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    • 5. 发明专利
    • Method for producing vinyl ether polymer having carboxy group at terminal
    • 用于生产具有羧基末端的乙烯基醚聚合物的方法
    • JP2003335816A
    • 2003-11-28
    • JP2002148300
    • 2002-05-22
    • Kyowa Yuka Co Ltd協和油化株式会社
    • INAYAMA TOSHIHIRONIIMI TATSUOMURATA SHIGERUSHIMIZU IKUO
    • C08F8/06C08F16/00
    • PROBLEM TO BE SOLVED: To provide a method for simply and industrially advantageously producing a vinyl ether polymer having a carboxy group at the terminal by oxidizing a vinyl ether polymer having an acetal or a formyl group at the terminal without accompanying the reduction of the reaction rate, the secondary production of an ester compound, the secondary production of a peroxide and the like.
      SOLUTION: The method for producing the vinyl ether polymer having a carboxy group at the terminal comprises oxidizing a polymer having a formyl group or an acetal at the terminal and, simultaneously, containing a polyvinyl ether structure in the presence of a compound to be selected from the group consisting of a peroxyacid, its salt, and their mixture in the reaction system free of tetrahydrofuran and alumina.
      COPYRIGHT: (C)2004,JPO
    • 待解决的问题:提供简单且工业上有利地通过在末端氧化具有缩醛或甲酰基的乙烯基醚聚合物在末端具有羧基的乙烯基醚聚合物而不伴随着还原的方法 反应速率,酯化合物的二次生成,二次过氧化物的二次生成等。 解决方案:在端子上具有羧基的乙烯基醚聚合物的制造方法包括在化合物的存在下将末端具有甲酰基或缩醛的聚合物氧化,同时含有聚乙烯基醚结构, 在不含四氢呋喃和氧化铝的反应体系中选自过氧酸,其盐及其混合物。 版权所有(C)2004,JPO
    • 6. 发明专利
    • Method for producing ether-dicarboxylic acid or its salt
    • 生产二苯甲酸或其盐的方法
    • JP2003012598A
    • 2003-01-15
    • JP2001195653
    • 2001-06-28
    • Kyowa Yuka Co Ltd協和油化株式会社
    • MATSUOKA YOJIKONISHI SHINICHINAKAYAMA SHINGOFUKUDA YUKITOSHI
    • C07C51/367C07C59/305
    • PROBLEM TO BE SOLVED: To provide a method for producing an ether-dicarboxylic acid or its salt, capable of producing the ether-dicarboxylic acid or its salt in high yield in a highly safe and simple manner, and suitable as an industrial process.
      SOLUTION: The method for producing an ether-dicarboxylic acid or its salt comprises a reaction of a diol expressed by general formula (I) (wherein, n is an integer of 1-10) with an α-halocarboxylic acid expressed by general formula (II) [wherein, R is an alkyl, a cycloalkyl or a (substituted) aryl; and X is a halogen] or its salt in the presence of an alkali alkoxide. An ether- dicarboxylic acid expressed by formula (III) (wherein, R and n are defined as above) is obtained by the method.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供一种以高安全性和简单的方式生产醚二羧酸或其盐的方法,该方法能够以高产率生产醚二羧酸或其盐,并且适合作为工业方法。 解决方案:制备醚 - 二羧酸或其盐的方法包括由通式(I)表示的二醇(其中n为1-10的整数)与通式(I)表示的α-卤代羧酸的反应 II)[其中,R是烷基,环烷基或(取代的)芳基; 并且X是卤素]或其盐在碱金属醇盐的存在下进行。 通过该方法得到由式(III)表示的醚 - 二羧酸(其中,R和n如上定义)。