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    • 1. 发明专利
    • MEASURING METHOD FOR CONCENTRATION OF SOLUTE ELEMENT IN MOLTEN METAL
    • JPH10185863A
    • 1998-07-14
    • JP35622896
    • 1996-12-24
    • KAWASO DENKI KOGYOIWASE MASANORI
    • IWASE MASANORIGOMYO KENICHI
    • G01N27/411G01N20060101G01N33/20
    • PROBLEM TO BE SOLVED: To obtain a measuring method by which the concentration itself of an element as an object to be measured can be measured, by using an electrochemical sensor, which measures the activity of the object to be measured in molten metal and computing the concentration by using a specific expression on the basis of a detected electromotive force and on the basis of the temperature of the molten metal. SOLUTION: An electrochemical sensor, which measures the activity of an object to be measured in a molten metal is used in such a way that a solid electrolyte, which is oxygen ion-conductive and an inorganic substance containing the oxide of an element identical to an element as an object to be measured, with which a subelectrode or the solid electrolyte is to be coated are combined or that a solid electrolyte, which contains the oxide of the element identical to the element as the object to be measured and which is oxygen ion-conductive is used. Then, on the basis of an electromotive force E detected by a sensor and on the basis of the temperature T of a liquid metal, the concentration [%M] of the element as the object to be measured is computed by an expression: log[%M]+C0 [%M]=C1 +C2 (E/T)+C3 /T-ΣCi[%X] (where C0 , C1 , C2 , C3 and Ci represent constant, and [%X] represents a solute element other tham a component M in the molten metal).
    • 6. 发明专利
    • LEAKAGE SENSING SENSOR IN METAL MELTING FACILITY
    • JPH08303964A
    • 1996-11-22
    • JP13277195
    • 1995-05-02
    • KAWASO DENKI KOGYO
    • SAKAGUCHI IKUHEI
    • G01M3/04F27B3/28F27D21/00G01M3/16
    • PURPOSE: To prevent an erroneous operation of an alarm by a method wherein a sensor electrode is sealingly enclosed at a protective cap made of specifically selected metal between it and molten metal so as to protect it. CONSTITUTION: A leakage sensing sensor 16 inserted into and loaded at one location or a plurality of locations in a clearance 15 between a crucible 13 storing molten metal 12 therein and an external container 14 is comprised of an insulator 17 and a metalic protection cap 20 inserted into the insulator and for sealingly enclosing a pair of electrodes 19, 19 in a non-contacted state which are projected from the insulator 17 at its extremity end. As a metal constituting raw material of the protection cap 20, it is selected from metal in which its melting point is higher than an operating temperature, although a melting point of alloy when the molten metal 12 is contacted with the cap to make alloy is set to be higher than an operating temperature. Due to this fact, the protection cap 20 is not melted during an operation of a melting furnace, but protects the electrodes 19 and in turn upon contact of it with the leaked molten metal 12, the metal is rapidly melted under the operating temperature to cause the electrodes 19 to be operated, resulting in that a stable operation and a real time sensing of leakage can be realized.
    • 8. 发明专利
    • MULTI-WAVELENGTH RADIATION THERMOMETER
    • JPH07294337A
    • 1995-11-10
    • JP11037794
    • 1994-04-25
    • KAWASO DENKI KOGYOSUMITOMO METAL IND
    • SHIBATA TOMOOUEMATSU CHIHIROHIRAMOTO KAZUO
    • G01J5/08G01J5/60
    • PURPOSE:To obtain a highly precise thermometer without dependency on temperature and moisture by insulating a spectroscopic filter from an outer air by an insulative housing and keeping the temperature and/or moisture within the housing to be constant. CONSTITUTION:A spectroscopic filter 4 is placed parallel to the transparent plates of windows 2 and 3 and the inside temperature within an insulative housing 1 is kept constant by a temperature keeping means 5. A thermal radiation light entering from the first window 2 is dispersed into different multiple thermal radiaton lights by the filter 4, and after they enters from the second window 3, they are detected in the outside of the housing 1 by a detector 6. Therefore, since the housing 1 encloses the filter 4 therein and keeps the inside temperature to be at a constant temperature regardless of the outside temperature, the filter 4 is hardly affected by the change in ambient temperature accompanying the change of climate as well as the invasion of moisture from the outside, and furthermore stable measurement can be prefomed even under such a measuring environment that ultra micro-dusts fly.
    • 9. 发明专利
    • METHOD FOR MEASURING CARBON CONTENT IN MOLTEN STEEL SUCH AS STAINLESS STEEL
    • JPH07151716A
    • 1995-06-16
    • JP32320193
    • 1993-11-29
    • KAWASO DENKI KOGYONIPPON STEEL CORP
    • TAKANO HIRONORIMORISHIGE HIROAKISHIGETA YOSHITERU
    • G01N25/06G01N33/20
    • PURPOSE:To make the accurate measurement of carbon content in molten steel possible, by carrying out operation on the basis of a molten steel temperature detected from the molten steel, the solidification temperature of the molten steel and the Cr content in the molten steel. CONSTITUTION:When a probe 1 is immersed in molten steel, a metal cover 17 and metal cap 16 are eluted to be lost, and the molten steel is filled up in a sampling holder 12. The solidification temperature LT of the molten steel solidified in a molten steel solidification chamber 12b is detected by a means 14 for measuring solidification temperature. The temperature MT of a molten steel bath is detected by a means 4 for measuring molten steel temperature, and the Cr content in the molten steel is detected by a Cr sensor 3a, 3b. The activity of Cr in the molten steel is converted into the oxygen potential by a sub-electrode of a sensor element 3a and brought out as the potential difference by a solid electrolyte, as the partial pressure of oxygen equilibrated on three phase interfaces between molten metal/sub-electrode/solid electrolyte, and the electromotive force E is generated between a reference electrode of the element 3a and a molten metal electrode 3b. The C content in the molten steel is computed by an equation (C0-C5 are coefficients). An error of a measured value by the fluctuation of the Cr content does not occur.