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    • 2. 发明专利
    • Composite electrode
    • 复合电极
    • JP2009064779A
    • 2009-03-26
    • JP2008219430
    • 2008-08-28
    • Technical Univ Of Denmarkテクニカル ユニヴァーシティー オブ デンマーク
    • MENON MOHANLARSEN PETER HALVOR
    • H01M4/88H01M4/86
    • H01M4/8605H01M4/8652H01M4/90H01M4/9016H01M4/9066H01M2008/1293
    • PROBLEM TO BE SOLVED: To provide a new composite electrode capable of attaining both the suitable stability (limited rough and large size) and the high performance (low ASR) of a created composite electrode material.
      SOLUTION: The electrode material can be obtained by following a process comprising steps of: (a) providing a precursor solution or a suspension of a first component wherein the solution or the suspension contains a solvent; (b) forming particles of the first component and entrapping the particles of the first component within the pore structure of a second component by mixing and subsequently heating, drying or centrifuging the solution, the suspension, or powder of the second component with the precursor solution or the suspension of the first component, in which the second component has a porous structure with an average pore diameter of 2 to 1,000 nm.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种能够实现所制造的复合电极材料的合适的稳定性(有限粗大和大尺寸)和高性能(低ASR)的新型复合电极。 电极材料可以通过以下方法获得,该方法包括以下步骤:(a)提供第一组分的前体溶液或悬浮液,其中溶液或悬浮液含有溶剂; (b)通过混合并随后加热,干燥或离心第二组分的溶液,悬浮液或粉末与前体溶液,形成第一组分的颗粒并将第一组分的颗粒截留在第二组分的孔结构内 或第一组分的悬浮液,其中第二组分具有平均孔径为2至1000nm的多孔结构。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Metal support type solid oxide fuel cell
    • 金属支持类固体氧化物燃料电池
    • JP2009059697A
    • 2009-03-19
    • JP2008219433
    • 2008-08-28
    • Technical Univ Of Denmarkテクニカル ユニヴァーシティー オブ デンマーク
    • LARSEN PETER HALVOR
    • H01M4/88H01M4/86H01M8/02H01M8/12
    • H01M4/8889H01M4/8621H01M4/9033H01M4/9066H01M8/1226H01M8/1246Y02E60/525Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a solid oxide fuel cell being robust and having higher corrosion stability than a conventional fuel cell and high resistance to poisonous chromium.
      SOLUTION: A reversible solid oxide fuel cell obtainable by a method comprising the steps of: providing a metallic support layer; forming a cathode precursor layer on the metallic support layer; forming an electrolyte layer on the cathode precursor layer; sintering the obtained multilayer structure; in any order conducting the steps of: forming a cathode layer by impregnating the cathode precursor layer; and forming an anode layer on the electrolyte layer; characterized in that the method further comprises prior to forming the cathode layer, impregnating a precursor solution or a precursor suspension of a barrier material into the metallic support layer and the cathode precursor layer and subsequently conducting a heat treatment.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种坚固的固体氧化物燃料电池,并且具有比常规燃料电池更高的腐蚀稳定性,并且具有高的耐有机铬。 解决方案:一种可逆固体氧化物燃料电池,其可通过包括以下步骤的方法获得:提供金属支撑层; 在金属支撑层上形成阴极前体层; 在阴极前体层上形成电解质层; 烧结得到的多层结构; 以任何顺序进行以下步骤:通过浸渍阴极前体层形成阴极层; 以及在所述电解质层上形成阳极层; 其特征在于,所述方法还包括在形成阴极层之前,将阻挡材料的前体溶液或前体悬浮液浸渍到金属支撑层和阴极前体层中,并随后进行热处理。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Solid oxide cell and solid oxide cell stack
    • 固体氧化物细胞和固体氧化物细胞堆积
    • JP2010177187A
    • 2010-08-12
    • JP2009274262
    • 2009-12-02
    • Technical Univ Of Denmarkテクニカル・ユニヴァーシティ・オブ・デンマーク
    • VANG HENDRIKSEN PETERBARFOD RASMUSLIU YI-LINCHEN MING
    • H01M8/02C04B35/00C04B35/48C25B1/04C25B13/04H01M4/86H01M4/88H01M8/12
    • H01M4/8652H01M4/8657H01M4/8846H01M4/9016H01M4/9033H01M8/1253Y02E60/366Y02E60/525Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a solid oxide cell which is hardly deteriorated. SOLUTION: An assembly of a fuel electrode support, fuel electrode, and an electrolyte layer is fabricated by depositing a fuel electrode layer on a fuel electrode support layer, and by depositing an electrolyte layer containing stabilized zirconia on the fuel electrode layer. Arbitrarily, an assembly of the fuel electrode support layer, the fuel electrode, and an electrolyte is sintered together, and a preliminarily sintered half cell is fabricated. One or more oxygen electrode layer is deposited on the electrode layer of that half cell, and a complete solid oxide cell is fabricated. At least one of oxygen electrode layers out of one or more oxygen electrode layers contains composite of lanthanum-strontium-manganite and stabilized zirconia, one or more of oxygen electrode layers is sintered together with the preliminarily sintered half cell, sintered complete solid oxide cells is fabricated. One or more of oxygen electrode layers is impregnated into manganese, and manganese impregnated solid oxide cell is fabricated to obtain the solid oxide cell. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供几乎不劣化的固体氧化物电池。 解决方案:通过在燃料电极支撑层上沉积燃料电极层,并通过在燃料电极层上沉积含有稳定的氧化锆的电解质层来制造燃料电极支撑体,燃料电极和电解质层的组件。 任意地,燃料电极支撑层,燃料电极和电解质的组装被烧结在一起,并且制造预烧结的半电池。 一个或多个氧电极层沉积在该半电池的电极层上,并制成完整的固体氧化物电池。 一个或多个氧电极层中的氧电极层中的至少一个含有镧 - 锶 - 锰酸盐和稳定的氧化锆的复合物,一个或多个氧电极层与预烧结的半电池一起烧结,烧结的完全固体氧化物电池 制造。 将一个或多个氧电极层浸渍到锰中,并制备锰浸渍的固体氧化物电池以获得固体氧化物电池。 版权所有(C)2010,JPO&INPIT
    • 8. 发明专利
    • Electrode based on cerium oxide and stainless steel
    • 基于氧化铈和不锈钢的电极
    • JP2009110934A
    • 2009-05-21
    • JP2008219434
    • 2008-08-28
    • Technical Univ Of Denmarkテクニカル ユニヴァーシティー オブ デンマーク
    • BLENNOW PETERMOGENSEN MOGENS
    • H01M4/86C22C38/00C25B11/04H01M4/04H01M4/88H01M8/12
    • H01M4/9066H01M4/0416H01M4/9016H01M4/9033
    • PROBLEM TO BE SOLVED: To provide an anode structure can obtaining high electrochemical activity under a wide range of temperatures by improving expansion of an electrode and low stability due to such expansion.
