的化合物（式中，R1表示氢原子或烷基），R2表示氢原子或取代或未取代的烷基，n表示1〜6的整数。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2006049003A Solid polymer electrolyte, its manufacturing method, and solid polymer fuel cell 审中-公开
标题翻译：固体聚合物电解质，其制造方法和固体聚合物燃料电池
公开(公告)号：JP2006049003A
公开(公告)日：2006-02-16
申请号：JP2004225870
申请日：2004-08-02
申请人： Canon Inc , Uni-Chemical Co Ltd , キヤノン株式会社 , ユニケミカル株式会社
发明人： ERITATE SHINJI , KOBAYASHI MOTOKAZU , KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： H01M8/02 , C08F230/02 , H01B1/06 , H01B13/00 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte that is inexpensive and excellent in oxidation resistance and durability. SOLUTION: This solid polymer electrolyte contains a copolymer of one or more kinds of monomer selected from α-methyl styrene phosphonic acid, styrene phosphonic acid, α-methyl styrene alkyl phosphonic acid, and styrene alkyl phosphonic acid, and (meta) acrylic ester expressed by the general formula (A) (in the formula, R 1 is H or CH 3 , R 2 is H, CH 3 , or CH 2 Cl, and n is an integer of 1 to 10). COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供廉价且耐氧化性和耐久性优异的固体聚合物电解质。该固体聚合物电解质含有选自α-甲基苯乙烯膦酸，苯乙烯膦酸，α-甲基苯乙烯烷基膦酸和苯乙烯烷基膦酸中的一种或多种单体的共聚物，和（间）由通式（A）表示的丙烯酸酯（式中，R 1 为H或CH 3，SB 2为H，CH 或者CH 2 ，n为1〜10的整数。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2005322491A Solid polyelectrolyte membrane having phosphate group and conjugated diene based liquid oligomer part, and its use 有权
标题翻译：具有磷酸酯基和稠合二烯基液体低聚物部分的固体聚电解质膜及其用途
公开(公告)号：JP2005322491A
公开(公告)日：2005-11-17
申请号：JP2004138852
申请日：2004-05-07
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： RIKUKAWA MASAHIRO , KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： C08J5/22 , C08F290/04 , C08L55/00 , H01B1/06 , H01M6/18 , H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a solid polyelectrolyte membrane which can be manufactured at a comparatively low cost, and which has a high proton conductivity in wide ranges of temperature and humidity, and has superior solvent resistance and water resistance, and provide its use. SOLUTION: The solid polyelectrolyte membrane, in which (1) (a) phosphate group containing unsaturated monomer having at least one or more phosphate group and ethylenic unsaturated bond in the molecule respectively, and (b) butadiene oligomer and isoprene oligomer having at least two of ethylenic unsaturated linkages in the molecule respectively, and at least one kind of conjugated diene based liquid oligomer selected from a group consisting of their derivatives are copolymerized, or in which (2) (c) a solid polyelectrolyte membrane is obtained by mixing a polymer of the phosphate group containing unsaturated monomer and (d) the conjugated diene based liquid oligomer, has the high proton conductivity in the wide ranges of temperature and humidity, and has the superior solvent resistance and water resistance. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种固体聚电解质膜，其能够以较低成本制造，并且在宽温度和湿度范围内具有高质子传导性，并且具有优异的耐溶剂性和耐水性，并提供其使用。解决方案：分子中分别含有（1）（a）含有不饱和单体的磷酸酯基和烯键式不饱和键的固体聚电解质膜和（b）丁二烯低聚物和异戊二烯低聚物，其具有分子中的至少两个烯键式不饱和键和至少一种选自其衍生物的共轭二烯系液体低聚物共聚，或者其中（2）（c）固体聚电解质膜通过混合含有不饱和单体的磷酸酯基团和（d）共轭二烯系液体低聚物的聚合物在宽温度和湿度范围内具有高质子传导性，并且具有优异的耐溶剂性和耐水性。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2005255855A Solid polyelectrolyte membrane containing amine-modified phosphate group, its raw material monomer composition, method for producing the solid polyelectrolyte membrane and use thereof 有权
标题翻译：含有氨基改性磷酸酯基团的固体聚电解质膜，其原料单体组合物，生产固体聚电解质膜的方法及其用途
公开(公告)号：JP2005255855A
公开(公告)日：2005-09-22
申请号：JP2004069652
申请日：2004-03-11
