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    • 4. 发明专利
    • MANUFACTURING METHOD OF SnO2 GAS SENSOR, AND MANUFACTURING METHOD OF SnO2 CARRYING HAVING NOBLE METAL NANOPARTICLES
    • SnO2气体传感器的制造方法及具有金属纳米粒子的SnO2的制造方法
    • JP2010032343A
    • 2010-02-12
    • JP2008194402
    • 2008-07-29
    • Figaro Eng Incフィガロ技研株式会社
    • SHIMANOE KENGOKIDA TETSUYAYUASA MASAYOSHI
    • G01N27/12G01N27/16
    • PROBLEM TO BE SOLVED: To manufacture efficiently SnO
      2 having noble metal nanoparticles carried thereon.
      SOLUTION: A chelate compound equipped with at least two ligands coordinated into SnO
      2 and at least two ligands coordinated into a noble metal is added to hydrosol of SnO
      2 , to thereby coordinate the chelate compound into SnO
      2 sol, wherein noble metal nanoparticles in which an organic compound is coordinated are dispersed in an organic dispersant is brought into contact with the hydrosol of SnO
      2 in which the chelate compound is coordinated, to thereby coordinate the chelate compound into the noble metal nanoparticles; thereby the noble metal nanoparticles are carried on SnO
      2 particles in the sol; and the calcination is performed to acquire an SnO
      2 gas sensor. The noble metal nanoparticles can be carried efficiently on SnO
      2 .
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了有效地制造在其上承载有贵金属纳米颗粒的SnO 2 SB 2 。 解决方案:将配有至少两种配位到SnO 2 SBS中的配体和至少两种配位到贵金属中的配体的螯合物加入SnO 2 SBS的水溶胶中, 从而将螯合化合物配制成SnO 2 SBS 2溶胶,其中将有机化合物配位的贵金属纳米颗粒分散在有机分散剂中,使其与SnO 2的水溶胶接触, SB>其中螯合化合物配位,从而将螯合化合物配位成贵金属纳米颗粒; 从而将贵金属纳米颗粒载在溶胶中的SnO 2 颗粒上; 并进行煅烧以获取SnO 2 气体传感器。 贵金属纳米粒子可以在SnO 2 SBB上有效地载运。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Liquid electrochemical gas sensor
    • 液体电化学气体传感器
    • JP2008058213A
    • 2008-03-13
    • JP2006237248
    • 2006-09-01
    • Figaro Eng Incフィガロ技研株式会社
    • FUJIMORI HIROKIKATO YUKIINOUE TOSHIHIRO
    • G01N27/404
    • PROBLEM TO BE SOLVED: To provide a new liquid electrochemical gas sensor that prevents overflow of electrolyte in a high humidity atmosphere by using no sulfuric acid and operates even at a low temperature of approximately -40°C. SOLUTION: The liquid electrochemical gas sensor is a gas sensor where at least one pair of electrodes are connected to liquid electrolyte. In the liquid electrolyte, condensation polymerization compound of at least one material of a group made of naphthalene sulfonic acid, its salt, and its derivative is used as an electrolyte component. The liquid electrolyte is held in a separator, and a detection pole and counter pole are connected to the separator. The liquid electrochemical gas sensor has: a sump; a means for supplying a detected atmosphere to the detection pole side; and a means for supplying water vapor from the sump to the counter electrode side. CO sensitivity is obtained at about -40 to 70°C, and the gas sensitivity is maintained even after the high temperature atmosphere and high-temperature high-humidity atmosphere are experienced. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种新的液体电化学气体传感器,其通过不使用硫酸来防止电解质在高湿度环境中溢出,即使在大约-40℃的低温下也能运行。 解决方案:液体电化学气体传感器是一种气体传感器,其中至少一对电极连接到液体电解质。 在液体电解质中,使用由萘磺酸,其盐及其衍生物构成的组中的至少一种材料的缩聚化合物作为电解质成分。 液体电解质保持在隔板中,检测极和反极连接到隔板上。 液体电化学气体传感器具有:贮槽; 用于将检测气氛提供到检测极侧的装置; 以及用于从水槽向对电极侧供给水蒸气的装置。 在约-40〜70℃下获得CO灵敏度,即使经历了高温大气和高温高湿气氛之后也保持气敏性。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Co2 sensor and co2 detecting method
    • CO2传感器和二氧化碳检测方法
    • JP2005201698A
    • 2005-07-28
    • JP2004006239
    • 2004-01-14
    • Figaro Eng Incフィガロ技研株式会社
    • YAMAZOE NOBORUSHIMANOE KENGOSAKAI TAKESHIMIYAJI YUJI
    • G01N27/406G01N27/416
    • PROBLEM TO BE SOLVED: To reduce the effect of CO 2 or steam on a counter electrode when a Berthollide compound, which contains an alkali metal, a transition metal and oxygen and is characterized in that alkali metal is contained in a non-stoichiometric ratio is used in the counter electrode and to suppress the fluctuations in electromotive force caused by non-heating standing. SOLUTION: A detection electrode and the counter electrode comprising a glass-sealed Na x CoO 2-y film are connected to a NASICON film. When the CO 2 sensor thus produced is restarted after allowed to stand at a room temperature, a stable electromotive force is rapidly obtained. COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:为了减少含有碱金属,过渡金属和氧气的贝氏体化合物,并且其特征在于碱的作用,可以降低CO 2 或蒸汽对对电极的影响 金属以非化学计量比包含在对电极中并且抑制由非加热静置引起的电动势的波动。

      解决方案:包括玻璃密封的Na SB SBO 2的检测电极和对电极连接到NASICON膜。 当这样制造的CO 2 传感器在室温下放置后重新启动时,迅速获得稳定的电动势。 版权所有(C)2005,JPO&NCIPI

    • 10. 发明专利
    • Gas sensor and its manufacturing method
    • 气体传感器及其制造方法
    • JP2005037316A
    • 2005-02-10
    • JP2003276536
    • 2003-07-18
    • Figaro Eng Incフィガロ技研株式会社
    • TONE HIROSHIHONDA TOMOYASUOGOSHI TOKIO
    • G01N27/12G01N27/00G01N27/14
    • PROBLEM TO BE SOLVED: To provide a gas sensor and its manufacturing method capable of maintaining bonding strength even in parallel directions and in vertical directions to a substrate for a long period without covering a bonding part to a pad with a gold paste. SOLUTION: Pt-based leads are arranged on gold alloy pads, and thermo-compression bonding is performed on gold-based bumps to sandwich and fix the leads between the bumps and the pads. The bumps are formed in a disk shape, and are six to twelve times larger than the leads in diameter, two to five times higher, and do not have any recession part in their upper surfaces. By this method, it is possible to facilitate bonding and maintain high bonding strength for a long period. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种气体传感器及其制造方法,其能够即使在平行方向和垂直方向上保持长时间的基板的接合强度,也不用金膏将焊接部分覆盖到焊盘上。

      解决方案:Pt基导线布置在金合金焊盘上,并且在金基凸块上进行热压接,以将引线夹在并固定在凸块和焊盘之间。 凸块形成为圆盘状,比直径大6〜12倍,高2〜5倍,上表面不具有任何凹部。 通过这种方法,可以长时间地促进粘合和保持高的结合强度。 版权所有(C)2005,JPO&NCIPI