      SOLUTION: A thermet anode structure can be obtained by a method including following steps, that is, by a step (a) in which slurry is prepared by dispersing powder of a conductive phase, and then by adding a binder to these dispersed powders, and at this time, the conductive phase contains an FeCrMx alloy in which Mx is selected from a group consisting of Ni, Ti, Nb, Ce, Mn, Mo, W, Co, La, Y, Al, and their mixtures, a step (b) in which a metallic support body is formed from the slurry of the conductive phase, a step (c) in which precursor solution of cerium oxide is prepared, and this solution contains a solvent and a surfactant, a step (d) in which the structure of the step (b) is impregnated with the precursor solution of the step (c), a step (e) in which the structure obtained in the step (d) is calcined, and then a step (f) in which the steps of (d) to (e) are carried out at least once.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供阳极结构,可以通过改善电极的膨胀和由于这种膨胀导致的低稳定性,在宽的温度范围内获得高的电化学活性。 解决方案:热阳极结构可以通过包括以下步骤的方法获得,即通过步骤(a),其中通过分散导电相粉末制备浆料,然后通过向这些分散的粉末中加入粘合剂 粉末,此时导电相含有Fe x M x合金,其中M x选自Ni,Ti,Nb,Ce,Mn,Mo,W,Co,La,Y,Al及其混合物, 由导电相的浆料形成金属支撑体的工序(b),其中制备氧化铈的前体溶液的工序(c),该溶液含有溶剂和表面活性剂,工序(d )其中步骤(b)的结构用步骤(c)的前体溶液浸渍,其中步骤(d)中获得的结构被煅烧的步骤(e),然后步骤(f) 其中步骤(d)至(e)至少进行一次。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Improved method for manufacturing reversible solid oxide cell
    • 用于制造可逆固体氧化物细胞的改进方法
    • JP2008130568A
    • 2008-06-05
    • JP2007301729
    • 2007-11-21
    • Technical Univ Of Denmarkテクニカル ユニバーシティ オブ デンマーク
    • LARSEN PETER HALVORBRODERSEN KAREN
    • H01M4/88H01M8/02H01M8/12
    • H01M8/1253H01M4/8621H01M4/8857H01M8/1213H01M8/1226H01M8/124H01M8/1246H01M8/184H01M2008/1293Y02E60/528Y02P70/56
    • PROBLEM TO BE SOLVED: To provide an improved and cost-effective method for manufacturing a reversible solid oxide cell.
      SOLUTION: The method for manufacturing the reversible solid oxide cell has a step of tape-casting an anode support layer on a support 1, a step of tape-casting the anode layer on a support 2, and a step of tape-casting an electrolyte layer on a support 3. The method also has a step of laminating the anode layers in the upper part of the anode support layer, a step of removing the support 2 from the anode layer, a step of laminating the electrolyte layers in the upper part of the anode layer, and a step of sintering the multi-layered structure, or this method has a step of laminating the anode layers on the upper part of the electrolyte layer, a step of removing the support 2 from the anode layer, a step of laminating the anode support layers in the upper part of the anode layer, and a step of sintering the multi-layered structure.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于制造可逆固体氧化物电池的改进且成本有效的方法。 解决方案:用于制造可逆固体氧化物电池的方法具有将载体1上的阳极支撑层流延的步骤,将支撑体2上的阳极层带入的步骤, 在支撑体3上浇铸电解质层。该方法还具有在阳极支撑层的上部层叠阳极层的步骤,从阳极层除去载体2的步骤,将电解质层层叠的步骤 阳极层的上部和烧结多层结构的步骤,或者该方法具有将阳极层层压在电解质层的上部的步骤,从阳极层除去载体2的步骤 ,在阳极层的上部层叠阳极支撑层的工序和烧结多层结构的工序。 版权所有(C)2008,JPO&INPIT