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： C08J5/22 , C08F220/54 , C08F226/02 , C08F228/02 , C08F230/02 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a solid polyelectrolyte membrane producible at a relatively low cost and having high proton conductivity in a wide temperature region and excellent solvent resistance, to provide a raw material monomer composition and to provide a method for producing the solid polyelectrolyte membrane and use thereof. SOLUTION: The solid polyelectrolyte membrane is obtained by polymerizing an unsaturated monomer prepared by modifying (a) a phosphate group-containing unsaturated monomer having one or more phosphate groups and ethylenically unsaturated bonds in the molecule, respectively with (b) an amino group-containing unsaturated monomer having one or more substituted or unsubstituted amino groups and ethylenically unsaturated bonds in the molecule, respectively and has quaternary ammonium base in which a part or most of hydroxy groups in the phosphate groups are reacted with the amino group. The solid polyelectrolyte membrane can be produced at the relatively low cost and has the high proton conductivity in the wide temperature region and the excellent solvent resistance. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供以较低成本生产且在宽温度区域具有高质子传导性和优异的耐溶剂性的固体聚电解质膜，以提供原料单体组合物并提供一种生产方法固体聚电解质膜及其用途。解决方案：固体聚电解质膜通过聚合通过将（a）分子中具有一个或多个磷酸酯基和烯键式不饱和键的含磷酸根基的不饱和单体分别改性（a）和（b）氨基在分子中具有一个或多个取代或未取代的氨基和烯属不饱和键的含有基团的不饱和单体，并且具有其中磷酸酯基中的部分或多数羟基与氨基反应的季铵碱。固体聚电解质膜可以以较低的成本生产，并且在宽温度区域具有高质子传导性和优异的耐溶剂性。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005194305A Method for producing homopolymerized product of phosphorus-based acid residue-containing unsaturated monomer, use of the homopolymerized product, method for producing solution of the homopolymerized product and use of the solution of the homopolymerized product 有权
标题翻译：用于生产含磷酸残留物的不饱和单体的共聚合产物的方法，使用共聚合产物，生产聚合产物的溶液的方法和使用共聚合产物的溶液
公开(公告)号：JP2005194305A
公开(公告)日：2005-07-21
申请号：JP2003435031
申请日：2003-12-26
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： KANZAKI YOSHIO , KANZAKI MUNEHIRO
IPC分类号： C08L29/04 , C08F2/04 , C08F30/02 , C08L43/02 , C08L61/28 , C09D5/24 , C09D129/04 , C09D143/02 , C09D159/00 , H01B1/20
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a polymerized product solely composed of a phosphorus-based acid residue-containing unsaturated monomer by solution polymerization without gelling.
SOLUTION: The method for producing the polymerized product solely composed of a phosphorus-based acid residue-containing unsaturated monomer containing at least one phosphorus-based acid residue and at least one ethylenically unsaturated bond in the molecule by solution polymerization comprises using an aliphatic lower alcohol containing 0.1 to 35 mass%, based on 100 mass% entire solvent, water as a solvent and making the concentration of the above phosphorus-based acid residue-containing unsaturated monomer to ≤14 mass% based on 100 mass% entire polymerization solution.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种仅通过不凝胶化的溶液聚合由含磷酸残基的不饱和单体组成的聚合产物的方法。解决方案：通过溶液聚合制备分子中含有至少一个磷酸残基和至少一个烯键式不饱和键的仅含磷基酸残基的不饱和单体的聚合产物的制备方法包括使用基于100质量％的全部溶剂，水作为溶剂含有0.1〜35质量％的脂肪族低级醇，基于100质量％的全部聚合使上述含磷类酸性残基的不饱和单体的浓度为≤14质量％解。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2005194304A Phosphate group-containing hydrocarbon oligomer material and/or phosphate group-containing hydrocarbon polymer material, composite solid electrolyte membrane containing acidic group-containing fullerene derivative and its use 审中-公开
标题翻译：含磷酸基的烃类低聚物材料和/或含磷酸酯基的含烃聚合物材料，含有酸性基团的富烯烃衍生物的复合固体电解质膜及其用途
公开(公告)号：JP2005194304A
公开(公告)日：2005-07-21
申请号：JP2003435030
申请日：2003-12-26
申请人： Uni-Chemical Co Ltd , ユニケミカル株式会社
发明人： SANAI KOHEI , RIKUKAWA MASAHIRO , TAKEOKA HIROKO , AKIZUKI TAKESHI , KANZAKI YOSHIO , ITO KOREATSU
IPC分类号： C08L63/00 , C08K3/04 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： B82Y30/00
摘要： PROBLEM TO BE SOLVED: To provide a composite solid electrolyte membrane excellent in proton conductivity not only at high humidity but also in the absence of humidity which comprises a hydrocarbon oligomer material and/or a hydrocarbon polymer material capable of exhibiting proton conductivity and an acidic group-containing fullerene derivative, and its use.
SOLUTION: The composite solid electrolyte membrane is obtained by adding a phosphate group-containing hydrocarbon oligomer material and/or a phosphate group-containing hydrocarbon polymer material as an adhesive to an acidic group-containing fullerene derivative.
COPYRIGHT: (C)2005,JPO&NCIPI

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